Corrosion Behavior of High Strength 15Cr Martensitic Stainless Steel in Organic Salt Completion Fluid
摘 要
通过高温高压腐蚀模拟试验、应力腐蚀开裂试验及电化学测试,研究了高强15Cr马氏体不锈钢在有机盐完井液中的腐蚀行为。结果表明:180℃温度下,在密度为1.4 g/cm3的有机盐完井液中腐蚀720 h,高强15Cr马氏体不锈钢的均匀腐蚀速率为0.289 8 mm/a;相同条件下高强15Cr马氏体不锈钢具有良好的耐应力腐蚀性能;当有机盐完井液密度为1.4 g/cm3,温度为30~150℃时,高强15Cr马氏体不锈钢的点蚀电位随温度升高而降低,且降低的趋势逐渐变弱;当温度为30℃,有机盐完井液的密度为1.1~1.5 g/cm3时,有机盐完井液的密度对高强15Cr马氏体不锈钢的点蚀电位几乎没有影响。
Abstract
The corrosion behavior of high strength 15Cr martensitic stainless steel in organic salt completion fluid was studied by high temperature and high pressure corrosion simulation test, stress corrosion cracking test and electrochemical test. The results show that the uniform corrosion rate of high strength 15Cr martensitic stainless steel was 0.289 8 mm/a when it was corroded in the completion fluid with density of 1.4 g/cm3 and containing organic salt at 180℃ for 720 h. Under the same conditions, the high strength 15Cr martensitic stainless steel had good resistance to stress corrosion. When the density of organic salt completion fluid was 1.4 g/cm3, the pitting potential of the high strength 15Cr martensitic stainless steel decreased with the increase of temperature in the range of 30~150℃, and the decreasing trend weakened gradually. The density of organic salt completion fluid in the range of 1.1~1.5 g/cm3 had little effect on the pitting potential of the high strength 15Cr martensitic stainless steel at 30℃.
中图分类号 TG172 DOI 10.11973/fsyfh-201812002
所属栏目 试验研究
基金项目 国家自然科学基金项目(51271146);陕西省自然科学基金(2016JM5064)
收稿日期 2017/6/17
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引用该论文: YANG Xiangtong,LÜ,Xianghong,XIE Junfeng,LI Danping,GENG Hailong,MA Lei,XUE Yan. Corrosion Behavior of High Strength 15Cr Martensitic Stainless Steel in Organic Salt Completion Fluid[J]. Corrosion & Protection, 2018, 39(12): 901
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参考文献
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【3】王立翀,吕祥鸿,赵荣怀,等. 超级13Cr与高强15Cr马氏体不锈钢在酸化液中的耐蚀性能对比[J]. 机械工程材料,2014,38(5):57-58.
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【6】HABIB K,BOURESLI K. Detection of localized corrosion of stainless steels by optical interferometry[J]. Electrochimica Acta,2000,45(3):203-209.
【7】MAYORGA C D,MARQUEZ A P A,SARMIENTO M Q,et al. Evaluation of corrosion in electrochemical systems using michelson interferometry[J]. Optics and Lasers in Engineering,2007,45(1):140-144.
【8】申泽骥,姜炳焕,苏贵桥,等. 奥氏体铸体和18-8不锈钢在烧碱中的腐蚀行为[J]. 材料科学与工艺,1999,7(3):10-13.
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【10】LI G M,GUO X P,ZHENG J S. Pitting corrosion behavior of stainless steel 304 in carbon dioxide environments[J]. Journal of Iron and Steel Research International,2004,11(4):47-51.
【11】ABUBAKIR S. The effect of temperature and acidity on the pitting corrosion behavior of duplex stainless steel in 3.5% NaCl solution[C]//10th Asian Pacific Corrosion Control Conference.[S.l.]:[s.n.],1997:324-329.
【12】邓博,蒋益明. F-和Cl-对316不锈钢临界点点蚀温度的协同作用[J]. 中国腐蚀与防护学报,2008,28(1):31-32.
【13】张蕙文,王旷. 环境因素对不锈钢点蚀电位的影响[J]. 北京钢铁学院学报,1985(3):104-109.
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