Preparation and Corrosion Resistance of Ni/Cu/Zn Multilayer Coating
摘 要
采用电沉积法在低碳钢基体上制备了镍/铜/锌多层镀层。采用扫描电镜观察镍/铜/锌多层镀层的微观结构;通过盐水(NaCl质量分数为5%)浸泡试验对制得的镍/铜/锌多层镀层进行耐蚀性评价;利用电化学阻抗谱(EIS)技术测试镍/铜/锌多层镀层在5% NaCl(质量分数)溶液中的电化学性能。结果表明:底层镍镀层颗粒以四角锥型交错堆积,中间层铜镀层颗粒以圆胞型结构沉积,表层锌镀层的表面平整致密,无明显孔隙;镍/铜/锌多层镀层具有较好的耐蚀性,电化学阻抗达到了5 623 Ω·cm2,耐盐水浸泡时间可达2 880 h时,是相同厚度单一镀层耐盐水浸泡时间的5~8倍。
Abstract
Ni/Cu/Zn multilayer coating was prepared on low carbon steel substrate by electrodeposition. The microstructure of the Ni/Cu/Zn multilayer coating was observed by scanning electron microscopy (SEM). The corrosion resistance of the Ni/Cu/Zn multilayer coating was evaluated by the brine immersion testing in which NaCl mass fraction was 5%. The electrochemical properties of Ni/Cu/Zn multilayer coating in 5.0% (mass) NaCl solution were measured by electrochemical impedance spectroscopy (EIS) technique. The results show that:the particles in the under layer of nickel were stacked interlacedly as four pyramid type, the particles in the middle layer of copper were deposited by round cell structure, and the surface layer of zinc was flat and compact without apparent pores. The Ni/Cu/Zn multilayer coating exhibited good corrosion resistance, showing a value of electrochemical impedance of 5 623 Ω·cm2. The immersion time of red rust spot occurring on the coating surface in brine reached 2 880 h which was 5-8 times of that for single layer coating with the same thickness.
中图分类号 TG174.4 DOI 10.11973/fsyfh-201712006
所属栏目 试验研究
基金项目 南通市产学研协同创新计划项目(BC2014010);上海市钢铁冶金新技术开发应用重点实验室开放课题基金资助(SELF-2015-01)
收稿日期 2016/4/6
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引用该论文: SUN Jinhu,LI Hui,ZHONG Qingdong,HUANG Zherui,LI Yulin. Preparation and Corrosion Resistance of Ni/Cu/Zn Multilayer Coating[J]. Corrosion & Protection, 2017, 38(12): 928
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参考文献
【1】田伟,谢发勤,吴向清. 锌镍合金镀层耐蚀性研究[J]. 腐蚀与防护,2006,27(11):552-554.
【2】JIANG Y F,LIU L F,ZHAI C Q,et al. Corrosion behavior of pulse plated Zn-Ni alloy coatings on AZ91 magnesium-alloy in alkaline solutions[J]. Thin Solid Films,2005,484:232-237.
【3】ZHAI L L,LIU X J,LI T Q,et al. Vacuum and ultrasonic co-assisted electroless copper plating on carbon foams[J]. Vacuum,2015,114:21-25.
【4】ZHANG W Y,WANG S J,LI J G,et al. Photocatalytic hydrogen production from methanol aqueous solution under visible-light using Cu/S-TiO2 prepared by electroless plating method[J]. Catalysis Communications,2015,59:189-194.
【5】KAN H M,YANG Z Y,ZHANG N. Preparation of Ni-SiC composite coating by electrochemical deposition[J]. Rare Metal Materials and Engineering,2015,44(12):2960-2964.
【6】杜朝军,李欣玲,杨家祥,等. 电沉积铜-镍-锡-聚四氟乙烯复合镀层及其性能[J]. 电镀与涂饰,2015,34(24):1391-1394.
【7】FEI J Y,WILCOX G D. Electrodeposition of zinc-nickel compositionally modulated multilayer coatings and their corrosion behaviours[J]. Surface & Coatings Technology,2006,200(11):3533-3539.
【8】SHAO A L,CHENG Y,ZHOU Y,et al. Electrochemistry properties of multilayer TiN/Ti coatings on NiTi alloy for cardia occlude application[J]. Surface & Coatings Technology,2013,228:257-261.
【9】WANG H,XIE G Y,YING Z,et al. Enhanced mechanical properties of multi-layer graphene filled poly(vinyl chloride) composite films[J]. Journal of Materials Science & Technology,2015,31:340-344.
【10】YI P Y,PENG L F,HUANG J Q. Multilayered TiAlN films on Ti6Al4V alloy for biomedical applications by closed field unbalanced magnetron sputter ion plating process[J]. Materials Science and Engineering:C,2016,59(2):669-676.
【11】ZHANG C,LI Y P,HOU Y H,et al. Corrosion resistance of Cu and Fe modified Ni-30Co-16Cr-15Mo alloy in aqueous hydrofluoric acid[J]. Corrosion Science,2014,89(89):81-92.
【12】SOSIATI H,HATA S,DOI T,et al. Nanostructure characterization of Ni and B layers as artificial pinning centers in multilayered MgB2/Ni and MgB2/B superconducting thin films[J]. Physica C:Superconductivity,2013,488:1-8.
