Cathodic Protection Potential of 9Ni Steel LNG Storage Tanks During Hydrostatic Test Using Seawater
摘 要
9Ni钢是制作液化天然气(LNG)储罐的主要材料。通过电化学法、挂片浸泡法、慢应变速率试验,研究了9Ni钢在模拟海水试压环境中及阴极保护条件下的腐蚀行为。结果表明:阴极保护电位(以下简称阴保电位)为-0.70~-1.00 V(相对于SCE,下同)时,9Ni钢的腐蚀速率由0.235 5 mm/a降至0.022 0~0.004 4 mm/a,保护度均在90%以上;在试压沉降周期内,-0.70 V阴保电位能够满足9Ni钢的耐缝隙腐蚀要求。阴保电位为-0.85~-0.93 V时,9Ni钢主要为韧性断裂,但-0.93 V时断口附近出现大量微裂纹;阴保电位为-0.95 V时,断口出现准解理特征,9Ni钢进入氢脆危险区。因此,为充分保证9Ni钢服役安全,LNG储罐在海水试压过程中,9Ni钢的阴保电位推荐值为-0.70~-0.90 V。
Abstract
9Ni steel is the main material for liquefied natural gas (LNG) storage tents. The corrosion behavior of 9Ni steel in simulated environment of hydrostatic test using seawater and under the condition of cathodic protection was investigated by means of electrochemical method, immersion method and slow strain rate test (SSRT) method. The results showed that when the cathodic protection potential decreased in the rage of -0.70 V (vs. SCE the same below) ~ -1.00 V, the corrosion rate of 9Ni steel decreased from 0.235 5 mm/a to 0.022 0 ~ 0.004 4 mm/a, and the protection degrees all reached above 90%. Also, -0.70 V was able to meet the requirements of crevice corrosion resistance of 9Ni steel during the period of hydrostatic test. When the potential decreased in the range of -0.85 V ~ -0.93 V, 9Ni steel was mainly subject to ductile fracture. A large number of microcracks appeared near the fracture surface. Quasi-cleavage feature was found on the fracture surface at -0.95 V and 9Ni steel entered dangerous zone of hydrogen embrittlement. So in order to ensure the service safety of 9Ni steel, the recommended cathodic protection potential range of 9Ni steel was -0.70 V ~ -0.90 V during hydrostatic test using seawater of LNG storage tanks.
中图分类号 TG174 DOI 10.11973/fsyfh-201905008
所属栏目 试验研究
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收稿日期 2017/10/25
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引用该论文: LIU Xuxia,LIU Xiwu,CUI Xin,CHENG Rongqi. Cathodic Protection Potential of 9Ni Steel LNG Storage Tanks During Hydrostatic Test Using Seawater[J]. Corrosion & Protection, 2019, 40(5): 347
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【6】HARDIE D,CHARLES E A,LOPEZ A H. Hydrogen embrittlement of high strength pipeline steels[J]. Corrosion Science,2006,48(12):4378-4385.
【7】杨兆艳,闫永贵,马力,等. 阴极极化对907钢氢脆敏感性的影响[J]. 腐蚀与防护,2009,30(10):701-703.
【8】丁有元,张维,李成涛,等. 40CrNiMoA高强钢氢脆敏感性和氢含量的关系[J]. 腐蚀与防护,2017,38(7):547-550.
【9】陈祥曦,马力,赵程,等. 阴极保护电位对E460钢氢脆敏感性的影响[J]. 腐蚀与防护,2015,36(11):1026-1029,1071.
【10】李会录,余竹焕,李颖,等. 高强钢氢脆敏感性和氢致附加应力的相关性[J]. 腐蚀与防护,2009,30(10):678-683.
【11】张体明,赵卫民,郭望,等. 阴极保护下X65钢在模拟海水中的氢脆敏感性研究[J]. 中国腐蚀与防护学报,2014,34(4):315-320.
【12】潘大伟,高心心,马力,等. 模拟深海环境中高强钢的阴极保护准则[J]. 腐蚀与防护,2016,37(3):225-229.
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【14】LAJEVARDI A,TAFRESHI H,SHAHRABI T. Investigation of calcareous deposits formation on 5052 aluminium alloy under cathodic polarisation in natural and artificial sea water[J]. Corrosion Engineering,Science and Technology,2011,46(3):249-255.
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