Mechanism of High Temperature Hydrogen Damage and Risk Analysis to Hydrogenation Units
摘 要
近年来国内外多家大型石化公司高温临氢环境中的加氢装置设备与管道发生了腐蚀泄漏事故。根据部分加氢装置风险评估的数据及国内外高温氢损伤机理的研究进展,分析了发生高温氢损伤的关键因素。结果表明:国内部分加氢装置设备与管道选用材料的抗高温氢损伤能力不足,存在较高的风险。因此对这些设备或管道的选材与操作提出了降险的措施与建议,避免或减缓腐蚀的发生。
Abstract
In recent years, corrosion and leakage accidents of equipment and pipeline occurred in hydrogenation units of many large petrochemical companies at high temperature in hydrogen environment at home and abroad. The risk assessment data of some hydrogenation units and the research progress of high temperature hydrogen damage mechanisms at home and abroad were analyzed to understand the key factors of high temperature hydrogen damage. The results show that there was a high risk in the selection of materials for equipment and pipelines in some domestic hydrogenation units at high temperature in hydrogen environment. Therefore, measures and suggestions were proposed to reduce the risk of material selection and operation for these equipment and pipelines, so as to avoid corrosion leakage.
中图分类号 TG174 DOI 10.11973/fsyfh-201908015
所属栏目 失效分析
基金项目 中石化科技开发项目(313064)
收稿日期 2018/11/14
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备注陈炜(1980-),教授级高级工程师,主要从事石化装置基于风险的检验(RBI)工作,13966722745,45894114@qq.com
引用该论文: CHEN Wei,CHEN Xuedong,GU Wangping,ZHOU Yang,HU Jiushao. Mechanism of High Temperature Hydrogen Damage and Risk Analysis to Hydrogenation Units[J]. Corrosion & Protection, 2019, 40(8): 623
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参考文献
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【2】America Petroleum Institute (API). Steels for hydrogen service at elevated temperatures and pressures in petroleum refineries and petrochemical plants:API RP 941-2016. Washington DC:American Petroleum Institute, 2016.
【3】America Petroleum Institute (API). Guidelines for avoiding sulfidation (sulfidic) corrosion failures in oil refineries:API RP 939-C-2009.Washington DC:American Petroleum Institute, 2009.
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【9】陈炜,乔光谱. FREP加氢处理装置风险评估报告:2011-GMRI-FREP-RBI-HTC-01. 合肥:合肥通用机械研究院特种设备检验站,2011.
【10】陈炜,乔光谱. QDLH加氢处理装置风险评估报告:2014-GMRI-QDLH-RBI-07-01. 合肥:合肥通用机械研究院特种设备检验站,2014.
【11】周斌. SCSH加氢裂化装置风险评估报告:2016-GMRI-SCSH-RBI-01. 合肥:合肥通用机械研究院特种设备检验站,2016.
【2】America Petroleum Institute (API). Steels for hydrogen service at elevated temperatures and pressures in petroleum refineries and petrochemical plants:API RP 941-2016. Washington DC:American Petroleum Institute, 2016.
【3】America Petroleum Institute (API). Guidelines for avoiding sulfidation (sulfidic) corrosion failures in oil refineries:API RP 939-C-2009.Washington DC:American Petroleum Institute, 2009.
【4】苏铁健, 李树奎, 王富耻. 热处理对0.14C-1.25Cr-0.5Mo钢的抗氢蚀能力的影响. 特殊钢, 2003, 24(5):22-24.
【5】方煜, 刘小辉. 对美国一起高温氢腐蚀重大事故的反思. 安全、健康和环境, 2014, 14(9):4-7, 11.
【6】MCLAUGHLIN J E. Sulfidation corrosion due to H2S/H2:effect of H2 partial pressure and effect of fluid flow//API Roundtable on Sulfidation Presentation. New Orleans, Louisiana:, 2005.
【7】陈炜,乔光谱. CLSH渣油加氢装置风险评估报告:2015-GMRI-CLSH-RBI-01-01. 合肥:合肥通用机械研究院特种设备检验站,2015.
【8】陈炜,乔光谱. FREP加氢裂化装置风险评估报告:2011-GMRI-FREP-RBI-HCU-01. 合肥:合肥通用机械研究院特种设备检验站,2011.
【9】陈炜,乔光谱. FREP加氢处理装置风险评估报告:2011-GMRI-FREP-RBI-HTC-01. 合肥:合肥通用机械研究院特种设备检验站,2011.
【10】陈炜,乔光谱. QDLH加氢处理装置风险评估报告:2014-GMRI-QDLH-RBI-07-01. 合肥:合肥通用机械研究院特种设备检验站,2014.
【11】周斌. SCSH加氢裂化装置风险评估报告:2016-GMRI-SCSH-RBI-01. 合肥:合肥通用机械研究院特种设备检验站,2016.
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