Incoloy800H合金在高温纯水蒸气中的氧化行为
Oxidation Behaviour of Incoloy800H Alloy in High-Temperature Pure Steam
摘 要
采用不连续称重法、X射线衍射及扫描电子显微镜等研究了Incoloy800H合金在750℃和850℃纯水蒸气中的氧化行为。结果表明：试验合金的氧化动力学近似遵循抛物线规律，温度升高后其氧化急剧加速；在750℃蒸汽中氧化后，试验合金表面形成以（Cr，Mn）2O3为主的氧化膜，其上分布着不连续呈突起状的Fe3O4，在氧化膜下方基体中的铬被内氧化为Cr2O3；在850℃蒸汽中氧化后，试验合金表面形成双层氧化膜，外层为薄的（Fe，Mn）3O4，内层为厚的（Cr，Mn）2O3，氧化膜下方基体中的铝沿晶界发生内氧化生成Al2O3。
高温水蒸气
氧化行为
氧化膜
Incoloy800H alloy
high-temperature steam
oxidation behaviour
oxide layer
Abstract
The oxidation behaviour of Incoloy800H alloy in 750℃ and 850℃ pure steam was investigated by discontinuous weighing method, X-ray diffraction, and scanning electron microscopy. The results show that the oxidation kinetics of the tested alloy followed a parabolic law; the oxidation accelerated rapidly with rising temperature. After oxidation in 750℃ steam, an oxide layer mainly composed of (Cr, Mn)2O3 was formed on the surface of the tested alloy, discontinuous bulgy Fe3O4 was distributed on the oxide layer and Cr in the matrix under the oxide layer was oxidized internally to Cr2O3. After oxidation in 850℃ steam, a duplex oxide layer, composed of a thin outer layer of (Fe, Mn)3O4 and a thick inner layer of (Cr, Mn)2O3, was formed on the surface of the tested alloy; beneath the oxide layer, Al was oxidized inernally to Al2O3 along grain boundaries in the matrix.
中图分类号 TG172.81 DOI 10.11973/jxgccl201801001
所属栏目 试验研究
基金项目 国家自然科学基金资助项目（51401163）
收稿日期 2016/12/13
修改稿日期 2017/8/24
网络出版日期
作者单位点击查看
备注杨珍(1985-),女,河南驻马店人,高级工程师,博士
引用该论文: YANG Zhen,LU Jintao,LE Ming,ZHOU Yongli,LI Hao,YUAN Yong. Oxidation Behaviour of Incoloy800H Alloy in High-Temperature Pure Steam[J]. Materials for mechancial engineering, 2018, 42(1): 1～6
杨珍,鲁金涛,乐明,周永莉,李浩,袁勇. Incoloy800H合金在高温纯水蒸气中的氧化行为[J]. 机械工程材料, 2018, 42(1): 1～6
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参考文献
【1】尹清辽,孙玉良,居怀明,等. 模块式高温气冷堆超临界蒸汽发生器设计[J]. 原子能科学技术,2006,40(6):707-713.
【2】FULGER M, OHAI D, MIHALACHE M, et al. Oxidation behavior of Incoloy 800 under simulated supercritical water conditions[J]. Journal of Nuclear Materials, 2009, 385(2):288-293.
【3】TAN L, ALLEN T R, YANG Y. Corrosion behavior of alloy 800H (Fe-21Cr-32Ni) in supercritical water[J]. Corrosion Science, 2011, 53(2):703-711.
【4】OTSUKA N, FUJIKAWA H. Scaling of austenitic stainless steels and nickel-base alloys in high-temperature steam at 973 K[J]. Corrosion, 1991, 47(4):240-248.
【5】TAN L, REN X, SRIDHARAN K, et al. Effect of shot-peening on the oxidation of alloy 800H exposed to supercritical water and cyclic oxidation[J]. Corrosion Science, 2008, 50(7):2040-2046.
【6】TAN L, SRIDHARAN K, ALLEN T R. The effect of grain boundary engineering on the oxidation behavior of INCOLOY alloy 800H in supercritical water[J]. Journal of Nuclear Materials, 2006, 348(3):263-271.
【7】TAN L,SRIDHARAN K,ALLEN T R,et al.Microstructure tailoring for property improvements by grain boundary engineering[J]. Journal of Nuclear Materials, 2008, 374(1/2):270-280.
【8】CHEN W S, KAI W, TSAY L W, et al. The oxidation behavior of three different zones of welded Incoloy 800H alloy[J]. Nuclear Engineering and Design, 2014, 272:92-98.
