Corrosion Behavior of 1 000 MPa Grade Ultra-High Strength Hot-Dip Galvanized Steel Sheets
摘 要
在中性盐雾模拟的海洋大气环境中,对1 000 MPa级超高强度热镀锌钢板进行了腐蚀加速试验,利用激光共聚焦显微镜、扫描电镜以及电化学试验等手段对盐雾腐蚀不同时间后镀锌钢板的耐腐蚀性能进行了研究。结果表明:镀锌钢板首先发生点蚀,点蚀坑直径15~25 μm且无明显增大趋势,随后逐渐向均匀腐蚀发展;腐蚀产物最初为较为疏松的针絮状,随后发展为较为致密的板带状和团簇状,基体暴露后腐蚀产物以疏松沟壑状为主;锌层腐蚀初期产物主要是Zn(OH)2和ZnO,氯离子则会与锌氧化物结合生成ZnCl和Zn5(OH)8Cl2·H2O,并破坏氧化层,加速腐蚀产物的溶解,盐雾试验较长时间后还会生成Zn5(CO3)2(OH)6,基体腐蚀产物主要为Fe2O3;盐雾试验进行至48 h时,腐蚀产物较为致密,腐蚀速率和腐蚀电流密度均处于较低水平,其中腐蚀速率为0.195 g/(m2·h),腐蚀电流密度为3.83 μA/cm2,相对致密的腐蚀产物对镀锌钢板的全面腐蚀起到明显的抑制作用。
Abstract
The corrosion accelerated test for 1 000 MPa grade ultra-high strength hot-dip galvanized steel sheets was carried out in marine atmospheric environment simulated by neutral salt-spray. The corrosion resistance of galvanized steel sheets after salt-spray corrosion for different periods of time was studied by means of laser confocal microscopy, scanning electron microscopy and electrochemical test. The results show that the galvanized steel sheets corroded as pitting. The pit diameters were 15-25 μm, and there was no obvious increase trend. Subsequently, the corrosion form of the galvanized steel sheets gradually developed toward uniform corrosion. Corrosion products were initial looser needle-like, and subsequently developed into denser ribbons and clusters. After the substrate was exposed, the corrosion products were dominated by loose gully. The primary products of zinc layer corrosion were mainly Zn(OH)2 and ZnO. Chloride ion combined with zinc oxide to form ZnCl and Zn5(OH)8Cl2·H2O, and destroyed the oxide layer and accelerated the dissolution of corrosion products. Zn5(CO3)2(OH)6 was generated after salt-spray test for a long time, and the main corrosion products of matrix were Fe2O3. When the salt-spray test was conducted for 48 h, the corrosion products were dense, and the corrosion rate of 0.195 g/(m2·h) and corrosion current density of 3.83 μA/cm2 were both at a low level. The relatively dense corrosion products could obviously inhibit the overall corrosion of galvanized steel sheets.
中图分类号 TG174 DOI 10.11973/fsyfh-201910004
所属栏目 试验研究
基金项目
收稿日期 2018/3/15
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联系人作者刘李斌(liulbwx@163.com)
引用该论文: LIU Libin,KANG Yonglin,SONG Renbo,JIANG Guangrui,SHANG Ting,TENG Huaxiang. Corrosion Behavior of 1 000 MPa Grade Ultra-High Strength Hot-Dip Galvanized Steel Sheets[J]. Corrosion & Protection, 2019, 40(10): 723
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参考文献
【1】DE AZEVEDO ALVARENGA E, DE FREITAS CUNHA LINS V. Atmospheric corrosion evaluation of electrogalvanized, hot-dip galvanized and galvannealed interstitial free steels using accelerated field and cyclic tests[J]. Surface and Coatings Technology, 2016, 306:428-438.
【2】ASLAM I, LI B, MARTENS R L, et al. Transmission electron microscopy characterization of the interfacial structure of a galvanized dual-phase steel[J]. Materials Characterization, 2016, 120:63-68.
【3】REICHINGER M, BREMSER W, DORNBUSCH M. Interface and volume transport on technical cataphoretic painting:a comparison of steel, hot-dip galvanised steel and aluminium alloy[J]. Electrochimica Acta, 2017, 231:135-152.
【4】MEIRA G R, ANDRADE C, VILAR E O, et al. Analysis of chloride threshold from laboratory and field experiments in marine atmosphere zone[J]. Construction and Building Materials, 2014, 55:289-298.
【5】LIU S, SUN H Y, SUN L J, et al. Effects of pH and Cl- concentration on corrosion behavior of the galvanized steel in simulated rust layer solution[J]. Corrosion Science, 2012, 65(12):520-527.
【6】SUN M, XIAO K, DONG C F, et al. Stress corrosion cracking of ultrahigh strength martensite steel Cr9Ni5MoCo14 in 3.5% NaCl solution[J]. Aerospace Science & Technology, 2014, 36(1):125-131.
【7】EL-MAHDY G A, NISHIKATA A, TSURU T. Electrochemical corrosion monitoring of galvanized steel under cyclic wet-dry conditions[J]. Corrosion Science, 2000, 42(1):183-194.
【8】THÉBAULT F, VUILLEMIN B, OLTRA R, et al. Investigation of self-healing mechanism on galvanized steels cut edges by coupling SVET and numerical modeling[J]. Electrochimica Acta, 2008, 53(16):5226-5234.
【9】THÉBAULT F, VUILLEMIN B, OLTRA R, et al. Protective mechanisms occurring on zinc coated steel cut-edges in immersion conditions[J]. Electrochimica Acta, 2011, 56(24):8347-8357.
【10】PANTAZOPOULOU S J, PAPOULIA K D. Modeling cover-cracking due to reinforcement corrosion in RC structures[J]. Journal of Engineering Mechanics, 2001, 127(4):342-351.
