Performance of a Reference Electrode in High-temperature Fluoride Salt Environment
摘 要
制备了一种可用于高温氟盐环境的参比电极,该参比电极通过内外两个热解氮化硼套管,保护石墨管体不受高温氟盐腐蚀作用。采用电位差测试及高温氟盐试验等方法考察了其在高温氟盐中的稳定性。结果表明:该参比电极的稳定性不会因使用次数的增加而变差,在14 400 s内,其电位差始终维持在2.4~2.8 mV;该参比电极还具有良好的能斯特性能、可逆性、重复利用性。在高温氟盐环境的相关研究中,该参比电极具有较好的应用前景。
Abstract
A reference electrode used in high temperature fluoride salt environment was prepared. Graphite tube was protected from high temperature fluoride salt corrosion by internal and external pyrolytic boron nitride tubes. The stability of the reference electrode in high temperature fluoride salt environment was investigated by potential difference (ΔE)test and high temperature fluoride salt test. The results show that the stability of the reference electrode did not deteriorate due to the increase of uses,and ΔE was always maintained at 2.4 mV to 2.8 mV within 14 400 s. The reference electrode had good Nernst property, reversibility and reusability. In the related research of high temperature fluoride salt environment, the reference electrode had a good application prospect.
中图分类号 TG172.82 DOI 10.11973/fsyfh-202001003
所属栏目 试验研究
基金项目 国家核电技术有限公司资助项目(SNP-KJ-CX-2014-21)
收稿日期 2019/3/12
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引用该论文: WANG Feng. Performance of a Reference Electrode in High-temperature Fluoride Salt Environment[J]. Corrosion & Protection, 2020, 41(1): 14
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参考文献
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【4】ZHU H M, LI B C, CHEN M H, et al. AlN coatings on Hastelloy-N alloy offering superior corrosion resistance in LiF-KF-NaF molten salt[J]. Journal of Fluorine Chemistry,2018,213:80-86.
【5】FABRE S, CABET C, CASSAYRE L, et al. Use of electrochemical techniques to study the corrosion of metals in model fluoride melts[J]. Journal of Nuclear Materials,2013,441(1/2/3):583-591.
【6】BRONSTEIN H R, MANNING D L. Lanthanum trifluoride as a membrane in a reference electrode for use in certain molten fluorides[J]. Journal of the Electrochemical Society,1972,119(2):125-128.
【7】KONTOYANNIS C G. Pyrolytic boron nitride coated graphite as a container of reference electrodes for molten fluorides[J]. Electrochimica Acta,1995,40(15):2547-2551.
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