钢筋阻锈剂的阻锈机理及性能评价的研究进展
Research Progress of Anti-Corrosion Mechanism and Performance Evaluation of Corrosion Inhibitor for Steel Bar
摘 要
钢筋腐蚀是引起钢筋混凝土构筑物提前失效的主要因素，应用钢筋阻锈剂是主要的防腐蚀措施之一。重点介绍了海洋环境中，氯盐的侵蚀机理和阻锈剂的作用机理；讨论了阻锈剂的性能评价方法和应用现状；指出高效且环境友好复合型阻锈剂的合成是今后研究的主要方向，这对于提高我国钢筋混凝土结构耐久性具有重要意义。
锈蚀
阻锈机理
性能评价
研究进展
steel bar
corrosion
anti-corrosion mechanism
performance evaluation
research progress
Abstract
The main factor causing the failure of reinforced concrete structures in advance is the corrosion of steel bar. Using corrosion inhibitor is one of the main methods to prevent corrosion. The mechanism of chloride induced corrosion in marine environment and the effect mechanism of inhibitors are mainly introduced. And the evaluation methods of inhibiting performance and application situation of corrosion inhibitor are discussed. It is pointed out that synthesis of highly efficient and environment friendly mixed inhibitors is the main research directions in the future, which is of great significance to enhance the durability of reinforced concrete structures in our country.
中图分类号 TG174 DOI 10.11973/fsyfh-201712013
所属栏目 专论
基金项目 国家863计划（2015AA034404）；黄岛区海洋科技专项（2014-04-1）
收稿日期 2016/5/18
修改稿日期
网络出版日期
作者单位点击查看
引用该论文: MA Shihao,LI Weihua,ZHENG Haibing,JI Tao. Research Progress of Anti-Corrosion Mechanism and Performance Evaluation of Corrosion Inhibitor for Steel Bar[J]. Corrosion & Protection, 2017, 38(12): 963
共有人对该论文发表了看法，其中：
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】ORMELLESE M,BERRA M,BOLZONI F,et al. Corrosion inhibitors for chlorides induced corrosion in reinforced concrete structures[J]. Cement and Concrete Research,2006,36(3):536-547.
【2】GARCES P,SAURA P,ZORNOZA E,et al. Influence of pH on the nitrite corrosion inhibition of reinforcing steel in simulated concrete pore solution[J]. Corrosion Science,2011(53):3991-3994.
【3】WEI J,DONG J,KE W. Corrosion resistant performance of a chemical quenched rebar in concrete[J]. Construction and Building Materials,2011,25:1243-1247.
【4】杨建森. 氯盐对混凝土中钢筋的腐蚀机理与防腐技术[J]. 混凝土,2001,141(7):52-53.
【5】GAIDIS J M. Chemistry of corrosion inhibitors[J]. Cement and Concrete Composites,2004,26:1775-1781.
【6】TULLIN M A A. Electrochemical techniques for measuring reinforcing steel corrosion[M].[S.l.]:[s.n.],1998.
【7】李伟华,菲长岭,何桥,等. 混凝土中钢筋腐蚀与钢筋阻锈剂[J]. 材料开发与应用,2007,22(5):57-60.
【8】徐永膜. 迁移性阻锈剂——钢筋混凝土阻锈剂的新发展[J]. 硅酸盐学报,2002,30(1):94-101.
【9】张天胜,张浩,高红. 缓蚀剂[M]. 北京:化学工业出版社,2008:5-12.
【10】VAYSBURD A M,EMMONS P H. Corrosion inhibitors and other protective systems in concrete repair:concepts or misconcepts[J]. Cement and Concrete Composites,2004,26(3):255-263.
【11】马新伟,邙静喆,范征宇. 钢筋阻锈剂的新发展[J]. 低温建筑技术,2004(6):7-8.
【12】SOEDA K,ICHIMURA T. Present state of corrosion inhibitors in Japan[J]. Cement & Concrete Composites,2003(25):117-122.
【13】ES-SALAH K,KEDDAM M,RAHMOUNI K,et al. Aminotriazole as corrosion inhibitor of Cu30Ni alloy in 3% NaCl in presence of ammoniac[J]. Electrochimica Acta,2004,49(17/18):2771-2778.
【14】孙俊,刘彦东,王建成. 有机钢筋混凝土阻锈剂的研究[J]. 混凝土,2010(2):6-7.
【15】CHAUSSADENT T. Effectiveness conditions of sodium monofluor phosphate as a corrosion inhibitor for concrete reinforcements[J]. Cement and Concrete Research,2006(36):556-561.
【16】刘志勇,缪昌文,周伟玲,等. 迁移性阻锈剂对混凝土结构耐久性的保持和提升作用[J]. 硅酸盐学报,2008,36(10):1495-1496.
【17】张前前,孙伟,刘加平. 混凝土模拟液中临界氯离子浓度影响因素分析[J]. 东南大学学报(自然科学版),2010,40(S2):177-181.