【11】FUJITA S, MIZUNO D. Corrosion and corrosion test methods of zinc coated steel sheets on automobiles[J]. Corrosion Science, 2007, 49(1):211-219.
【12】DILER E, ROUVELLOU B, RIOUAL S, et al. Characterization of corrosion products of Zn and Zn-Mg-Al coated steel in a marine atmosphere[J]. Corrosion Science, 2014, 87(6):111-117.
【13】GRANESE S L, ROSALES B M, FERNANDEZ A. Behavior of Zn in atmospheres containing sulfur dioxide and chloride ions[C]//11th International Corrosion Congress. Florence:International Corrosion Council, 2009.
【14】SUN H Y, LIU S, SUN L J. A Comparative study on the corrosion of galvanized steel under simulated rust layer solution with and without 3.5wt%NaCl[J]. International Journal of Electrochemical Science, 2013, 8(3):3494-3509.
【15】CHEN Z Y, PERSSON D, LEYGRAF C. Initial NaCl-particle induced atmospheric corrosion of zinc-effect of CO2 and SO2[J]. Corrosion Science, 2008, 50(1):111-123.
【16】SVENSSON J E, JOHANSSON L G. A laboratory study of the initial stages of the atmospheric corrosion of zinc in the presence of NaCl; Influence of SO2 and NO2[J]. Corrosion Science, 1993, 34(5):721-740.
【17】LI Y. Corrosion behavior of hot dip zinc and zinc-aluminium coatings on steel in seawater[J]. Bulletin of Materials Science, 2001, 24(4):355-360.
【18】OHTSUKA T, MATSUDA M. In situ Raman spectroscopy for corrosion products of zinc in humidified atmosphere in the presence of sodium chloride precipitate[J]. Corrosion, 2003, 59(5):407-413.
【2】ASLAM I, LI B, MARTENS R L, et al. Transmission electron microscopy characterization of the interfacial structure of a galvanized dual-phase steel[J]. Materials Characterization, 2016, 120:63-68.
【3】REICHINGER M, BREMSER W, DORNBUSCH M. Interface and volume transport on technical cataphoretic painting:a comparison of steel, hot-dip galvanised steel and aluminium alloy[J]. Electrochimica Acta, 2017, 231:135-152.
【4】MEIRA G R, ANDRADE C, VILAR E O, et al. Analysis of chloride threshold from laboratory and field experiments in marine atmosphere zone[J]. Construction and Building Materials, 2014, 55:289-298.
【5】LIU S, SUN H Y, SUN L J, et al. Effects of pH and Cl- concentration on corrosion behavior of the galvanized steel in simulated rust layer solution[J]. Corrosion Science, 2012, 65(12):520-527.
【6】SUN M, XIAO K, DONG C F, et al. Stress corrosion cracking of ultrahigh strength martensite steel Cr9Ni5MoCo14 in 3.5% NaCl solution[J]. Aerospace Science & Technology, 2014, 36(1):125-131.
【7】EL-MAHDY G A, NISHIKATA A, TSURU T. Electrochemical corrosion monitoring of galvanized steel under cyclic wet-dry conditions[J]. Corrosion Science, 2000, 42(1):183-194.
【8】THÉBAULT F, VUILLEMIN B, OLTRA R, et al. Investigation of self-healing mechanism on galvanized steels cut edges by coupling SVET and numerical modeling[J]. Electrochimica Acta, 2008, 53(16):5226-5234.
【9】THÉBAULT F, VUILLEMIN B, OLTRA R, et al. Protective mechanisms occurring on zinc coated steel cut-edges in immersion conditions[J]. Electrochimica Acta, 2011, 56(24):8347-8357.
【10】PANTAZOPOULOU S J, PAPOULIA K D. Modeling cover-cracking due to reinforcement corrosion in RC structures[J]. Journal of Engineering Mechanics, 2001, 127(4):342-351.
【11】FUJITA S, MIZUNO D. Corrosion and corrosion test methods of zinc coated steel sheets on automobiles[J]. Corrosion Science, 2007, 49(1):211-219.
【12】DILER E, ROUVELLOU B, RIOUAL S, et al. Characterization of corrosion products of Zn and Zn-Mg-Al coated steel in a marine atmosphere[J]. Corrosion Science, 2014, 87(6):111-117.
【13】GRANESE S L, ROSALES B M, FERNANDEZ A. Behavior of Zn in atmospheres containing sulfur dioxide and chloride ions[C]//11th International Corrosion Congress. Florence:International Corrosion Council, 2009.
【14】SUN H Y, LIU S, SUN L J. A Comparative study on the corrosion of galvanized steel under simulated rust layer solution with and without 3.5wt%NaCl[J]. International Journal of Electrochemical Science, 2013, 8(3):3494-3509.
【15】CHEN Z Y, PERSSON D, LEYGRAF C. Initial NaCl-particle induced atmospheric corrosion of zinc-effect of CO2 and SO2[J]. Corrosion Science, 2008, 50(1):111-123.
【16】SVENSSON J E, JOHANSSON L G. A laboratory study of the initial stages of the atmospheric corrosion of zinc in the presence of NaCl; Influence of SO2 and NO2[J]. Corrosion Science, 1993, 34(5):721-740.
【17】LI Y. Corrosion behavior of hot dip zinc and zinc-aluminium coatings on steel in seawater[J]. Bulletin of Materials Science, 2001, 24(4):355-360.
【18】OHTSUKA T, MATSUDA M. In situ Raman spectroscopy for corrosion products of zinc in humidified atmosphere in the presence of sodium chloride precipitate[J]. Corrosion, 2003, 59(5):407-413.
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