油气管道CO2与H2S腐蚀与防护研究进展
Research Progress on Corrosion and Protection of CO2 and H2S in Oil and Gas Pipeline
摘 要
针对油气管道的腐蚀问题，对油气管道中的CO2腐蚀和H2S腐蚀的研究现状、腐蚀机理以及腐蚀规律进行了介绍。分析了CO2和H2S协同腐蚀研究中存在的问题，介绍了常用的管道防腐蚀方法，如添加缓蚀剂、使用耐腐蚀合金钢、施加电化学防腐蚀技术以及涂覆管道内涂层等，同时对其研究进展及存在的问题进行了总结。
CO2
H2S
腐蚀机理
防腐蚀研究
oil and gas pipeline
CO2
H2S
corrosion mechanism
anticorrosive research
Abstract
In view of the corrosion problem of oil and gas pipelines, the research status, corrosion mechanism and corrosion law of CO2 corrosion and H2S corrosion in oil and gas pipelines are introduced. The problems in the research of CO2 and H2S synergistic corrosion are analyzed. The common pipeline anti-corrosion methods are introduced, such as adding corrosion inhibitor, using corrosion-resistant alloy steel, applying electrochemical anti-corrosion technology and coat the inner coating of pipeline, etc. The research progress and existing problems of those methods are summarized.
中图分类号 TG174.4 DOI 10.11973/fsyfh-201905004
所属栏目 管道的腐蚀与防护
基金项目
收稿日期 2019/1/5
修改稿日期
网络出版日期
作者单位点击查看
引用该论文: YAO Peifang. Research Progress on Corrosion and Protection of CO2 and H2S in Oil and Gas Pipeline[J]. Corrosion & Protection, 2019, 40(5): 327
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参考文献
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【28】张光华,王腾飞,孙卫玲,等. 硫脲基烷基咪唑啉类缓蚀剂的制备、缓蚀性能及其机理[J]. 材料保护,2011,44(2):21-23.
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【32】张忠铧,黄子阳,孙元宁,等. 3Cr抗CO2和H2S腐蚀系列油套管开发[J]. 宝钢技术,2006(3):5-8.
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【34】李珣. 井下油套管二氧化碳腐蚀研究[D]. 成都:四川大学,2005.
【35】王少兰,费敬银,林西华,等. 高性能耐蚀管材及超级13Cr研究进展[J]. 腐蚀科学与防护技术,2013,25(4):322-326.
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【2】佟淑娇,吴宗之,王如君,等. 埋地油气管道沿线土壤腐蚀性可拓评价研究[J]. 中国安全生产科学技术,2015(12):116-122.
【3】赵元雷. 埋地油气管道腐蚀分析[J]. 石化技术,2016,23(11):73-73.
【4】郭建永,胡军,李庆达,等. 国内外油气管道腐蚀与防护的研究进展[J]. 材料保护,2017,50(6):83-87.
【5】李明,王晓霖,乔国春,等. 天然气长输管道外腐蚀直接评价的实践[J]. 材料保护,2015,48(8):70-73.
【6】程鹏,黄先球. 管线钢抗硫化氢腐蚀研究进展[J]. 武汉工程职业技术学院学报,2015,27(1):32-35.
【7】文小明,陈宇,张立龙. 管线钢X65MS的硫化氢腐蚀开裂分析[J]. 金属世界,2017(1):57-59.
【8】王全庭,杨晶晶. 克服硫化氢应力腐蚀开裂的几种方法[J]. 石油化工腐蚀与防护,2014,31(5):37-39.
【9】张清,李全安,文九巴,等. 温度和压力对N80钢CO2/H2S腐蚀速率的影响[J]. 石油矿场机械,2004,33(3):42-44.
【10】DE WAARD C,MILLIAMS D E. Carbonic acid corrosion of steel[J]. Corrosion,1975,31(5):177-181.
【11】OGUNDELE G I,WHITE W E. Some observations on corrosion of carbon steel in aqueous environments containing carbon dioxide[J]. Corrosion,1986,42(2):71-78.
【12】姜放,戴海黔,曹小燕,等. 油套管在CO2和H2S共存时的腐蚀机理研究[J]. 石油与天然气化工,2005,34(3):213-215.
【13】陈墨,宋晓琴,许玉磊,等. CO2对金属管道腐蚀的研究现状及发展趋势[J]. 内蒙古石油化工,2006(7):9-10.
【14】WANG P Y,WANG J,ZHENG S Q,et al. Effect of H2S/CO2 partial pressure ratio on the tensile properties of X80 pipeline steel[J]. International Journal of Hydrogen Energy,2015,40(35):11925-11930.