【9】杨珍,鲁金涛,赵新宝,等. HR3C在750℃空气和水蒸气中的高温氧化行为研究[J]. 动力工程学报,2015,35(10):859-864.
【10】TALLMAN R L, GULBRANSEN E A. Dislocation and grain boundary diffusion in the growth of α-Fe2O3 whiskers and twinned platelets peculiar to gaseous oxidation[J]. Nature, 1968, 218:1046-1047.
【11】VOSS D A, BUTLER E P, MITCHELL T E. The growth of hematite blades during the high temperature oxidation of iron[J]. Metallurgical Transactions A, 1982, 13(5):929-935.
【12】RAYNAUD G, RAPP R. In situ observation of whiskers, pyramids and pits during the high-temperature oxidation of metals[J]. Oxidation of Metals, 1984, 21(1/2):89-102.
【13】LIMOGE Y, BOCQUET J L. Selfdiffusion and point defects in iron oxides FeO, Fe3O4, α-Fe2O3[J]. Defect and Diffusion Forum, 2001, 194:1051-1056.
【14】HAGEL W C, SEYBOLT A U. Cation diffusion in Cr2O3[J]. Journal of the Electrochemical Society, 1961, 108(12):1146-1152.
【15】HAGEL W C. Anion diffusion in α-Cr2O3[J]. Journal of the American Ceramic Society, 1965, 48(2):70-75.
【16】JUTTE R H, KOOI B J, SOMERS M A, et al. On the oxidation of α-Fe and ε-FeFe2N1-z:I. Oxidation kinetics and microstructural evolution of the oxide and nitride layers[J]. Oxidation of Metals, 1997, 48(1/2):87-109.
【17】STOTT F, WEI F. High temperature oxidation of commercial austenitic stainless steels[J]. Materials Science and Technology, 1989, 5(11):1140-1147.
【18】KOFSTAD P K. Nonstoichiometry, diffusion and electrical conductivity in binary metal oxides[M]. New York:Wiley-Interscience, 1972.
【19】KOFSTAD P, LILLERUD K. Chromium transport through Cr2O3 scales I. On lattice diffusion of chromium[J]. Oxidation of Metals, 1982, 17(3/4):177-194.
【20】GRESKOVICH C. Deviation from stoichiometry in Cr2O3 at high oxygen partial pressures[J]. Journal of the American Ceramic Society, 1984, 67(6):C111-C112.
【21】LOBNIG R E, SCHMIDT H P, HENNESEN K, et al. Diffusion of cations in chromia layers grown on iron-base alloys[J]. Oxidation of Metals, 1992, 37(1/2):81-93.
【22】WAGNER C. Reaktionstypen bei der oxydation von legierungen[J].Berichte der Bunsengesellschaft für Physikalische Chemie, 1959, 63(7):772-782.
【23】WAGNER C. Theoretical analysis of the diffusion processes determining the oxidation rate of alloys[J]. Journal of the Electrochemical Society, 1952, 99(10):369-380.
【24】SUZUOKA T. Lattice and grain boundary diffusion in polycrystals[J]. Transactions of Japan Institute of Metals, 1961, 2:25-33.
【25】LAFLAMME G R,MORRAL J E. Limiting cases of subscale formation[J].Acta Metallurgica, 1978, 26(12):1791-1794.
【26】KAMPMANN L, KAHLWEIT M. Zur theorie von fällungen[J]. Berichte der Bunsengesellschaft für Physikalische Chemie, 1970, 74(5):456-462.
【27】WAGNER C. Mathematical analysis of the formation of periodic precipitations[J]. Journal of Colloid Science, 1950, 51(1):85-97.
【2】FULGER M, OHAI D, MIHALACHE M, et al. Oxidation behavior of Incoloy 800 under simulated supercritical water conditions[J]. Journal of Nuclear Materials, 2009, 385(2):288-293.
【3】TAN L, ALLEN T R, YANG Y. Corrosion behavior of alloy 800H (Fe-21Cr-32Ni) in supercritical water[J]. Corrosion Science, 2011, 53(2):703-711.
【4】OTSUKA N, FUJIKAWA H. Scaling of austenitic stainless steels and nickel-base alloys in high-temperature steam at 973 K[J]. Corrosion, 1991, 47(4):240-248.
