Effect of CO2 Partial Pressure on Corrosion Behavior of N80 Steel in Auxiliary Steam Drive Oil Environment
摘 要
采用高温高压釜模拟CO2辅助蒸汽驱油注气井的工况条件,在温度160℃和CO2分压1~4 MPa条件下,对N80钢进行了挂片腐蚀试验,研究了CO2分压对其腐蚀行为的影响。结果表明:随着CO2分压的升高,腐蚀速率先升高后降低,并在CO2分压为2 MPa时达到最大,其值为0.073 7 mm·a-1;N80钢腐蚀产物的主要成分是FeCO3和少量Fe2O3,随着CO2分压的升高,FeCO3晶体尺寸减小,当CO2分压为3~4 MPa时FeCO3晶体发生融合;在试验条件下,N80钢的腐蚀速率在0.034 7~0.073 7 mm·a-1范围,均小于油田腐蚀速率控制指标(0.076 mm·a-1),满足CO2辅助蒸汽驱油注气井油套管的性能要求。
Abstract
The high temperature and high pressure autoclave was used to simulate the working conditions of CO2 auxiliary steam drive oil gas injection well. The coupon corrosion test was conducted on N80 steel at 160℃ and CO2 partial pressures of 1-4 MPa, and the effect of CO2 partial pressure on corrosion behavior of N80 steel was studied. The results show that with CO2 partial pressure increasing, the corrosion rate increased first and then decreased; when the CO2 partial pressure was 2 MPa, the corrosion rate reached the maximum value of 0.073 7 mm·a-1. The main composition of corrosion products of N80 steel was FeCO3 and a small amount of Fe2O3. With the increase of CO2 partial pressure, the size of FeCO3 crystals decreased, and FeCO3 crystals mixed together when CO2 partial pressure was 3-4 MPa. Under the test condition, the corrosion rate of N80 steel was 0.034 7-0.073 7 mm·a-1 which was lower than the corrosion rate control line of oil field (0.076 mm·a-1) and met the property requirement of CO2 auxiliary steam drive oil well casing.
中图分类号 TE983 DOI 10.11973/jxgccl201901004
所属栏目 试验研究
基金项目 国家自然科学基金资助项目(51774249);国家科技重大专项资助项目(2016ZX05012-001)
收稿日期 2017/10/19
修改稿日期 2018/12/7
网络出版日期
作者单位点击查看
备注董宝军(1989-),男,甘肃金昌人,硕士研究生
引用该论文: DONG Baojun,ZENG Dezhi,SHI Shanzhi,YU Huiyong,CHEN Yuxin,LU Wenting. Effect of CO2 Partial Pressure on Corrosion Behavior of N80 Steel in Auxiliary Steam Drive Oil Environment[J]. Materials for mechancial engineering, 2019, 43(1): 19~22
董宝军,曾德智,石善志,于会永,陈禹欣,鲁文婷. 辅助蒸汽驱油环境中CO2分压对N80钢腐蚀行为的影响[J]. 机械工程材料, 2019, 43(1): 19~22
共有人对该论文发表了看法,其中:
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】崔瑞杰.蒸汽驱后期二氧化碳辅助蒸汽驱实验研究[D]. 大庆:东北石油大学,2016.
【2】刘尚奇,杨双虎,高永荣,等.CO2辅助直井与水平井组合蒸汽驱技术研究[J]. 石油学报,2008,29(3):414-417.
【3】黄本生,卢杰,邓龙,等.某油田N80钢油管腐蚀失效的原因[J]. 机械工程材料, 2016, 40(1):93-97.
【4】曾德智,邓文良,田刚,等.温度对T95钢在H2S/CO2环境中腐蚀行为的影响[J]. 机械工程材料,2016,40(6):28-32.
【5】ZHANG G A,LIU D,LI Y Z,et al. Corrosion behaviour of N80 carbon steel in formation water under dynamic supercritical CO2 condition[J]. Corrosion Science,2017,120:107-120.
【6】LI Y Z,XU N,LIU G R,et al. Crevice corrosion of N80 carbon steel in CO2-saturated environment containing acetic acid[J]. Corrosion Science,2016,112:426-437.
【7】朱世东,李金灵,杨志刚,等.温度对J55油管CO2腐蚀行为的影响[J]. 机械工程材料,2014, 38(8):6-10.
【8】WEI L,PANG X,GAO K. Corrosion of low alloy steel and stainless steel in supercritical CO2/H2O/H2S systems[J]. Corrosion Science,2016,111:637-648.
【9】王霞,张仁勇,上官昌淮,等.两种套管钢在含CO2模拟油田地层水中的腐蚀行为[J]. 机械工程材料,2013,37(5):69-72.
【10】ZHANG G A,ZENG Y,GUO X P,et al. Electrochemical corrosion behavior of carbon steel under dynamic high pressure H2S/CO2 environment[J]. Corrosion Science,2012,65(12):37-47.
