物理气相沉积制备ZrMoN薄膜的腐蚀行为
Corrosion Behavior of ZrMoN Coatings Prepared by Physical Vapor Deposition
摘 要
采用物理气相沉积（PVD）技术在304不锈钢表面沉积ZrMoN薄膜，利用扫描电镜（SEM）、X射线衍射仪（XRD）和电化学测试等方法对不同温度下ZrMoN薄膜的表面形貌、相结构和腐蚀行为进行研究。结果表明：除400℃外，在其他试验温度下，ZrMoN薄膜均具有很高的表面能，表现出良好的疏水性，对防止电极系统中水累积有着明显的帮助；在模拟的质子交换膜燃料电池（PEMFC）阴极环境中，基体较早地出现了过钝化，而ZrMoN薄膜未发生过钝化，这表明ZrMoN薄膜有助于提高不锈钢的耐蚀性能；温度为300，400℃时，ZrMoN薄膜具有良好的耐蚀性，在PEMFC的双极板材料的研究中具有很大的潜力。
腐蚀行为
双极板材料
ZrMoN薄膜
physical vapor deposition (PVD)
corrosion behavior
bipolar plate material
ZrMoN coating
Abstract
ZrMoN coatings were deposited on 304 stainless steel surface by physical vapor deposition (PVD). The surface morphology, phase structure and corrosion behavior of ZrMoN coatings at different temperatures were analyzed by the method of scanning electron microscopy (SEM), X-ray diffraction (XRD) and electrochemical test. The results show that ZrMoN coatings at test temperatures except 400℃ had high surface energy, showing good hydrophobicity which is helpful to prevent water accumulating in electrode system. In the simulated cathode environment of proton exchange membrance fuel cell (PEMFC), transpassivation appeared early for the substrate but did not appear for ZrMoN coatings. This indicates that the ZrMoN coating is helpful to improve the corrosion resistance of the stainless steel. ZrMoN coatings exhibited excellent corrosion resistance at temperatures of 300℃ and 400℃, which shows great potential in the study of bipolar plate material of PEMFC.
中图分类号 TG174 DOI 10.11973/fsyfh-201806008
所属栏目 试验研究
基金项目 江苏省自然科学基金项目（BK20141292）
收稿日期 2016/10/15
修改稿日期
网络出版日期
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引用该论文: ZHENG Chuanbo,CHEN Xi,CAI Yuanfei. Corrosion Behavior of ZrMoN Coatings Prepared by Physical Vapor Deposition[J]. Corrosion & Protection, 2018, 39(6): 453
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参考文献
【1】STIMMING U. Fuel cells-fundamentals and applications[J]. Fuel Cells,2001,1(1):5-39.
【2】COLLANTES G O. Incorporating stakeholders perspectives into models of new technologies diffusion:the case of fuel cell vehicles[J]. Technol Forecasting Soc Change,2007,74(3):267-280.
【3】SCHÄFER A,HEYWOOD J B,WEISS M A. Future fuel cell and internal combustion engine automobile technologies:a 25-year life cycle and fleet impact assessment[J]. Energy,2006,31(12):2064-2087.
【4】段良涛,张东明,郭路,等. 质子交换膜燃料电池钛基双极板多弧离子镀TiN膜的腐蚀行为[J]. 中国有色金属学报,2011,21(1):159-164.
【5】郭华. PEMFC用不锈钢双极板表面改性研究[D]. 大连:大连海事大学,2008:3-9.
【6】SOUTO R M,ALANYALI H. Electrochemical characteristics of steel coated with TiN and TiAlN coatings[J]. Corrosion Science,2000,42(12):2201-2211.
【7】LEAVEN L V,ALIAS M N,BROWN R. Corrosion behavior of ion plated and implated films[J]. Surface & Coatings Technology,1992,53(1):25-34.
【8】SHANMUGHAM C,RAJENDRAN N. Corrosion resistance of poly p-phenylenediamine conducting polymer coated 316L SS bipolar plates for proton exchange membrane fuel cells[J]. Progress in Organic Coatings,2015,89:42-49.
【9】LI M C,LUO S Z,ZENG C L,et al. Corrosion behavior of TiN coated type 316 stainless steel in simulated PEMFC environments[J]. Corrosion Science,2004,46(6):1369-1380.
【10】CHO E A,JEON U S,HONG S A,et al. Performance of a 1 kW-class PEMFC stack using TiN-coated 316 stainless steel bipolar plates[J]. Journal of Power Sources,2005,142(1/2):177-183.
【11】YAO S H,SU Y L,KAO W H,et al. Wear behavior of DC unbalanced magnetron sputter deposited ZrCN films[J]. Materials Letters,2005,59(26):3230-3233.
【12】BELL B D C,MURPHYS T,BURR P A,et al. The influence of alloying elements on the corrosion of Zr alloys[J]. Corrosion Science,2016,105:36-43.
【13】JARGELIUS-PETTERSSON R F A,POUND B G. Examination of the role of molybdenum in passivation of stainless steels using AC impedance spectroscopy[J]. Journal of the Electrochemical Society,1998,145(5):1462-1469.
