几种热采井用油管钢在次生H2S/CO2环境中的腐蚀行为
Corrosion Behavior of Several Thermal Recovery Well Tubular Steels in Secondary H2S/CO2 Environment
摘 要
利用动态高温高压釜模拟研究了普碳油管钢N80和两种热采井用低合金油管钢TP100H和TP110H在稠油热采次生H2S/CO2腐蚀环境中的腐蚀行为。结果表明：在次生H2S/CO2腐蚀环境中，N80钢呈非均匀腐蚀特征，导致其腐蚀速率较低；TP110H钢及TP100H钢的腐蚀速率略高于N80钢的，清理产物膜后，呈现均匀腐蚀特征；三种钢的腐蚀速率与微观形貌特征一致，随腐蚀时间的延长，钢表面粗糙度增加，腐蚀速率降低。
耐热油管钢
次生腐蚀环境
H2S/CO2腐蚀
heavy oil thermal recovery
heat resistant tubular steel
secondary corrosive environment
CO2/H2S corrosion
Abstract
The corrosion behavior of ordinary carbon tubular steel N80 and two thermal recovery well tubular steels TP100H and TP110H in heavy oil thermal recovery secondary H2S/CO2 corrosive environment was studied in high-temperature and high-pressure autoclave. The results show that the corrosion rate of N80 steel was the lowest in three kinds of steels due to the characteristic of non-uniform corrosion. Both the TP110H steel and the TP100H steel had the corrosion rate slightly higher than that of the N80 steel, and presented uniform corrosion characteristics after removal of corrosion products. The corrosion rates of these three kinds of steels were consistent with their characteristics of microscopic appearance. With the increase of corrosion time, the surface roughness increased and the corrosion rate reduced correspondingly for three kinds of steels.
中图分类号 TG172 DOI 10.11973/fsyfh-201806006
所属栏目 试验研究
基金项目 北京市自然科学基金资助项目（2172048）
收稿日期 2017/9/22
修改稿日期
网络出版日期
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引用该论文: WANG Yangang,CHEN Yi,SUN Dongzheng,LIN Hai,WANG Kongyang,YAN Wei,DENG Jingen,XIANG Yong. Corrosion Behavior of Several Thermal Recovery Well Tubular Steels in Secondary H2S/CO2 Environment[J]. Corrosion & Protection, 2018, 39(6): 443
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参考文献
【1】赵杰,李强,王超,等. 注蒸汽热采技术研究进展[J]. 内蒙古石油化工,2010,36(9):110-112.
【2】卢小庆,李勤,李春香. 高强度稠油热采井专用套管TP110H的开发[J]. 钢管,2007,36(5):14-17.
【3】王兆会,高德利. 热采井套管损坏机理及控制技术研究进展[J]. 石油钻探技术,2003,31(5):46-48.
【4】李永东. 油水井套管损坏的断裂力学机理的研究[D]. 哈尔滨:哈尔滨工程大学,2001.
【5】卢小庆,方华,张冬梅,等. 高强度热采井专用套管TP100H的开发[J]. 钢铁,2001,36(10):30-32.
【6】HYNE J B. Aquathermolysis:a synopsis of work on chemical reaction between water (steam) and heavy oil sands during simulated steam stimulation[M].[S.l]:Alberta Oil Sands Technology and Research Authority,1986.
【7】ZHANG X,LIU Y,FAN Y,et al. Effects of reservoir minerals and chemical agents on aquathermolysis of heavy oil during steam injection[J]. China Petroleum Processing & Petrochemical Technology,2010,12(3):25-31.
【8】范洪富,刘永建,赵晓非. 稠油在水蒸汽作用下组成变化研究[J]. 燃料化学学报,2001,29(3):269-272.
【9】NASSAR N N,HUSEIN M M,PEREIRA-ALMAO P. Ultradispersed particles in heavy oil:part Ⅱ,sorption of H2S (g)[J]. Fuel Processing Technology,2010,91(2):169-174.
【10】刘永建,钟立国,蒋生健,等. 水热裂解开采稠油技术研究的进展[J]. 燃料化学学报,2004,32(1):117-122.
【11】朱光有,张水昌,梁英波,等. 川东北地区飞仙关组高含H2S天然气TSR成因的同位素证据[J]. 中国科学,2005,35(11):1037-1046.
【12】BELGRAVE J D M,MOORE R G,URSENBACH M G. Comprehensive kinetic models for the aquathermolysis of heavy oils[J]. Journal of Canadian Petroleum Technology,1997,36(4):38-44.
【13】徐东林. 两种油套管抗硫钢的H2S/CO2腐蚀研究[D]. 武汉:华中科技大学,2007.
【14】路民旭,白真权,赵新伟,等. 油气采集储运中的腐蚀现状及典型案例[J]. 腐蚀与防护,2002,23(3):105-113.
