Effect of Sensitization on the Chromium Ion Released from 430 Ferritic Stainless Steel
摘 要
采用微观形貌观察,电化学方法等研究了热处理温度对430不锈钢敏化的影响以及敏化对430不锈钢在腐蚀液中铬离子析出量的影响。结果表明:热处理温度为800~900℃时,随着温度的上升试样的敏化度增加,并在约900℃最为严重,继续升高热处理温度,试样晶粒长大,单位晶间腐蚀面积变小,敏化度降低。试样在酸性无氯或含氯中性溶液中,其敏化度的高低对铬析出量影响甚小,而在酸性含氯溶液中,铬离子析出量大且随其敏化度的增大而升高。敏化试样浸泡首日的铬离子析出量较多,随着时间的延长,不同溶液中铬离子的析出总量都有不同程度的累计上升,但日均上升幅度却不尽相同。溶液温度的上升,均会加速敏化试样在腐蚀溶液中的腐蚀,使得铬离子析出量增大。
Abstract
The effect of heat treatment temperature on the sensitization of 430 stainless steel and the effect of sensitization on the precipitation of 430 stainless steel in corrosive solutions were investigated by microscopic observation and electrochemical methods. The results show that when the heat treatment temperature was 800-900 ℃, the sensitization degree of the sample increased with the increase of temperature, and it was most serious at about 900 ℃. Continue to increase the heat treatment temperature, the sample grain growed, the intergranular corrosion area became smaller, and the sensitization degree decreased. In acidic chlorine-free or chlorine-containing neutral solutions, the sensitization degree of the sample had little effect on the amount of chromium precipitation. In acidic chloride-containing solution, the amount of chromium ion precipitated was large and increased with the increase of sensitization degree. The amount of chromium ion precipitated on the first day of sensitization of the sample was relatively high. With the extension of time, the total amount of chromium ion in different solutions increased cumulatively, but the daily average increase was not the same. The rise of solution temperature accelerated the corrosion of sensitized sample in corrosive solutions, so that the amount of chromium ion precipitation increased.
中图分类号 TG174 DOI 10.11973/fsyfh-201903005
所属栏目 试验研究
基金项目 广东省质监局科技计划资助项目(2016ZZ06)
收稿日期 2017/10/5
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引用该论文: HUANG Zidong,CHEN Huibo,CHEN Liling,JIANG Chuangsheng,LIN Junming,HONG Zehao,WEI Liangxin. Effect of Sensitization on the Chromium Ion Released from 430 Ferritic Stainless Steel[J]. Corrosion & Protection, 2019, 40(3): 179
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【2】邵泽斌,陈海涛,郎宇平,等. 热加工对430铁素体不锈钢“金粉”现象的影响[J]. 材料工程,2013(3):61-66.
【3】温军国,郑弃非,涂思京,等. 热处理对铁素体不锈钢组织和性能的影响[J]. 稀有金属,2006,30:152-154.
【4】万章. 铁素体不锈钢晶间腐蚀问题的探讨[J]. 石油化工腐蚀与防护,2015,32(4):62-64.
【5】KANEKO K,FUKUNAGA T,YAMADA K,et al. Formation of M23C6-type precipitates and chromium-depleted zones in austenite stainless steel[J]. Scripta Materialia,2011,65(6):509-512.
【6】KIM J K,KIM Y H,UHM S H,et al. Intergranular corrosion of Ti-stabilized 11wt% Cr ferritic stainless steel for automotive exhaust systems[J]. Corrosion Science,2009,51(11):2716-2723.
【7】KIM J K,LEE J S,KIM K Y. Intergranular precipitation and corrosion in weld of low Cr ferritic stainless steel[J]. Metals and Materials International,2012,18(4):619-624.
【8】金维松,朗宇平,荣凡. EPR法评价奥氏体不锈钢晶间腐蚀敏感性的研究[J]. 中国腐蚀与防护学报,2007,27(1):54-59.
【9】邵泽斌,陈海涛,朗宇平,等. 430铁素体不锈钢晶间腐蚀敏感性评测方法及影响因素[J]. 特殊钢,2012,33(5):57-60.
【10】LOPEZ N,CID M,PUIGGALI M,et al. Application of double loop electrochemical potentiodynamic reactivation test to austenitic and duplex stainless steels[J]. Mater Sci Eng A,1997,229:123-128.
【11】AMADOU T,BRAHAM C,SIDHOM H. Double loop electrochemical potentiokinetic reactivation test optimization in checking of duplex stainless steel intergranular corrosion susceptibility[J]. Metall Mater Trans A,2004,35:3499-3513.
【12】SINYAVSKⅡ V S,LANOVA V V,KALININ V D. On the mechanism of intergranular corrosion of aluminum[J]. Prot Met,2001(40):537-539.
【13】HUANG X Z,WANG D,YANG Y T. Effect of precipitation on intergranular corrosion resistance of 430 ferritic stainless steel[J]. Journal of Iron and Steel Research,International,2015,22(11):1062-1068.
【14】胡潘,毛宏焕,杨弋涛. 碳含量对430铁素体不锈钢耐晶间腐蚀性能的影响[J]. 腐蚀与防护,2016,37(12):956-960.
【15】梁成浩,高扬. 敏化对不锈钢孔蚀性能的影响[J]. 腐蚀科学与防护技术,1996,8(4):281-285.
【16】JIANG J,XU D,XI T,et al. Effects of aging time on intergranular and pitting corrosion behavior of Cu-bearing 304L stainless steel in comparison with 304L stainless steel[J]. Corrosion Science,2016,113:46-56.
【17】陈惠波,黄子东,江乙逵,等. 晶间腐蚀对304不锈钢食具铬离子析出量的影响[J]. 现代食品科技,2017,33(6):240-247.
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