Galvanic Corrosion Behavior of Hub-bolt Joint of Magnesium Alloy
摘 要
针对镁合金汽车轮毂在实际应用中出现的电偶腐蚀这一难题,建立了轮毂、螺栓连接电偶腐蚀的物理模型和数学模型,推导出电偶腐蚀分析的控制方程式,利用有限元方法结合移动网格技术,模拟研究了镁合金轮毂-钢质螺栓连接在NaCI溶液中的电偶腐蚀行为,得到了连接螺栓沉孔深度和沉孔半径对轮毂腐蚀深度的影响规律;并通过轮毂-螺栓连接偶对金属的全浸试验,验证了镁合金轮毂-钢质螺栓连接电偶腐蚀模拟分析方法的正确性。结果表明:随着沉孔深度增加,平均腐蚀深度先增加后减小;随着沉孔半径增加,平均腐蚀深度逐渐减小,而连接边缘处最大腐蚀深度先增加后近似保持不变。
Abstract
Aiming at the problem of galvanic corrosion of magnesium alloy hub in automotive industry, the physical model and mathematical model of galvanic corrosion for hub-bolt joint were built and the governing equations of galvanic corrosion were deduced. In combination with a moving mesh technique, the galvanic corrosion behavior of magnesium alloy hub-steel bolt joints in a sodium chloride solution was investigated by finite element method. And the influence law of counterbore depth and counterbore radius on the corrosion depth of hub was obtained. The correctness of the simulation method for the galvanic corrosion of magnesium alloy hub-steel bolt joint was verified by the full immersion test of the hub-bolt coupling pair. The results showed that with the increase of sinkhole depth, the average depth of corrosion increased first and then decreased. With the increase of sinkhole radius, the average depth of corrosion decreased, while the maximum depth of corrosion increased first and then remained approximately unchanged.
中图分类号 TG174.3 DOI 10.11973/fsyfh-201803004
所属栏目 试验研究
基金项目 中信戴卡股份有限公司资助项目(DK-YJY-20140014)
收稿日期 2016/9/16
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联系人作者安子军(zjan@ysu.edu.cn)
引用该论文: HU Zhijiang,AN Zijun,ZHU Zhihua,XU Shiwen. Galvanic Corrosion Behavior of Hub-bolt Joint of Magnesium Alloy[J]. Corrosion & Protection, 2018, 39(3): 184
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参考文献
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【2】张新,张奎. 镁合金腐蚀行为及机理研究进展[J]. 腐蚀科学与防护技术,2015(1):78-84.
【3】曾荣昌,陈君,张津. 镁合金电偶腐蚀研究及其进展[J]. 材料导报,2008,22(1):107-109.
【4】CROSS S R,GOLLAPUDI S,SCHUH C A. Validated numerical modeling of galvanic corrosion of zinc and aluminum coatings[J]. Corrosion Science,2014,88(88):226-233.
【5】THAMIDA S K. Modeling and simulation of galvanic corrosion pit as a moving boundary problem[J]. Computational Materials Science,2012,65(3):269-275.
【6】JIA J X,SONG G,ATRENS A. Influence of geometry on galvanic corrosion of AZ91D coupled to steel[J]. Corrosion Science,2006,48(8):2133-2153.
【7】THÉBAULT F,VUILLEMIN B,OLTRA R,et al. Reliability of numerical models for simulating galvanic corrosion processes[J]. Electrochimica Acta,2012,82(21):349-355.
【8】DESHPANDE K B. Effect of aluminium spacer on galvanic corrosion between magnesium and mild steel using numerical model and SVET experiments[J]. Corrosion Science,2012,62(9):184-191.
【9】刘贵昌,孙文,王立达. 海水中牺牲阳极阴极保护的分段非线性边界数学模型[J]. 腐蚀与防护,2012(10):876-879.
【10】高福勇,赵明,何广平,等. AZ31镁合金微区电偶腐蚀的数值研究[J]. 北京科技大学学报,2013,35(5):634-641.
【11】DESHPANDE K B. Experimental investigation of galvanic corrosion:comparison between SVET and immersion techniques[J]. Corrosion Science,2010,52(9):2819-2826.
【12】DESHPANDE K B. Validated numerical modelling of galvanic corrosion for couples:magnesium alloy (AE44)-mild steel and AE44-aluminium alloy (AA6063) in brine solution[J]. Corrosion Science,2010,52(10):3514-3522.
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