【14】DAVIS J R. Atmospheric and aqueous corrosion[M]//ASM Speciality Handbook:Stainless Steel.[S.l.]:ASM International,1994:134-180.
【15】YI P,PENG L,FENG L,et al. Performance of a proton exchange membrane fuel cell stack using conductive amorphous carbon-coated 304 stainless steel bipolar plates[J]. Journal of Power Sources,2010,195(20):7061-7066.
【16】付宇,侯明,林国强,等. 质子交换膜燃料电池双极板用金属改性的研究[J]. 西安交通大学学报,2008,42(3):364-367.
【17】钱耀川,谭俊,石恭臣,等. 电沉积铅改性304不锈钢双极板在模拟PEMFC环境中的性能[J]. 南京工业大学学报:自然科学版,2009,31(5):47-51.
【18】ANTUNES R A,OLIVEIRA M C L,ETT G,et al. Corrosion of metal bipolar plates for PEM fuel cells:a review[J]. International Journal of Hydrogen Energy,2010,35(8):3632-3647.
【19】CHA B C,YOU Y Z,HONG S T,et al. Nitride films as protective layers for metallic bipolar plates of polymer electrolyte membrane fuel cell stacks[J]. International Journal of Hydrogen Energy,2011,36(7):4565-4572.
【2】COLLANTES G O. Incorporating stakeholders perspectives into models of new technologies diffusion:the case of fuel cell vehicles[J]. Technol Forecasting Soc Change,2007,74(3):267-280.
【3】SCHÄFER A,HEYWOOD J B,WEISS M A. Future fuel cell and internal combustion engine automobile technologies:a 25-year life cycle and fleet impact assessment[J]. Energy,2006,31(12):2064-2087.
【4】段良涛,张东明,郭路,等. 质子交换膜燃料电池钛基双极板多弧离子镀TiN膜的腐蚀行为[J]. 中国有色金属学报,2011,21(1):159-164.
【5】郭华. PEMFC用不锈钢双极板表面改性研究[D]. 大连:大连海事大学,2008:3-9.
【6】SOUTO R M,ALANYALI H. Electrochemical characteristics of steel coated with TiN and TiAlN coatings[J]. Corrosion Science,2000,42(12):2201-2211.
【7】LEAVEN L V,ALIAS M N,BROWN R. Corrosion behavior of ion plated and implated films[J]. Surface & Coatings Technology,1992,53(1):25-34.
【8】SHANMUGHAM C,RAJENDRAN N. Corrosion resistance of poly p-phenylenediamine conducting polymer coated 316L SS bipolar plates for proton exchange membrane fuel cells[J]. Progress in Organic Coatings,2015,89:42-49.
【9】LI M C,LUO S Z,ZENG C L,et al. Corrosion behavior of TiN coated type 316 stainless steel in simulated PEMFC environments[J]. Corrosion Science,2004,46(6):1369-1380.
【10】CHO E A,JEON U S,HONG S A,et al. Performance of a 1 kW-class PEMFC stack using TiN-coated 316 stainless steel bipolar plates[J]. Journal of Power Sources,2005,142(1/2):177-183.
【11】YAO S H,SU Y L,KAO W H,et al. Wear behavior of DC unbalanced magnetron sputter deposited ZrCN films[J]. Materials Letters,2005,59(26):3230-3233.
【12】BELL B D C,MURPHYS T,BURR P A,et al. The influence of alloying elements on the corrosion of Zr alloys[J]. Corrosion Science,2016,105:36-43.
【13】JARGELIUS-PETTERSSON R F A,POUND B G. Examination of the role of molybdenum in passivation of stainless steels using AC impedance spectroscopy[J]. Journal of the Electrochemical Society,1998,145(5):1462-1469.
【14】DAVIS J R. Atmospheric and aqueous corrosion[M]//ASM Speciality Handbook:Stainless Steel.[S.l.]:ASM International,1994:134-180.
【15】YI P,PENG L,FENG L,et al. Performance of a proton exchange membrane fuel cell stack using conductive amorphous carbon-coated 304 stainless steel bipolar plates[J]. Journal of Power Sources,2010,195(20):7061-7066.
【16】付宇,侯明,林国强,等. 质子交换膜燃料电池双极板用金属改性的研究[J]. 西安交通大学学报,2008,42(3):364-367.
【17】钱耀川,谭俊,石恭臣,等. 电沉积铅改性304不锈钢双极板在模拟PEMFC环境中的性能[J]. 南京工业大学学报:自然科学版,2009,31(5):47-51.
【18】ANTUNES R A,OLIVEIRA M C L,ETT G,et al. Corrosion of metal bipolar plates for PEM fuel cells:a review[J]. International Journal of Hydrogen Energy,2010,35(8):3632-3647.
【19】CHA B C,YOU Y Z,HONG S T,et al. Nitride films as protective layers for metallic bipolar plates of polymer electrolyte membrane fuel cell stacks[J]. International Journal of Hydrogen Energy,2011,36(7):4565-4572.
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