【11】CHOI Y S,NESIC S,LING S. Effect of H2S on the CO2 corrosion of carbon steel in acidic solutions[J]. Electrochimica Acta,2011,56(4):1752-1760.
【12】陈东,柳伟,路民旭,等.CO2分压对N80钢腐蚀产物膜保护性能的影响[J]. 北京科技大学学报,2007,29(3):288-292.
【13】刘晓玮,蔡庆伍,武会宾,等. CO2分压对X80管线钢腐蚀性能的影响[J]. 腐蚀与防护, 2012, 33(6):502-506.
【14】SUN C,SUN J,WANG Y,et al. Effect of impurity interaction on the corrosion film characteristics and corrosion morphology evolution of X65 steel in water-saturated supercritical CO2 system[J]. International Journal of Greenhouse Gas Control,2017,65:117-127.
【15】王世杰. CO2驱油注采井油套管腐蚀速率控制值[J]. 腐蚀与防护,2015,36(3):218.
【16】TANG Y,GUO X P,ZHANG G A. Corrosion behaviour of X65 carbon steel in supercritical-CO2 containing H2O and O2 in carbon capture and storage (CCS) technology[J]. Corrosion Science,2017,118:118-128.
【17】GUO S,XU L,ZHANG L,et al. Characterization of corrosion scale formed on 3Cr steel in CO2-saturated formation water[J]. Corrosion Science,2016,110:123-133.
【18】WU Q,ZHANG Z,DONG X,et al. Corrosion behavior of low-alloy steel containing 1% chromium in CO2 environments[J]. Corrosion Science,2013,75:400-408.
【2】刘尚奇,杨双虎,高永荣,等.CO2辅助直井与水平井组合蒸汽驱技术研究[J]. 石油学报,2008,29(3):414-417.
【3】黄本生,卢杰,邓龙,等.某油田N80钢油管腐蚀失效的原因[J]. 机械工程材料, 2016, 40(1):93-97.
【4】曾德智,邓文良,田刚,等.温度对T95钢在H2S/CO2环境中腐蚀行为的影响[J]. 机械工程材料,2016,40(6):28-32.
【5】ZHANG G A,LIU D,LI Y Z,et al. Corrosion behaviour of N80 carbon steel in formation water under dynamic supercritical CO2 condition[J]. Corrosion Science,2017,120:107-120.
【6】LI Y Z,XU N,LIU G R,et al. Crevice corrosion of N80 carbon steel in CO2-saturated environment containing acetic acid[J]. Corrosion Science,2016,112:426-437.
【7】朱世东,李金灵,杨志刚,等.温度对J55油管CO2腐蚀行为的影响[J]. 机械工程材料,2014, 38(8):6-10.
【8】WEI L,PANG X,GAO K. Corrosion of low alloy steel and stainless steel in supercritical CO2/H2O/H2S systems[J]. Corrosion Science,2016,111:637-648.
【9】王霞,张仁勇,上官昌淮,等.两种套管钢在含CO2模拟油田地层水中的腐蚀行为[J]. 机械工程材料,2013,37(5):69-72.
【10】ZHANG G A,ZENG Y,GUO X P,et al. Electrochemical corrosion behavior of carbon steel under dynamic high pressure H2S/CO2 environment[J]. Corrosion Science,2012,65(12):37-47.
【11】CHOI Y S,NESIC S,LING S. Effect of H2S on the CO2 corrosion of carbon steel in acidic solutions[J]. Electrochimica Acta,2011,56(4):1752-1760.
【12】陈东,柳伟,路民旭,等.CO2分压对N80钢腐蚀产物膜保护性能的影响[J]. 北京科技大学学报,2007,29(3):288-292.
【13】刘晓玮,蔡庆伍,武会宾,等. CO2分压对X80管线钢腐蚀性能的影响[J]. 腐蚀与防护, 2012, 33(6):502-506.
【14】SUN C,SUN J,WANG Y,et al. Effect of impurity interaction on the corrosion film characteristics and corrosion morphology evolution of X65 steel in water-saturated supercritical CO2 system[J]. International Journal of Greenhouse Gas Control,2017,65:117-127.
【15】王世杰. CO2驱油注采井油套管腐蚀速率控制值[J]. 腐蚀与防护,2015,36(3):218.
【16】TANG Y,GUO X P,ZHANG G A. Corrosion behaviour of X65 carbon steel in supercritical-CO2 containing H2O and O2 in carbon capture and storage (CCS) technology[J]. Corrosion Science,2017,118:118-128.
【17】GUO S,XU L,ZHANG L,et al. Characterization of corrosion scale formed on 3Cr steel in CO2-saturated formation water[J]. Corrosion Science,2016,110:123-133.
【18】WU Q,ZHANG Z,DONG X,et al. Corrosion behavior of low-alloy steel containing 1% chromium in CO2 environments[J]. Corrosion Science,2013,75:400-408.
相关信息