【18】陈品龙,杨医博,黄威,等. 钢筋阻锈剂阻锈性能评价方法研究进展[J]. 广东建材:2012(1):17-18.
【19】LABJAR N,LEBRINI M,BENISS F,et al. Corrosion inhibition of carbon steel and antibacterial properties of aminotris-(methylenephosphonic) acid[J]. Materials Chemistry and Physics,2010,119:330-336.
【20】AMIN M A,IBRAHIM M M. Corrosion and corrosion control of mild steel in concentrated H2SO4 solutions by a newly synthesized glycine derivative[J]. Corrosion Science,2011,53:875-885.
【21】ANSARI K R,QURAISHI M A,SINGH A. Schiff's base of pyridyl substituted triazoles as new and effective corrosion inhibitors for mild steel in hydrochloric acid solution[J]. Corrosion Science,2014,79:5-15.
【22】MOURYA P,SINGH P,TEWARI A K,et al. Relationship between structure and inhibition behaviour of quinolinium salts for mild steel corrosion:experimental and theoretical approach[J]. Corrosion Science,2015,95:71-87.
【23】穆振军,杜敏. 天然海水中高效缓蚀剂对碳钢缓蚀作用的研究[J]. 中国腐蚀与防护学报,2005,25(4):205-208.
【24】刘建平,李正奉,周晓湘. 一种咪唑啉缓蚀剂在碳钢表面成膜的电化学研究[J]. 腐蚀科学与防护技术,2003,15(5):263-265.
【25】赵永韬,吴建华,于辉. 交流阻抗法研究膜层的形成和破损(I)-缓蚀剂膜层的EIS变化[J]. 四川化工与腐蚀控制,1999,2(4):14-17.
【26】陈飞,解利昕,孙晨,等. 动电位极化曲线法研究铝合金材料在海水中腐蚀现象[J]. 天津化工,2014,28(5):12-13.
【27】陈舒恬,马文亮,王珏. 采用极化曲线法研究GH4700合金的耐蚀性[J]. 现代冶金,2015,43(1):7-8.
【28】HANSSON C M,MAMMOLITI L,HOPE B B. Corrosion inhibitors in concrete-part I:the principles[J]. Cement and Concrete Research,1998,28(12):1775-1781.
【29】王佳,曹楚南,陈家坚. 缓蚀剂理论与研究方法的进展[J]. 腐蚀科学与防护技术,1992,14(2):80-87.
【30】屈钧娥. 缓蚀剂界面行为与缓蚀机理的电化学及AFM研究[D]. 武汉:华中科技大学,2005.
【31】CHENG P F,LUO J I. Passivity and pitting of carbon steel in chromate solutions[J]. Electrochimica Acta,1999,44(26):4795.
【32】宋诗哲,尹立辉,武杰,等. 模拟循环冷却系统黄铜管的腐蚀电化学[J]. 化工学报,2005,56(1):121.
【33】LEGAT A,LEBAN M,BAJT Z. Corrosion processes of steel in concrete characterized by means of electrochemical noise[J]. Electrochimica Acta,2004,49(17/18):2741-2751.
【34】潘崇根,杨小草,徐强,等. 阻锈剂在海洋工程高性能混凝土中的研究进展[J]. 材料导报,2013,21(11):99-100.
【35】CHEN J J,JIA X,SHE Q J,et al. Preparation of nano-sulfur/MWCNTs and its electrochemical performance[J]. Electrochimica Acta,2010,55(27):8062-8066.
【2】GARCES P,SAURA P,ZORNOZA E,et al. Influence of pH on the nitrite corrosion inhibition of reinforcing steel in simulated concrete pore solution[J]. Corrosion Science,2011(53):3991-3994.
【3】WEI J,DONG J,KE W. Corrosion resistant performance of a chemical quenched rebar in concrete[J]. Construction and Building Materials,2011,25:1243-1247.
【4】杨建森. 氯盐对混凝土中钢筋的腐蚀机理与防腐技术[J]. 混凝土,2001,141(7):52-53.
【5】GAIDIS J M. Chemistry of corrosion inhibitors[J]. Cement and Concrete Composites,2004,26:1775-1781.
【6】TULLIN M A A. Electrochemical techniques for measuring reinforcing steel corrosion[M].[S.l.]:[s.n.],1998.
【7】李伟华,菲长岭,何桥,等. 混凝土中钢筋腐蚀与钢筋阻锈剂[J]. 材料开发与应用,2007,22(5):57-60.
【8】徐永膜. 迁移性阻锈剂——钢筋混凝土阻锈剂的新发展[J]. 硅酸盐学报,2002,30(1):94-101.
【9】张天胜,张浩,高红. 缓蚀剂[M]. 北京:化学工业出版社,2008:5-12.
