Effects of Medium Condition on CO2 Corrosion of X65 Pipeline Steel and Its Welded Joint
摘 要
利用开路电位测量、电化学阻抗谱测量和扫描电镜(SEM)观测研究了在含饱和CO2的3.5% NaCl水溶液中不同介质条件对X65管线钢及其焊接接头不同区域CO2腐蚀的影响。结果表明:在pH较低环境中,X65管线钢表面难以形成致密的FeCO3腐蚀产物膜,而在pH较高环境中,即便温度较低也能生成致密的腐蚀产物膜,且温度越高,腐蚀产物膜越致密,X65管线钢的腐蚀速率下降,点蚀加剧;X65管线钢焊接接头不同区域中,母材最先形成致密的腐蚀产物膜,其次是热影响区,最后是焊缝区,但焊缝区形成的腐蚀产物膜较其他两个区域形成的更加致密。
Abstract
The effects of medium condition on CO2 corrosion of X65 pipeline steel and different zones of its welded joint were studied in 3.5% NaCl solution with saturated CO2 by open-circuit potential measurement, electrochemical impedance spectroscopy testing and scanning electron microscopy (SEM) observation. The results show that a dense corrosion product film of FeCO3 was difficult to form on the surface of X65 pipeline steel in low pH environment. But it could form in high pH environment even at a low temperature, the higher the temperature, the denser the corrosion product film. And with the increase of temperature the average corrosion rate of X65 pipeline steel decreased and the pitting corrosion resistance became worse. In the different zones of X65 pipeline steel welded joint, the base metal formed a dense corrosion product film first, followed by the heat affected zone, and finally the weld zone. The product film formed on the weld zone was denser than that formed on the base metal and heat affected zone.
中图分类号 TG172 DOI 10.11973/fsyfh-201910003
所属栏目 试验研究
基金项目 国家科技重大专项子任务(2016ZX05057006)
收稿日期 2018/3/6
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引用该论文: YANG Zhuangchun,CAI Yiyang,ZHU Yesen,HUANG Yi,WANG Xiaona. Effects of Medium Condition on CO2 Corrosion of X65 Pipeline Steel and Its Welded Joint[J]. Corrosion & Protection, 2019, 40(10): 717
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参考文献
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【12】HUANG H H,TSAI W T,LEE J T. The influences of microstructure and composition on the electrochemical behavior of A516 steel weldment[J]. Corrosion Science,1994,36(6):1027-1038.
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