GC-MS/MS Determination of Migrated Amounts of 18 PAHs in Household Soybean Milk Machines
摘 要
提出了家用豆浆机中18种多环芳烃(PAHs)迁移量的气相色谱-串联质谱法。取食品模拟液1 L在豆浆机正常运行下迁移60 min,迁移溶液经活化的C18固相萃取柱净化,用正己烷5 mL以3 mL·min-1的速率洗脱。净化液经无水硫酸钠干燥后,采用Agilent DB-17MS色谱柱进行气相色谱分离。质谱分析中采用电子轰击离子源和多反应监测模式。18种多环芳烃的质量浓度在一定范围内与其峰面积呈线性关系,检出限(3S/N)在0.3~2.0 ng·L-1之间。按标准加入法在3个浓度水平上进行回收试验,回收率在78.5%~121%之间,测定值的相对标准偏差(n=6)在2.9%~12%之间。
Abstract
A method was proposed for determination of migrated amounts of 18 PAHs in household soybean milk machines by GC-MS/MS. 1 L of food simulation was added in soybean milk machine and migrated for 60 min under the normal operation. The migrated solution was purified on activated C18 solid phase extraction (SPE) column and the analytes were eluted from the column with 5 mL of n-hexane (a flow rate of 3 mL·min-1). After dying with anhydrous sodium sulfate, the purified solution was separated by GC using Agilent DB-17MS column. EI and MRM were adopted in MS. Linear relationships between values of peak area and mass concentration of 18 PAHs were found in definite ranges, with detection limits (3S/N) in the range of 0.3-2.0 ng·L-1. Test for recovery was made by standard addition at 3 concentration levels, giving results in the range of 78.5%-121%, with RSDs (n=6) ranged from 2.9% to 12%.
中图分类号 O657.63 DOI 10.11973/lhjy-hx201710005
所属栏目 工作简报
基金项目 质检公益性行业科研专项(201510031)
收稿日期 2016/12/1
修改稿日期
网络出版日期
作者单位点击查看
备注王志娟(1987-),女,黑龙江大兴安岭人,工程师,研究方向为消费品安全
引用该论文: WANG Zhijuan,WANG Wan,LI Haiyu,XIAO Haiqing,ZHANG Qing,BAI Hua,LÜ,Qing. GC-MS/MS Determination of Migrated Amounts of 18 PAHs in Household Soybean Milk Machines[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2017, 53(10): 1140~1145
王志娟,王婉,李海玉,肖海清,张庆,白桦,吕庆. 气相色谱-串联质谱法测定家用豆浆机中18种多环芳烃迁移量[J]. 理化检验-化学分册, 2017, 53(10): 1140~1145
共有人对该论文发表了看法,其中:
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】尚海龙,秦丽.豆浆机润滑油风波调查[J].电器, 2011(10):23-24.
【2】王丽琴.气质联用仪测定电子电气产品中多环芳烃[J].化学分析计量, 2010,19(5):46-48.
【3】殷居易,谢东华,陈建国,等.液相色谱-大气压光电电离源质谱法同时测定电子电气产品中16种多环芳烃残留[J].质谱学报, 2009,30(5):300-306.
【4】梁鸣,姜晓黎,翁若荣,等.气相色谱-质谱法测定电子电气衬料中多环芳烃和多氯联苯[J].分析试验室, 2009,28(S1):36-41.
【5】姜晓黎,梁鸣,翁若荣,等.气相色谱-质谱法测定电子电气产品材料中多环芳烃[J].福建分析测试, 2009,18(2):50-54.
【6】GB/T 29784.1-2013电子电气产品中多环芳烃的测定第1部分:高效液相色谱法[S].
【7】GB/T 29784.2-2013电子电气产品中多环芳烃的测定第2部分:气相色谱-质谱法[S].
【8】GB/T 29784.3-2013电子电气产品中多环芳烃的测定第3部分:液相色谱-质谱法[S].
【9】GB/T 29784.4-2013电子电气产品中多环芳烃的测定第4部分:气相色谱法[S].
【10】ZEK 01.4-08 Testing and validation of polycyclic aromatic hydrocafbons (PAH) in the course of GS-Mark Certification[S].
【11】GB 31604.1-2015食品安全国家标准食品接触材料及制品迁移试验通则[S].
【2】王丽琴.气质联用仪测定电子电气产品中多环芳烃[J].化学分析计量, 2010,19(5):46-48.
【3】殷居易,谢东华,陈建国,等.液相色谱-大气压光电电离源质谱法同时测定电子电气产品中16种多环芳烃残留[J].质谱学报, 2009,30(5):300-306.
【4】梁鸣,姜晓黎,翁若荣,等.气相色谱-质谱法测定电子电气衬料中多环芳烃和多氯联苯[J].分析试验室, 2009,28(S1):36-41.
【5】姜晓黎,梁鸣,翁若荣,等.气相色谱-质谱法测定电子电气产品材料中多环芳烃[J].福建分析测试, 2009,18(2):50-54.
【6】GB/T 29784.1-2013电子电气产品中多环芳烃的测定第1部分:高效液相色谱法[S].
【7】GB/T 29784.2-2013电子电气产品中多环芳烃的测定第2部分:气相色谱-质谱法[S].
【8】GB/T 29784.3-2013电子电气产品中多环芳烃的测定第3部分:液相色谱-质谱法[S].
【9】GB/T 29784.4-2013电子电气产品中多环芳烃的测定第4部分:气相色谱法[S].
【10】ZEK 01.4-08 Testing and validation of polycyclic aromatic hydrocafbons (PAH) in the course of GS-Mark Certification[S].
【11】GB 31604.1-2015食品安全国家标准食品接触材料及制品迁移试验通则[S].
相关信息