【10】VAYSBURD A M,EMMONS P H. Corrosion inhibitors and other protective systems in concrete repair:concepts or misconcepts[J]. Cement and Concrete Composites,2004,26(3):255-263.
【11】马新伟,邙静喆,范征宇. 钢筋阻锈剂的新发展[J]. 低温建筑技术,2004(6):7-8.
【12】SOEDA K,ICHIMURA T. Present state of corrosion inhibitors in Japan[J]. Cement & Concrete Composites,2003(25):117-122.
【13】ES-SALAH K,KEDDAM M,RAHMOUNI K,et al. Aminotriazole as corrosion inhibitor of Cu30Ni alloy in 3% NaCl in presence of ammoniac[J]. Electrochimica Acta,2004,49(17/18):2771-2778.
【14】孙俊,刘彦东,王建成. 有机钢筋混凝土阻锈剂的研究[J]. 混凝土,2010(2):6-7.
【15】CHAUSSADENT T. Effectiveness conditions of sodium monofluor phosphate as a corrosion inhibitor for concrete reinforcements[J]. Cement and Concrete Research,2006(36):556-561.
【16】刘志勇,缪昌文,周伟玲,等. 迁移性阻锈剂对混凝土结构耐久性的保持和提升作用[J]. 硅酸盐学报,2008,36(10):1495-1496.
【17】张前前,孙伟,刘加平. 混凝土模拟液中临界氯离子浓度影响因素分析[J]. 东南大学学报(自然科学版),2010,40(S2):177-181.
【18】陈品龙,杨医博,黄威,等. 钢筋阻锈剂阻锈性能评价方法研究进展[J]. 广东建材:2012(1):17-18.
【19】LABJAR N,LEBRINI M,BENISS F,et al. Corrosion inhibition of carbon steel and antibacterial properties of aminotris-(methylenephosphonic) acid[J]. Materials Chemistry and Physics,2010,119:330-336.
【20】AMIN M A,IBRAHIM M M. Corrosion and corrosion control of mild steel in concentrated H2SO4 solutions by a newly synthesized glycine derivative[J]. Corrosion Science,2011,53:875-885.
【21】ANSARI K R,QURAISHI M A,SINGH A. Schiff's base of pyridyl substituted triazoles as new and effective corrosion inhibitors for mild steel in hydrochloric acid solution[J]. Corrosion Science,2014,79:5-15.
【22】MOURYA P,SINGH P,TEWARI A K,et al. Relationship between structure and inhibition behaviour of quinolinium salts for mild steel corrosion:experimental and theoretical approach[J]. Corrosion Science,2015,95:71-87.
【23】穆振军,杜敏. 天然海水中高效缓蚀剂对碳钢缓蚀作用的研究[J]. 中国腐蚀与防护学报,2005,25(4):205-208.
【24】刘建平,李正奉,周晓湘. 一种咪唑啉缓蚀剂在碳钢表面成膜的电化学研究[J]. 腐蚀科学与防护技术,2003,15(5):263-265.
【25】赵永韬,吴建华,于辉. 交流阻抗法研究膜层的形成和破损(I)-缓蚀剂膜层的EIS变化[J]. 四川化工与腐蚀控制,1999,2(4):14-17.
【26】陈飞,解利昕,孙晨,等. 动电位极化曲线法研究铝合金材料在海水中腐蚀现象[J]. 天津化工,2014,28(5):12-13.
【27】陈舒恬,马文亮,王珏. 采用极化曲线法研究GH4700合金的耐蚀性[J]. 现代冶金,2015,43(1):7-8.
【28】HANSSON C M,MAMMOLITI L,HOPE B B. Corrosion inhibitors in concrete-part I:the principles[J]. Cement and Concrete Research,1998,28(12):1775-1781.
【29】王佳,曹楚南,陈家坚. 缓蚀剂理论与研究方法的进展[J]. 腐蚀科学与防护技术,1992,14(2):80-87.
【30】屈钧娥. 缓蚀剂界面行为与缓蚀机理的电化学及AFM研究[D]. 武汉:华中科技大学,2005.
【31】CHENG P F,LUO J I. Passivity and pitting of carbon steel in chromate solutions[J]. Electrochimica Acta,1999,44(26):4795.
【32】宋诗哲,尹立辉,武杰,等. 模拟循环冷却系统黄铜管的腐蚀电化学[J]. 化工学报,2005,56(1):121.
【33】LEGAT A,LEBAN M,BAJT Z. Corrosion processes of steel in concrete characterized by means of electrochemical noise[J]. Electrochimica Acta,2004,49(17/18):2741-2751.
【34】潘崇根,杨小草,徐强,等. 阻锈剂在海洋工程高性能混凝土中的研究进展[J]. 材料导报,2013,21(11):99-100.
【35】CHEN J J,JIA X,SHE Q J,et al. Preparation of nano-sulfur/MWCNTs and its electrochemical performance[J]. Electrochimica Acta,2010,55(27):8062-8066.
相关信息