【13】SUN H K,DONG J Y,HWANG S T,et al. Investigation on growth behavior of multiphase silicon carbon film for front contact layer in a Si thin film solar cell[J]. Solar Energy Materials & Solar Cells,2014,127(4):98-103.
【14】DU X,ZHAO L,CHEN H,et al. Synthesis and properties of multilayered films foams[J]. Colloids & Surfaces A:Physicochemical & Engineering Aspects,2013,436(35):599-603.
【15】MU W N,ZHAI Y C,SHI S Z. Preparation,formation mechanism and mechanical properties of multilayered TiO2-organic nanocomposite film[J]. Transactions of Nonferrous Metals Society of China,2015,25(4):1128-1134.
【16】ZHOU Q,LI J J,WANG F,et al. Strain rate sensitivity of Cu/Ta multilayered films:comparison between grain boundary and heterophase interface[J]. Scripta Materialia,2016,111:123-126.
【17】LU Y,LI Y,SAKA M. Growth of Ag micro/nanoparticles using stress migration from multilayered metallic structure[J]. Applied Surface Science,2015,351:1011-1015.
【18】过家驹,郭乃名. Al-Mn合金镀层的组成结构及其耐蚀性[J]. 电化学,1995,1(4):451-455.
【2】JIANG Y F,LIU L F,ZHAI C Q,et al. Corrosion behavior of pulse plated Zn-Ni alloy coatings on AZ91 magnesium-alloy in alkaline solutions[J]. Thin Solid Films,2005,484:232-237.
【3】ZHAI L L,LIU X J,LI T Q,et al. Vacuum and ultrasonic co-assisted electroless copper plating on carbon foams[J]. Vacuum,2015,114:21-25.
【4】ZHANG W Y,WANG S J,LI J G,et al. Photocatalytic hydrogen production from methanol aqueous solution under visible-light using Cu/S-TiO2 prepared by electroless plating method[J]. Catalysis Communications,2015,59:189-194.
【5】KAN H M,YANG Z Y,ZHANG N. Preparation of Ni-SiC composite coating by electrochemical deposition[J]. Rare Metal Materials and Engineering,2015,44(12):2960-2964.
【6】杜朝军,李欣玲,杨家祥,等. 电沉积铜-镍-锡-聚四氟乙烯复合镀层及其性能[J]. 电镀与涂饰,2015,34(24):1391-1394.
【7】FEI J Y,WILCOX G D. Electrodeposition of zinc-nickel compositionally modulated multilayer coatings and their corrosion behaviours[J]. Surface & Coatings Technology,2006,200(11):3533-3539.
【8】SHAO A L,CHENG Y,ZHOU Y,et al. Electrochemistry properties of multilayer TiN/Ti coatings on NiTi alloy for cardia occlude application[J]. Surface & Coatings Technology,2013,228:257-261.
【9】WANG H,XIE G Y,YING Z,et al. Enhanced mechanical properties of multi-layer graphene filled poly(vinyl chloride) composite films[J]. Journal of Materials Science & Technology,2015,31:340-344.
【10】YI P Y,PENG L F,HUANG J Q. Multilayered TiAlN films on Ti6Al4V alloy for biomedical applications by closed field unbalanced magnetron sputter ion plating process[J]. Materials Science and Engineering:C,2016,59(2):669-676.
【11】ZHANG C,LI Y P,HOU Y H,et al. Corrosion resistance of Cu and Fe modified Ni-30Co-16Cr-15Mo alloy in aqueous hydrofluoric acid[J]. Corrosion Science,2014,89(89):81-92.
【12】SOSIATI H,HATA S,DOI T,et al. Nanostructure characterization of Ni and B layers as artificial pinning centers in multilayered MgB2/Ni and MgB2/B superconducting thin films[J]. Physica C:Superconductivity,2013,488:1-8.
【13】SUN H K,DONG J Y,HWANG S T,et al. Investigation on growth behavior of multiphase silicon carbon film for front contact layer in a Si thin film solar cell[J]. Solar Energy Materials & Solar Cells,2014,127(4):98-103.
【14】DU X,ZHAO L,CHEN H,et al. Synthesis and properties of multilayered films foams[J]. Colloids & Surfaces A:Physicochemical & Engineering Aspects,2013,436(35):599-603.
【15】MU W N,ZHAI Y C,SHI S Z. Preparation,formation mechanism and mechanical properties of multilayered TiO2-organic nanocomposite film[J]. Transactions of Nonferrous Metals Society of China,2015,25(4):1128-1134.
【16】ZHOU Q,LI J J,WANG F,et al. Strain rate sensitivity of Cu/Ta multilayered films:comparison between grain boundary and heterophase interface[J]. Scripta Materialia,2016,111:123-126.
【17】LU Y,LI Y,SAKA M. Growth of Ag micro/nanoparticles using stress migration from multilayered metallic structure[J]. Applied Surface Science,2015,351:1011-1015.
【18】过家驹,郭乃名. Al-Mn合金镀层的组成结构及其耐蚀性[J]. 电化学,1995,1(4):451-455.
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