碳纳米管/铝界面反应程度及其与复合材料力学性能的关系
CNTs/Al Interfacial Reaction Degree and the Relationship with Mechanical Performance of Composite
摘 要
采用电化学溶解-气相色谱标定方法，研究了不同烧结时间下质量分数2%CNTs/5083Al复合材料中界面反应程度的变化规律，并探讨了界面反应程度与复合材料力学性能的关系。结果表明：在570℃烧结温度下，当烧结时间从1 h延长到6 h时，2%CNTs/5083Al复合材料的界面反应程度从5.5%增加到24.1%，并与烧结时间成一定的线性关系；随着烧结时间的延长，复合材料的杨氏模量、屈服强度与抗拉强度均呈先增加后降低的趋势，而伸长率呈先略微下降后持续增加的趋势。
铝基复合材料
界面反应程度
力学性能
Carbon nanotube
aluminum matrix composite
interfacial reaction degree
mechanical performance
Abstract
The evolution of interfacial reaction degree with different sintering time of mass fraction 2% CNTs/5083Al composite was studied by the electrochemical dissolution-gas chromatography method. The relationship of interfacial reaction degree and mechanical performance was discussed. The results show that with sintering time increasing from 1 h to 6 h, interfacial reaction degree of 2%CNTs/5083Al composite increased from 5.5% to 24.1% and showed a certain linear relationship with sintering time when the composite was sintered at 570℃. Young's modulus, yield strength and tensile strength of the composite increased at first and then decreased, while the elongation decreased slightly at first and then increased continuously with the increase of sintering time.
中图分类号 TB331 DOI 10.11973/jxgccl201711003
所属栏目 试验研究
基金项目 科技部“973”计划项目（2012CB619600）；国家自然科学基金资助项目（51131004，51671130，51511130038）；上海市自然科学基金资助项目（14DZ2261200，15JC1402100）
收稿日期 2016/11/17
修改稿日期 2017/10/15
网络出版日期
作者单位点击查看
备注李忠文(1980-),男,山东青岛人,工程师,博士
引用该论文: LI Zhongwen,LIN Renbang,HU Li,YU Ziyun,YAN Laipeng,TAN Zhanqiu,FAN Genlian,LI Zhiqiang,ZHANG Di. CNTs/Al Interfacial Reaction Degree and the Relationship with Mechanical Performance of Composite[J]. Materials for mechancial engineering, 2017, 41(11): 19～22
李忠文,林仁邦,胡励,俞子贇,鄢来朋,谭占秋,范根莲,李志强,张荻. 碳纳米管/铝界面反应程度及其与复合材料力学性能的关系[J]. 机械工程材料, 2017, 41(11): 19～22
共有人对该论文发表了看法，其中：
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】AJAYAN P M, ZHOU O Z. Carbon nanotubes[M].[S.l.]: Springer, 2001: 391-425.
【2】BAKSHI S R, KESHRI A K, SINGH V, et al. Interface in carbon nanotube reinforced aluminum silicon composites: thermodynamic analysis and experimental verification[J]. Journal of Alloys and Compounds, 2009, 481(1): 207-213.
【3】CHU K, JIA C C, JIANG L K, et al. Improvement of interface and mechanical properties in carbon nanotube reinforced Cu-Cr matrix composites[J]. Materials & Design, 2013, 45: 407-411.
【4】DENG C, WANG D, ZHANG X, et al. Processing and properties of carbon nanotubes reinforced aluminum composites[J]. Materials Science and Engineering: A, 2007, 444(1): 138-145.
【5】HE C, ZHAO N, SHI C, et al. An approach to obtaining homogeneously dispersed carbon nanotubes in Al powders for preparing reinforced Al-matrix composites[J]. Advanced Materials, 2007, 19(8): 1128-1132.
【6】HWANG J, LIM B, TILEY J, et al. Interface analysis of ultra-high strength carbon nanotube/nickel composites processed by molecular level mixing[J]. Carbon, 2013, 57: 282-287.
【7】BAKSHI S R, AGARWAL A. An analysis of the factors affecting strengthening in carbon nanotube reinforced aluminum composites[J]. Carbon, 2011, 49: 533-544.
【8】LAHA T, KUCHIBHATLA S, SEAL S, et al. Interfacial phenomena in thermally sprayed multiwalled carbon nanotube reinforced aluminum nanocomposite[J]. Acta Materialia, 2007, 55(3): 1059-1066.
【9】ANDREWS R, WEISENBERGER M. Carbon nanotube polymer composites[J]. Current Opinion in Solid State and Materials Science, 2004, 8(1): 31-37.
【10】DESAI A, HAQUE M. Mechanics of the interface for carbon nanotube-polymer composites[J]. Thin-Walled Structures, 2005, 43(11): 1787-1803.
【11】MIRACLE D B, DONALDSON S L, HENRY S D, et al. ASM handbook[M]. OH: ASM International Materials Park, 2001.
【12】RODRIGUEZ-REYES M, PECH-CANUL M, PARGA-TORRES J, et al. Development of aluminum hydroxides in Al-Mg-Si/SiCp in infiltrated composites exposed to moist air[J]. Ceramics International, 2011, 37(7): 2719-2722.
【13】POIRIER D, GAUVIN R, DREW R A. Structural characterization of a mechanically milled carbon nanotube/aluminum mixture[J]. Composites Part A: Applied Science and Manufacturing, 2009, 40(9): 1482-1489.
