Microstructure and Wear Resistance of NiCrBSi/WC-Co Composite Coating by Laser Cladding
摘 要
采用同轴送粉激光熔覆技术在42CrMo合金钢基体表面制备WC-Co颗粒增强NiCrBSi复合涂层(NiCrBSi/WC-Co复合涂层),研究了复合涂层的物相组成、显微组织、显微硬度和耐磨性能。结果表明:复合涂层主要由γ-Ni固溶体、WC、FeNi3、B2Co3、CoCx、FeCr0.29Ni0.16C0.06、W3C、Co3W3C6等物相组成;复合涂层顶部为方向杂乱的细小树枝晶,中部为较粗大的柱状树枝晶,底部为垂直于结合界面生长的胞状晶,涂层与基体形成了良好的冶金结合;复合涂层表面的平均硬度为810 HV,远高于基体的(270 HV),磨损质量损失为0.3 mg,远低于基体的(1.9 mg),其磨损机制主要为磨粒磨损;复合涂层可显著提高42CrMo钢基体的耐磨性能。
Abstract
WC-Co particle reinforced NiCrBSi composite coating (NiCrBSi/WC-Co composite coating) was prepared on the surface of 42CrMo alloy steel substrate by coaxial powder feeding laser cladding technique. The phase composition, microstructure, microhardness and wear resistance of the composite coating were investigated. The results show that the primary phases of the composite coating were composed of γ-Ni solid solution, WC, FeNi3, B2Co3, CoCx, FeCr0.29Ni0.16C0.06, W3C and Co3W3C6. There were disoriented fine dendrite crystals at the upper area of the composite coating, massive columnar dendrite crystals in the middle area and cellular crystal which grew perpendicular to the interface at the bottom area. A good metallurgical bonding between coating and substrate was obtained. The average microhardness of the composite coating surface were 810 HV, which was much higher than that of the substrate (270 HV); the wear mass loss was 0.3 mg, which was much lower than that of the substrate (1.9 mg); the wear mechanism was abrasive wear. The composite coating could significantly improve the wear resistance of 42CrMo steel substrate.
中图分类号 TG156.99 DOI 10.11973/jxgccl201911005
所属栏目 材料性能及应用
基金项目 安徽省高等学校自然科学研究重点项目(KJ2015A197);安徽省高校优秀青年人才支持计划重点项目(gxyqZD2016320)
收稿日期 2018/11/15
修改稿日期 2019/10/11
网络出版日期
作者单位点击查看
备注王东生(1978-),男,江苏宜兴人,教授,博士
引用该论文: WANG Dongsheng,TIAN Zongjun. Microstructure and Wear Resistance of NiCrBSi/WC-Co Composite Coating by Laser Cladding[J]. Materials for mechancial engineering, 2019, 43(11): 16~20
王东生,田宗军. 激光熔覆NiCrBSi/WC-Co复合涂层的组织与耐磨性能[J]. 机械工程材料, 2019, 43(11): 16~20
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参考文献
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【2】TAM K F, CHENG F T, MAN H C. Cavitation erosion behavior of laser-clad Ni-Cr-Fe-WC on brass[J]. Materials Research Bulletin, 2002,37(7):1341-1351.
【3】SERRES N, HLAWKA F, COSTIL S,et al. Microstructures and environmental assessment of metallic NiCrBSi coatings manufactured via hybrid plasma spray process[J]. Surface and Coatings Technology, 2010, 205(4):1039-1046.
【4】晁明举, 杨坤, 袁斌, 等. In2O3 对Ni60激光熔覆层的影响[J]. 焊接学报, 2005, 26(8):27-30.
【5】FERNÁNDEZ M R, GARCÍA A, CUETOS J M, et al. Effect of actual WC content on the reciprocating wear of a laser cladding NiCrBSi alloy reinforced with WC[J]. Wear, 2015, 324/325:80-89.
【6】SUN R L, YANG D Z, GUO L X, et al. Laser cladding of Ti-6Al-4V alloy with TiC and TiC+NiCrBSi powders[J]. Surface and Coatings Technology, 2001, 135(2/3):307-312.
【7】VENCL A, MRDAK M, HVIZDOS P. Tribological properties of WC-Co/NiCrBSi and Mo/NiCrBSi plasma spray coatings under boundary lubrication conditions[J]. Tribology in Industry, 2017, 39(2):183-191.
【8】郭纯,陈建敏,周健松,等. WC-Co添加量对激光熔覆镍基涂层微观结构及摩擦学性能的影响[J].材料保护, 2012,45(1):23-26.
【9】DESCHUYTENEER D, PETIT F, GONON M, et al. Processing and characterization of laser clad NiCrBSi/WC composite coatings:Influence of microstructure on hardness and wears[J]. Surface and Coatings Technology, 2015, 283:162-171.
【10】HIDOUCI A, PELLETIER J M, DUCOIN F, et al.Microstructural and mechanical characteristics of laser coatings[J]. Surface and Coatings Technology, 2000, 123(1):17-23.
【11】袁庆龙, 冯旭东, 曹晶晶, 等. 激光熔覆镍基合金涂层微观组织研究[J]. 中国激光, 2010, 37(8):2116-2120.
【12】LUO X, LI J, LI G J. Effect of NiCrBSi content on microstructural evolution, cracking susceptibility and wear behaviors of laser cladding WC/Ni-NiCrBSi composite coatings[J]. Journal of Alloys and Compounds, 2015, 626:102-111.
【13】MAKAROV A V, SOBOLEVA N N, MALYGINA I Y. Role of the strengthening phases in abrasive wear resistance of laser-clad NiCrBSi coatings[J]. Journal of Friction and Wear, 2017, 38(4):272-278.
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