Corrosion Behavior of Carbon Steels 20 and L245NS in Drainage of CO2 Enhanced Oil Recovery
摘 要
通过腐蚀浸泡试验与电化学性能测试,并结合扫描电镜(SEM)、能谱仪(EDS)与X射线衍射仪(XRD)对20钢和L245NS钢在CO2驱油反排水中的腐蚀行为进行了研究。结果表明:20钢和L245NS钢的腐蚀速率随着温度和CO2分压的提高而显著增大,分别在温度55℃、CO2分压0.75 MPa时达到最大值;Cl-的抑制腐蚀机制与促进腐蚀机制之间的竞争,使两种碳钢的腐蚀速率随着Cl-含量的提高呈现先增大后减小再增大的规律;20钢和L245NS钢的腐蚀产物以FeCO3为主,其结构疏松,对基体保护性较差;腐蚀前后的极化曲线与电化学阻抗谱分析结果显示,20钢和L245NS钢的腐蚀电流密度与容抗弧直径分别有较小程度的降低与增大,表明腐蚀产物膜对钢材的保护作用不够明显。
Abstract
Corrosion behavior of carbon steel 20 and carbon steel L245NS in drainage of CO2 enhanced oil recovery (CO2-EOR) was studied by immersion tests and electrochemical measurements combined with scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and X-ray diffraction (XRD). The results show that the corrosion rates increased significantly with the increase of temperature and partial pressure of carbon dioxide. When the temperature was 55℃, or the partial pressure of carbon dioxide was 0.75 MPa, the corrosion rates of both carbon steels all reached a maximum. The competition between corrosion inhibition mechanism and corrosion promotion mechanism of Cl- made the corrosion rates increased first, and then decreased and increased at last with Cl- concentration increasing. The corrosion product film mainly consisted of FeCO3 with a loose structure, and had bad protection to substrate. The results of polarization curves and electrochemical impedance spectroscopy showed after corrosion the corrosion current density decreased and the capacitive loop increased for carbon steel 20 and L245NS in comparison with before corrosion, which indicated that protective effect of corrosion product film was not obvious.
中图分类号 TG172 DOI 10.11973/fsyfh-201806002
所属栏目 试验研究
基金项目 国家自然科学基金(51374180);西安长庆科技工程有限责任公司资助项目(CTEC(2015)Z-KY-003)
收稿日期 2017/2/6
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引用该论文: LIU Bo,REN Chengqiang,HE San,SUN Yinjuan,LIU Li,WANG Shuliang. Corrosion Behavior of Carbon Steels 20 and L245NS in Drainage of CO2 Enhanced Oil Recovery[J]. Corrosion & Protection, 2018, 39(6): 418
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【4】LIU Y,ZHANG B,ZHANG Y L,et al. Electrochemical polarization study on crude oil pipeline corrosion by the produced water with high salinity[J]. Engineering Failure Analysis,2016,60:307-315.
【5】袁青,刘音,毕研霞,等. 油气田开发中CO2腐蚀机理及防腐方法研究进展[J]. 天然气与石油,2015,33(2):78-81.
【6】李建忠,王海成,李宁. 油气田开发中二氧化碳腐蚀的危害与研究现状[J]. 广州化工,2011,39(21):21-23.
【7】APRAEL S Y,KHALID R,ABDUL K,et al. Effect of CO2 corrosion behavior of mild steel in oilfield produced water[J]. Journal of Loss Prevention in the Process Industries,2015,38:24-38.
【8】龙凤乐,郑文军,陈长风,等. 温度,CO2分压,流速,pH值对X65管线钢CO2均匀腐蚀速率的影响规律[J]. 腐蚀与防护,2005,26(7):290-293.
【9】张学元,邸超,雷良才. 二氧化碳腐蚀与防护[M]. 北京:化学工业出版社,2000:37-39.
【10】WAARD C D,LOTZ U,MILLIAMS D E. Predictive model for CO2 corrosion engineering in wet natural gas pipelines[J]. Corrosion,1991,47(12):976-985.
【11】傅献彩,沈文霞,姚天扬,等. 物理化学下册[M]. 5版.北京:高等教育出版社,2006:86-89.
【12】陈东,柳伟,路民旭,等. CO2分压对N80钢腐蚀产物膜保护性能的影响[J]. 北京科技大学学报,2007,29(3):288-292.
【13】ZHANG Y C,PANG X L,QU S P,et al. Discussion of the CO2 corrosion mechanism between low partial pressure and supercritical condition[J]. Corrosion Science,2012,59:186-197.
【14】贺三,姜锦涛,袁宗明. Cl-对CO2环境下的碳钢腐蚀影响[J]. 腐蚀研究,2012,26(6):36-38.
【15】ANSELMO N,MAY J E,MARIANO N A,et al. Corrosion behavior of supermartensitic stainless steel in aerated and CO2-saturated synthetic seawater[J]. Materials Science and Engineering:A,2006,428:73-79.
【16】LIU Q Y,MAO L J,ZHOU S W. Effects of chloride content on CO2 corrosion of carbon steel in simulated oil and gas well environments[J]. Corrosion Science,2014,84:165-171.
【17】LIU S,SUN H Y,SUN L J,et al. Effects of pH and Cl- concentration on corrosion behavior of the galvanized steel in simulated rust layer solution[J]. Corrosion Science,2012,65:520-527.
【18】CHENG Q L,TAO B,SONG L Y,et al. Corrosion behaviour of Q235B carbon steel in sediment water from crude oil[J]. Corrosion Science,2016,111:61-71.
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