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辅助蒸汽驱油环境中CO2分压对N80钢腐蚀行为的影响
          
Effect of CO2 Partial Pressure on Corrosion Behavior of N80 Steel in Auxiliary Steam Drive Oil Environment

摘    要
采用高温高压釜模拟CO2辅助蒸汽驱油注气井的工况条件,在温度160℃和CO2分压1~4 MPa条件下,对N80钢进行了挂片腐蚀试验,研究了CO2分压对其腐蚀行为的影响。结果表明:随着CO2分压的升高,腐蚀速率先升高后降低,并在CO2分压为2 MPa时达到最大,其值为0.073 7 mm·a-1;N80钢腐蚀产物的主要成分是FeCO3和少量Fe2O3,随着CO2分压的升高,FeCO3晶体尺寸减小,当CO2分压为3~4 MPa时FeCO3晶体发生融合;在试验条件下,N80钢的腐蚀速率在0.034 7~0.073 7 mm·a-1范围,均小于油田腐蚀速率控制指标(0.076 mm·a-1),满足CO2辅助蒸汽驱油注气井油套管的性能要求。
标    签 CO2分压   辅助蒸汽驱油   N80钢   腐蚀产物   腐蚀速率   CO2 partial pressure   auxiliary steam drive oil   N80 steel   corrosion product   corrosion rate  
 
Abstract
The high temperature and high pressure autoclave was used to simulate the working conditions of CO2 auxiliary steam drive oil gas injection well. The coupon corrosion test was conducted on N80 steel at 160℃ and CO2 partial pressures of 1-4 MPa, and the effect of CO2 partial pressure on corrosion behavior of N80 steel was studied. The results show that with CO2 partial pressure increasing, the corrosion rate increased first and then decreased; when the CO2 partial pressure was 2 MPa, the corrosion rate reached the maximum value of 0.073 7 mm·a-1. The main composition of corrosion products of N80 steel was FeCO3 and a small amount of Fe2O3. With the increase of CO2 partial pressure, the size of FeCO3 crystals decreased, and FeCO3 crystals mixed together when CO2 partial pressure was 3-4 MPa. Under the test condition, the corrosion rate of N80 steel was 0.034 7-0.073 7 mm·a-1 which was lower than the corrosion rate control line of oil field (0.076 mm·a-1) and met the property requirement of CO2 auxiliary steam drive oil well casing.

中图分类号 TE983   DOI 10.11973/jxgccl201901004

 
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所属栏目 试验研究

基金项目 国家自然科学基金资助项目(51774249);国家科技重大专项资助项目(2016ZX05012-001)

收稿日期 2017/10/19

修改稿日期 2018/12/7

网络出版日期

作者单位点击查看

备注董宝军(1989-),男,甘肃金昌人,硕士研究生

引用该论文: DONG Baojun,ZENG Dezhi,SHI Shanzhi,YU Huiyong,CHEN Yuxin,LU Wenting. Effect of CO2 Partial Pressure on Corrosion Behavior of N80 Steel in Auxiliary Steam Drive Oil Environment[J]. Materials for mechancial engineering, 2019, 43(1): 19~22
董宝军,曾德智,石善志,于会永,陈禹欣,鲁文婷. 辅助蒸汽驱油环境中CO2分压对N80钢腐蚀行为的影响[J]. 机械工程材料, 2019, 43(1): 19~22


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