【14】YAN L, TAN Z, JI G, et al. A quantitative method to characterize the Al4C3-formed interfacial reaction: The case study of MWCNT/Al composites[J]. Materials Characterization, 2016, 112: 213-218.
【15】HIHARA L. Corrosion of aluminium-matrix composites[J]. Corrosion Reviews, 1997, 15(3/4): 361-386.
【16】RAYMUNDO-PINERO E, AZAIS P, CACCIAGUERRA T, et al. KOH and NaOH activation mechanisms of multiwalled carbon nanotubes with different structural organisation[J]. Carbon, 2005, 43: 786-795.
【17】ZHOU W, BANG S, KURITA H, et al. Interface and interfacial reactions in multi-walled carbon nanotube-reinforced aluminum matrix composites[J]. Carbon, 2016, 96: 919-928.
【18】LIU Z, XU S, XIAO B, et al. Effect of ball-milling time on mechanical properties of carbon nanotubes reinforced aluminum matrix composites[J]. Composites Part A: Applied Science and Manufacturing, 2012, 43(12): 2161-2168.
【19】CHEN B, KONDOH K, IMAI H, et al. Simultaneously enhancing strength and ductility of carbon nanotube/aluminum composites by improving bonding conditions[J]. Scripta Materialia, 2016, 113: 158-162.
【2】BAKSHI S R, KESHRI A K, SINGH V, et al. Interface in carbon nanotube reinforced aluminum silicon composites: thermodynamic analysis and experimental verification[J]. Journal of Alloys and Compounds, 2009, 481(1): 207-213.
【3】CHU K, JIA C C, JIANG L K, et al. Improvement of interface and mechanical properties in carbon nanotube reinforced Cu-Cr matrix composites[J]. Materials & Design, 2013, 45: 407-411.
【4】DENG C, WANG D, ZHANG X, et al. Processing and properties of carbon nanotubes reinforced aluminum composites[J]. Materials Science and Engineering: A, 2007, 444(1): 138-145.
【5】HE C, ZHAO N, SHI C, et al. An approach to obtaining homogeneously dispersed carbon nanotubes in Al powders for preparing reinforced Al-matrix composites[J]. Advanced Materials, 2007, 19(8): 1128-1132.
【6】HWANG J, LIM B, TILEY J, et al. Interface analysis of ultra-high strength carbon nanotube/nickel composites processed by molecular level mixing[J]. Carbon, 2013, 57: 282-287.
【7】BAKSHI S R, AGARWAL A. An analysis of the factors affecting strengthening in carbon nanotube reinforced aluminum composites[J]. Carbon, 2011, 49: 533-544.
【8】LAHA T, KUCHIBHATLA S, SEAL S, et al. Interfacial phenomena in thermally sprayed multiwalled carbon nanotube reinforced aluminum nanocomposite[J]. Acta Materialia, 2007, 55(3): 1059-1066.
【9】ANDREWS R, WEISENBERGER M. Carbon nanotube polymer composites[J]. Current Opinion in Solid State and Materials Science, 2004, 8(1): 31-37.
【10】DESAI A, HAQUE M. Mechanics of the interface for carbon nanotube-polymer composites[J]. Thin-Walled Structures, 2005, 43(11): 1787-1803.
【11】MIRACLE D B, DONALDSON S L, HENRY S D, et al. ASM handbook[M]. OH: ASM International Materials Park, 2001.
【12】RODRIGUEZ-REYES M, PECH-CANUL M, PARGA-TORRES J, et al. Development of aluminum hydroxides in Al-Mg-Si/SiCp in infiltrated composites exposed to moist air[J]. Ceramics International, 2011, 37(7): 2719-2722.
【13】POIRIER D, GAUVIN R, DREW R A. Structural characterization of a mechanically milled carbon nanotube/aluminum mixture[J]. Composites Part A: Applied Science and Manufacturing, 2009, 40(9): 1482-1489.
【14】YAN L, TAN Z, JI G, et al. A quantitative method to characterize the Al4C3-formed interfacial reaction: The case study of MWCNT/Al composites[J]. Materials Characterization, 2016, 112: 213-218.
【15】HIHARA L. Corrosion of aluminium-matrix composites[J]. Corrosion Reviews, 1997, 15(3/4): 361-386.
【16】RAYMUNDO-PINERO E, AZAIS P, CACCIAGUERRA T, et al. KOH and NaOH activation mechanisms of multiwalled carbon nanotubes with different structural organisation[J]. Carbon, 2005, 43: 786-795.
【17】ZHOU W, BANG S, KURITA H, et al. Interface and interfacial reactions in multi-walled carbon nanotube-reinforced aluminum matrix composites[J]. Carbon, 2016, 96: 919-928.
【18】LIU Z, XU S, XIAO B, et al. Effect of ball-milling time on mechanical properties of carbon nanotubes reinforced aluminum matrix composites[J]. Composites Part A: Applied Science and Manufacturing, 2012, 43(12): 2161-2168.
【19】CHEN B, KONDOH K, IMAI H, et al. Simultaneously enhancing strength and ductility of carbon nanotube/aluminum composites by improving bonding conditions[J]. Scripta Materialia, 2016, 113: 158-162.
相关信息