【15】ZAFARM N,RIHANR,AL-HADHRAMI L. Evaluation of the corrosion resistance of SA-543 and X65 steels in emulsions containing H2S and CO2 using a novel emulsion flow loop[J]. Corrosion Science,2015,94:275-287.
【16】ZHAO J,DUAN H,JIANG R. Synergistic corrosion inhibition effect of quinoline quaternary ammonium salt and gemini surfactant in H2S and CO2 saturated brine solution[J]. Corrosion Science,2015,91:108-119.
【17】CHOI Y S,NESIC S,LING S. Effect of H2S on the CO2 corrosion of carbon steel in acidic solutions[J]. Electrochimica Acta,2011,56(4):1752-1760.
【18】吕祥鸿,赵国仙,张建兵,等. 用于集输管线0.5Cr钢在模拟塔里木油田环境中的H2S/CO2腐蚀行为研究[J]. 石油学报,2009,30(5):782-787.
【19】SRINIVASAN S,TEBBAL S. Critical factors in predicting CO2/H2S corrosion in multiphase systems[C]//Corrosion 98.[S.l.]:NACE International,1998.
【20】FIERROG,INGO G M,MANCIA F.XPS investiga-tion on the corrosion behavior of 13Cr-martensitic stainless steel in CO2-H2S-Cl- environments[J]. Corrosion,1989,45(10):814-823.
【21】YUNPING Z,XINGYI C,PING L,et al. Study on the CO2/H2S corrosion prediction technology of buried oil pipelines[J]. Cheminform,2016,47(4):597-604.
【22】WANG Y. Effect of CO2 partial pressure on CO2/H2S corrosion of oil tube steels[J]. Advanced Materials Research,2014,962/965(5):407-410.
【23】YIN Z F,LIU L,ZHANG Y Q,et al. Characteristics and mechanism of corrosion film formation on antisulphur steels in CO2/H2S environments[J]. British Corrosion Journal,2013,47(2):138-144.
【24】RAFAEL E R,MARÍA E R L,TREJO A,et al. Corrosion in aqueous solution of two alkanolamines with CO2 and H2S:N-Methyldiethanolamine+Diethanolamine at 393 K[J]. Industrial & Engineering Chemistry Research,2008,47(14):4726-4735.
【25】ZHOU Q,MA Q,YI Y,et al. H2S/CO2 corrosion behavior of tubular goods under high temperature and high pressure[J]. Chemical Engineering(China),2006(7):370-373.
【26】LIN G F,DONG X C,ZHU S D,et al. Effects of different ions on the corrosion behavior of SM 80SS tubing steel in CO2/H2S containing aqueous solution[J]. Advanced Materials Research,2013,734/737:1367-1373.
【27】FLIETHMANN J,SCHLERKMANN H,SCHWENK W. Autoklaven-untersuchungen der spannungsri bkorrosion von Fe-Cr-Ni-Legierungen in NaCl/CO2/H2S-Medien[J]. Materials & Corrosion,2015,43(10):467-474.
【28】张光华,王腾飞,孙卫玲,等. 硫脲基烷基咪唑啉类缓蚀剂的制备、缓蚀性能及其机理[J]. 材料保护,2011,44(2):21-23.
【29】宁朝辉,崔新安,申明周,等. 咪唑啉酰胺中和缓蚀剂的成膜性能研究[J]. 石油化工腐蚀与防护,2005,22(1):16-19.
【30】高阳,陈洪龄,陈步荣,等. 盐酸溶液中N-烷基苯并咪唑阳离子对碳钢的缓蚀性能[J]. 材料保护,2009,42(7):1-3.
【31】王倩,付朝阳. CO2饱和NaCl溶液中松香基咪唑啉季铵盐的缓蚀吸附行为[J]. 腐蚀科学与防护技术,2012,24(4):319-322.
【32】张忠铧,黄子阳,孙元宁,等. 3Cr抗CO2和H2S腐蚀系列油套管开发[J]. 宝钢技术,2006(3):5-8.
【33】UEDA M,TAKABE H,NICE P I. The development and implementation of a new alloyed steel for oil and gas production wells[C]//Corrosion 2000.[S.l.]:NACE International,2000.
【34】李珣. 井下油套管二氧化碳腐蚀研究[D]. 成都:四川大学,2005.
【35】王少兰,费敬银,林西华,等. 高性能耐蚀管材及超级13Cr研究进展[J]. 腐蚀科学与防护技术,2013,25(4):322-326.
【36】BOUCHET J. SEM,EDS and waxed microstructural characterization of a new enamel used as a protection and thermal barrier[J]. Sci Technol,2001,15(3):345.
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