【15】闫伟,邓金根,董星亮,等. 普通油井管钢在CO2和H2S共存环境中的腐蚀实验研究[J]. 中国海上油气,2011,23(3):205-209.
【16】ZHENG Y,NING J,BROWN B,et al. Advancement in predictive modeling of mild steel corrosion in CO2 and H2S containing environments[C]//Corrosion 2015. Houston,DX:NACE International,2015:6146.
【17】YAN W,DENG J,ZHU P,et al. Investigation of pH2S influence on 3% Cr tubing steel corrosion behaviours in CO2-H2S-Cl- environment[J]. British Corrosion Journal,2015,50(7):525-532.
【18】ZHONG X,ZHANG G,QIU Y,et al. The corrosion of tin under thin electrolyte layers containing chloride[J]. Corrosion Science,2013,66(10):14-25.
【19】闫伟,邓金根,袁俊亮,等. 油套管钢长周期CO2腐蚀速率的测试及准确计算方法[J]. 材料保护,2014,47(8):71-74.
【20】吕祥鸿,赵国仙,张建兵,等. 低Cr钢在H2S/CO2环境中的腐蚀行为研究[J]. 材料工程,2009(10):20-25.
【2】卢小庆,李勤,李春香. 高强度稠油热采井专用套管TP110H的开发[J]. 钢管,2007,36(5):14-17.
【3】王兆会,高德利. 热采井套管损坏机理及控制技术研究进展[J]. 石油钻探技术,2003,31(5):46-48.
【4】李永东. 油水井套管损坏的断裂力学机理的研究[D]. 哈尔滨:哈尔滨工程大学,2001.
【5】卢小庆,方华,张冬梅,等. 高强度热采井专用套管TP100H的开发[J]. 钢铁,2001,36(10):30-32.
【6】HYNE J B. Aquathermolysis:a synopsis of work on chemical reaction between water (steam) and heavy oil sands during simulated steam stimulation[M].[S.l]:Alberta Oil Sands Technology and Research Authority,1986.
【7】ZHANG X,LIU Y,FAN Y,et al. Effects of reservoir minerals and chemical agents on aquathermolysis of heavy oil during steam injection[J]. China Petroleum Processing & Petrochemical Technology,2010,12(3):25-31.
【8】范洪富,刘永建,赵晓非. 稠油在水蒸汽作用下组成变化研究[J]. 燃料化学学报,2001,29(3):269-272.
【9】NASSAR N N,HUSEIN M M,PEREIRA-ALMAO P. Ultradispersed particles in heavy oil:part Ⅱ,sorption of H2S (g)[J]. Fuel Processing Technology,2010,91(2):169-174.
【10】刘永建,钟立国,蒋生健,等. 水热裂解开采稠油技术研究的进展[J]. 燃料化学学报,2004,32(1):117-122.
【11】朱光有,张水昌,梁英波,等. 川东北地区飞仙关组高含H2S天然气TSR成因的同位素证据[J]. 中国科学,2005,35(11):1037-1046.
【12】BELGRAVE J D M,MOORE R G,URSENBACH M G. Comprehensive kinetic models for the aquathermolysis of heavy oils[J]. Journal of Canadian Petroleum Technology,1997,36(4):38-44.
【13】徐东林. 两种油套管抗硫钢的H2S/CO2腐蚀研究[D]. 武汉:华中科技大学,2007.
【14】路民旭,白真权,赵新伟,等. 油气采集储运中的腐蚀现状及典型案例[J]. 腐蚀与防护,2002,23(3):105-113.
【15】闫伟,邓金根,董星亮,等. 普通油井管钢在CO2和H2S共存环境中的腐蚀实验研究[J]. 中国海上油气,2011,23(3):205-209.
【16】ZHENG Y,NING J,BROWN B,et al. Advancement in predictive modeling of mild steel corrosion in CO2 and H2S containing environments[C]//Corrosion 2015. Houston,DX:NACE International,2015:6146.
【17】YAN W,DENG J,ZHU P,et al. Investigation of pH2S influence on 3% Cr tubing steel corrosion behaviours in CO2-H2S-Cl- environment[J]. British Corrosion Journal,2015,50(7):525-532.
【18】ZHONG X,ZHANG G,QIU Y,et al. The corrosion of tin under thin electrolyte layers containing chloride[J]. Corrosion Science,2013,66(10):14-25.
【19】闫伟,邓金根,袁俊亮,等. 油套管钢长周期CO2腐蚀速率的测试及准确计算方法[J]. 材料保护,2014,47(8):71-74.
【20】吕祥鸿,赵国仙,张建兵,等. 低Cr钢在H2S/CO2环境中的腐蚀行为研究[J]. 材料工程,2009(10):20-25.
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