Determination of Hydroquinone in Tin Electroplating Solution with Methanesulfonae by Ultra-High Performance Liquid Chromatography
摘 要
移取25.00 mL样品,用水定容至100 mL,用0.2 μm水系滤膜过滤后制得样品溶液,采用BEH Amide色谱柱(3.0 mm×150 mm,1.7 μm)分离,以0.010 mol·L-1乙酸铵乙腈溶液-0.010 mol·L-1乙酸铵水溶液(体积比为70:30)为流动相,流量为0.40 mL·min-1,采用蒸发光散射检测器。干扰试验表明:甲基磺酸盐镀锡电镀液中其他共存组分对对苯二酚的测定均没有干扰。对苯二酚质量浓度在10.0~100.0 mg·L-1内,其质量浓度的对数与其峰面积的对数呈线性关系,检出限(3S/N)为2.21 mg·L-1。方法用于测定甲基磺酸盐镀锡电镀液样品中的对苯二酚,测定值的相对标准偏差(n=11)为0.79%~1.2%,加标回收率为99.2%~102%,。按照甲基磺酸盐镀锡电镀液配方配制合成样品,采用试验方法对对苯二酚进行测定,测定值与理论值相符。
Abstract
The sample (25.00 mL) was diluted to 100 mL with deionized water, and the solution was filtered with a 0.2 μm aqueous filter to prepare the sample solution. BEH Amide chromatographic column (3.0 mm×150 mm, 1.7 μm) was used for seperation, with 0.010 mol·L-1 ammonium acetate acetonitrile solution-0.010 mol·L-1 ammonium acetate aqueous solution (volume ratio of 70:30) as the mobile phase at the flow rate of 0.40 mL·min-1. Evaporatire light scattering detector was used. The interference tests showed that the determination of hydroquinone was not affected by other coexisting components in the tin electroplating solution with methanesulfonate. When the mass concentration of hydroquinone was in range of 10.0-100.0 mg·L-1, the logarithm of its mass concentration was linear to the logarithm of its corresponding peak area, with detection limit (3S/N) of 2.21 mg·L-1. The proposed method was applied to the determination of hydroquinone in actual samples, giving relative standard deviations (n=11) were in the range of 0.79%-1.2%, and the values of recovery obtained by standard addition method ranged from 99.2% to 102%.The synthetic sample of tin electroplating solution with methanesulfonate was prepared according to its formula and determined by the proposed method.The results were consistent with the theoretical values.
中图分类号 O657.31 DOI 10.11973/lhjy-hx201809010
所属栏目 工作简报
基金项目
收稿日期 2017/8/10
修改稿日期
网络出版日期
作者单位点击查看
备注周桂海,高级工程师,主要从事冶金分析测试技术研究工作,zhouguihai@baosteel.com
引用该论文: ZHOU Guihai. Determination of Hydroquinone in Tin Electroplating Solution with Methanesulfonae by Ultra-High Performance Liquid Chromatography[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2018, 54(9): 1039~1043
周桂海. 超高效液相色谱法测定甲基磺酸盐镀锡电镀液中对苯二酚[J]. 理化检验-化学分册, 2018, 54(9): 1039~1043
共有人对该论文发表了看法,其中:
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】孙学亮,黄勇军,梅华兴,等.镀锡板生产中电镀工艺发展综述[J].电镀与涂饰, 2015,34(7):409-411.
【2】陈友强.浅谈卤素法电镀锡工艺[J].电镀与环保, 2005,25(4):4-6.
【3】MARTYAK N M, SEEFELDT R. Additive-effects during plating in acid tin methanesulfonate electrolytes[J]. Electrochimica Acta, 2004,49(25):4303-4311.
【4】李立芳.萃取-紫外分光光度法测定显影废液中的米吐尔和对苯二酚[J].化学工程师, 2005,113(2):18-22.
【5】李山,潘海卫.间接光度法测定对苯二酚[J].理化检验-化学分册, 2008,44(2):185-186.
【6】王园朝,项青雅.碘酸钾-5-溴-(2-吡啶偶氮)-二乙氨基酚体系催化动力学光度法测定痕量对苯二酚[J].冶金分析, 2008,28(6):51-68.
【7】KANG J, LI J, TANG J L, et al. Sensitized chemilu-minescence of Tween 20 on CdTe/H2O2 and its analytical applications for determination of phenolic compounds[J]. Colloid Surface B, 2010,76(1):259-264.
