Microstructure and Hydrogen Induced Cracking Behavior of Interface between Nickel-Based Alloy Surfacing Layer on X70 Pipeline Steel and Base Metal
摘 要
采用手工非熔化极惰性气体钨极保护焊将ERNiCrMo-3镍基合金焊丝堆焊于X70管线钢表面,分析了堆焊层/母材界面处的显微组织、元素分布和硬度分布,并采用电解充氢方法研究了氢致裂纹萌生位置和扩展方式。结果表明:X70管线钢表面镍基合金堆焊层/母材界面热影响区中细晶区的组织为细小铁素体和少量珠光体,靠近熔合线粗晶区的组织为粗大的铁素体,熔合区的组织为马氏体,堆焊层的组织为树枝状奥氏体;堆焊层冲击断口呈韧性断裂特征,母材断口呈解理或准解理脆性断裂特征,熔合区断口呈由浅韧窝+准解理组成的具有变形特征的混合过渡特征;堆焊层和熔合区的硬度均高于母材的;堆焊层表面氢致裂纹萌生于Al2O3和单质硅夹杂物处,扩展方式为沿晶和穿晶扩展。
Abstract
ERNiCrMo-3 nickel-based alloy welding wire was deposited on the surface of X70 pipeline steel by manual tungsten inert gas welding. The microstructure, element distribution and hardness distribution of the interface between the surfacing layer and base metal were analyzed. The initiation and propagation mode of hydrogen induced cracks were studied by electrochemical hydrogen charging method. The results show that the microstructure of fine grained region in heat affected zone of the interface between nickel-based alloy surfacing layer on X70 pipeline steel and base metal was fine ferrite and a small amount of pearlite. The microstructure of coarse grained region near fusion line was coarse ferrite. The microstructures of the fusion zone and surfacing layer were martensite and dendritic austenite, respectively. The impact fracture of surfacing layer showed a ductile fracture feature, the base metal showed a cleavage or quasi-cleavage brittle fracture feature, and fusion zone showed a mixture transition feature with deformation characteristics composed of shallow dimples and quasi-cleavage. The hardness of both the surfacing layer and fusion zone was higher than that of the base metal. The hydrogen induced cracks of the surfacing layer originated around the inclusions of Al2O3 and monatomic silicon, and propagation mode was intergranular and transgranular propagation.
中图分类号 TG174.44 DOI 10.11973/jxgccl201805005
所属栏目 试验研究
基金项目
收稿日期 2017/2/13
修改稿日期 2018/1/30
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备注于俊峰(1982-),男,山东东营人,工程师,学士
引用该论文: YU Junfeng,YANG Guang,WANG Jing,XING Yunying,WANG Xiuyun. Microstructure and Hydrogen Induced Cracking Behavior of Interface between Nickel-Based Alloy Surfacing Layer on X70 Pipeline Steel and Base Metal[J]. Materials for mechancial engineering, 2018, 42(5): 27~31
于俊峰,杨光,王晶,邢云颖,王修云. X70管线钢表面镍基合金堆焊层/母材界面的显微组织及氢致开裂行为[J]. 机械工程材料, 2018, 42(5): 27~31
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参考文献
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【3】ABERLE D, WOLF M, STENNER F. Corrosion resistance of nickel alloys and super austenitic stainless steel weld cladding as a function of dilution[C]//Corrosion 2010. Texas:NACE International, 2010:262-264.
【4】KOPLIKU A, CAVASSI P. Selection of UNS N08825 as cladding material for offshore pipelines transporting sour multiphase hydrocarbon[C]//Corrosion 2002. Colorado:NACE International, 2002:42-43.
【5】HUIZINGA S, MCLOUGHLIN B. Failure of a subsea super duplex manifold hub by HISC and implications for design[C]//Corrosion 2006. San Diego:NACE International, 2006:145-148.
【6】SAKAI T, ASAMI K, KATSUMATA M, et al. Hydrogen induced disbonding of weld overlay in pressure vessels and its prevention[C]//Current Solution to Hydrogen Problems in Steels. Washington DC:American Society for Metals, 1982:340-348.
【7】ARATE Y, MATSUDA F, NAKAGAWA H, et al. Solidification crack susceptibility in weld metals of fully austenitic stainless steels (report Ⅱ):Effect of strain rate on cracking threshold in weld metal during solidification[J]. Transactions of JWRI, 1977, 6:105-116.
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【10】SAVAGE W, NIPPES E, HOMMA H. Hydrogen induced cracking in HY-80 steel weldments[J]. Welding Journal, 1976, 55(11):368-376.
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