【5】TAN L, REN X, SRIDHARAN K, et al. Effect of shot-peening on the oxidation of alloy 800H exposed to supercritical water and cyclic oxidation[J]. Corrosion Science, 2008, 50(7):2040-2046.
【6】TAN L, SRIDHARAN K, ALLEN T R. The effect of grain boundary engineering on the oxidation behavior of INCOLOY alloy 800H in supercritical water[J]. Journal of Nuclear Materials, 2006, 348(3):263-271.
【7】TAN L,SRIDHARAN K,ALLEN T R,et al.Microstructure tailoring for property improvements by grain boundary engineering[J]. Journal of Nuclear Materials, 2008, 374(1/2):270-280.
【8】CHEN W S, KAI W, TSAY L W, et al. The oxidation behavior of three different zones of welded Incoloy 800H alloy[J]. Nuclear Engineering and Design, 2014, 272:92-98.
【9】杨珍,鲁金涛,赵新宝,等. HR3C在750℃空气和水蒸气中的高温氧化行为研究[J]. 动力工程学报,2015,35(10):859-864.
【10】TALLMAN R L, GULBRANSEN E A. Dislocation and grain boundary diffusion in the growth of α-Fe2O3 whiskers and twinned platelets peculiar to gaseous oxidation[J]. Nature, 1968, 218:1046-1047.
【11】VOSS D A, BUTLER E P, MITCHELL T E. The growth of hematite blades during the high temperature oxidation of iron[J]. Metallurgical Transactions A, 1982, 13(5):929-935.
【12】RAYNAUD G, RAPP R. In situ observation of whiskers, pyramids and pits during the high-temperature oxidation of metals[J]. Oxidation of Metals, 1984, 21(1/2):89-102.
【13】LIMOGE Y, BOCQUET J L. Selfdiffusion and point defects in iron oxides FeO, Fe3O4, α-Fe2O3[J]. Defect and Diffusion Forum, 2001, 194:1051-1056.
【14】HAGEL W C, SEYBOLT A U. Cation diffusion in Cr2O3[J]. Journal of the Electrochemical Society, 1961, 108(12):1146-1152.
【15】HAGEL W C. Anion diffusion in α-Cr2O3[J]. Journal of the American Ceramic Society, 1965, 48(2):70-75.
【16】JUTTE R H, KOOI B J, SOMERS M A, et al. On the oxidation of α-Fe and ε-FeFe2N1-z:I. Oxidation kinetics and microstructural evolution of the oxide and nitride layers[J]. Oxidation of Metals, 1997, 48(1/2):87-109.
【17】STOTT F, WEI F. High temperature oxidation of commercial austenitic stainless steels[J]. Materials Science and Technology, 1989, 5(11):1140-1147.
【18】KOFSTAD P K. Nonstoichiometry, diffusion and electrical conductivity in binary metal oxides[M]. New York:Wiley-Interscience, 1972.
【19】KOFSTAD P, LILLERUD K. Chromium transport through Cr2O3 scales I. On lattice diffusion of chromium[J]. Oxidation of Metals, 1982, 17(3/4):177-194.
【20】GRESKOVICH C. Deviation from stoichiometry in Cr2O3 at high oxygen partial pressures[J]. Journal of the American Ceramic Society, 1984, 67(6):C111-C112.
【21】LOBNIG R E, SCHMIDT H P, HENNESEN K, et al. Diffusion of cations in chromia layers grown on iron-base alloys[J]. Oxidation of Metals, 1992, 37(1/2):81-93.
【22】WAGNER C. Reaktionstypen bei der oxydation von legierungen[J].Berichte der Bunsengesellschaft für Physikalische Chemie, 1959, 63(7):772-782.
【23】WAGNER C. Theoretical analysis of the diffusion processes determining the oxidation rate of alloys[J]. Journal of the Electrochemical Society, 1952, 99(10):369-380.
【24】SUZUOKA T. Lattice and grain boundary diffusion in polycrystals[J]. Transactions of Japan Institute of Metals, 1961, 2:25-33.
【25】LAFLAMME G R,MORRAL J E. Limiting cases of subscale formation[J].Acta Metallurgica, 1978, 26(12):1791-1794.
【26】KAMPMANN L, KAHLWEIT M. Zur theorie von fällungen[J]. Berichte der Bunsengesellschaft für Physikalische Chemie, 1970, 74(5):456-462.
【27】WAGNER C. Mathematical analysis of the formation of periodic precipitations[J]. Journal of Colloid Science, 1950, 51(1):85-97.
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