【8】陈慧,王九春,周敏,等.流动注射化学发光法测定水中的邻苯二酚[J].兰州理工大学学报, 2010,36(2):52-55.
【9】谢建新,伍贤学.流动注射-Luminol/Tween 20化学发光体系测定邻苯二酚[J].贵州师范大学学报(自然科学版), 2013,31(3):72-75.
【10】刘雪,骆定法,王兰,等.对苯二酚在氧化石墨烯修饰玻碳电极上的电化学行为及测定[J].信阳师范学院学报(自然科学版), 2012,67(2):321-322.
【11】杨绍明,魏志鹏,胡光辉,等.碳纳米管修饰电极同时测定邻苯二酚和对苯二酚[J].高等学校化学学报, 2010,31(2):264-268.
【12】钱功明,杨昌柱,张敬东.纳米铂修饰玻碳电极对邻苯二酚的电化学氧化及测定[J].分析科学学报, 2010,26(1):83-86.
【13】孟昭仁,刘欣茹.示波极谱滴定法测定显影液中米吐尔和对苯二酚含量[J].分析科学学报, 2000,16(4):314-316.
【14】赵起越,岳志孝.气相色谱法分析固体废弃物中苯酚类物质[J].岩矿测试, 2001,20(4):279-283.
【15】鲁萍,孔黎明,吴俊.高效液相色谱法同时分析水中酚类混合物[J].扬州大学学报(自然科学版), 2004,7(4):24-26.
【16】杨佰娟,张魁英,郑立,等.超声辅助萃取/气相色谱-质谱测定沉积物中的对苯二酚[J].分析测试学报, 2011,42(7):305-307.
【2】陈友强.浅谈卤素法电镀锡工艺[J].电镀与环保, 2005,25(4):4-6.
【3】MARTYAK N M, SEEFELDT R. Additive-effects during plating in acid tin methanesulfonate electrolytes[J]. Electrochimica Acta, 2004,49(25):4303-4311.
【4】李立芳.萃取-紫外分光光度法测定显影废液中的米吐尔和对苯二酚[J].化学工程师, 2005,113(2):18-22.
【5】李山,潘海卫.间接光度法测定对苯二酚[J].理化检验-化学分册, 2008,44(2):185-186.
【6】王园朝,项青雅.碘酸钾-5-溴-(2-吡啶偶氮)-二乙氨基酚体系催化动力学光度法测定痕量对苯二酚[J].冶金分析, 2008,28(6):51-68.
【7】KANG J, LI J, TANG J L, et al. Sensitized chemilu-minescence of Tween 20 on CdTe/H2O2 and its analytical applications for determination of phenolic compounds[J]. Colloid Surface B, 2010,76(1):259-264.
【8】陈慧,王九春,周敏,等.流动注射化学发光法测定水中的邻苯二酚[J].兰州理工大学学报, 2010,36(2):52-55.
【9】谢建新,伍贤学.流动注射-Luminol/Tween 20化学发光体系测定邻苯二酚[J].贵州师范大学学报(自然科学版), 2013,31(3):72-75.
【10】刘雪,骆定法,王兰,等.对苯二酚在氧化石墨烯修饰玻碳电极上的电化学行为及测定[J].信阳师范学院学报(自然科学版), 2012,67(2):321-322.
【11】杨绍明,魏志鹏,胡光辉,等.碳纳米管修饰电极同时测定邻苯二酚和对苯二酚[J].高等学校化学学报, 2010,31(2):264-268.
【12】钱功明,杨昌柱,张敬东.纳米铂修饰玻碳电极对邻苯二酚的电化学氧化及测定[J].分析科学学报, 2010,26(1):83-86.
【13】孟昭仁,刘欣茹.示波极谱滴定法测定显影液中米吐尔和对苯二酚含量[J].分析科学学报, 2000,16(4):314-316.
【14】赵起越,岳志孝.气相色谱法分析固体废弃物中苯酚类物质[J].岩矿测试, 2001,20(4):279-283.
【15】鲁萍,孔黎明,吴俊.高效液相色谱法同时分析水中酚类混合物[J].扬州大学学报(自然科学版), 2004,7(4):24-26.
【16】杨佰娟,张魁英,郑立,等.超声辅助萃取/气相色谱-质谱测定沉积物中的对苯二酚[J].分析测试学报, 2011,42(7):305-307.
相关信息