含板状WC晶粒硬质合金的研究进展
Research Progress of Cemented Carbide with Plate-Like WC Grains
摘 要
结合WC晶粒的结构及其板状晶形成机理，从制备原料、球磨工艺、烧结工艺及非均匀结构等方面对含板状WC晶粒硬质合金的研究进展进行综述，指出了板状晶硬质合金现阶段所面临的问题及未来发展前景。
板状WC晶粒
制备工艺
cemented carbide
plate-like WC grain
preparation process
Abstract
Combined with the structure of WC grain and its panarization mechanismmechanism, The research progress of cemented carbide with plate-like WC grains is reviewed from aspects of raw materials, ball milling, sintering processes and inhomogeneous structure. The problems and future development prospect of plate-like grain cemented carbide are proposed.
中图分类号 TG146 DOI 10.11973/jxgccl202004001
所属栏目 综述
基金项目 国家自然科学基金青年基金资助项目（51705228）；广东省自然科学基金面上项目（2018A030307017）；湛江市财政科技专项竞争性分配项目（171213141910467）；湛江市非资助科技攻关计划项目（2019B01078）
收稿日期 2019/9/16
修改稿日期 2020/2/29
网络出版日期
作者单位点击查看
备注夏小群(1981-),女,湖北仙桃人,讲师,硕士
引用该论文: XIA Xiaoqun,GONG Manfeng,LI Meng,LIAN Haishan. Research Progress of Cemented Carbide with Plate-Like WC Grains[J]. Materials for mechancial engineering, 2020, 44(4): 1～6
夏小群,弓满锋,李萌,连海山. 含板状WC晶粒硬质合金的研究进展[J]. 机械工程材料, 2020, 44(4): 1～6
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参考文献
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【3】BRUN M K,NEURGAONKAR R R,STUBICAN V S.Precipitation studies in the system WC-tic[J].Journal of the American Ceramic Society, 1975,58(9/10):392-395.
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【5】KINOSHITA S,SAITO T,KOBAYASHI M,et al.Microstructure and mechanical properties of new WC-Co base cemented carbide having,highly oriented plate-like triangular prismatic WC grains[J].Journal of the Japan Society of Powder and Powder Metallurgy, 2000,47(5):526-533.
【6】KINOSHITA S,KOBAYASHI M,TANIGUCHI Y,et al.Effects of starting powder size and ball-milling time on microstructure of WC-Co base cemented carbides prepared from W+C+Co base mixed powder[J].Journal of the Japan Society of Powder and Powder Metallurgy, 2003,50(5):377-384.
【7】KINOSHITA S,SAITO T,KOBAYASHI M,et al.Mechanisms for formation of highly oriented plate-like triangular prismatic WC grains in WC-Co base cemented carbides prepared from W and C instead of WC[J].Journal of the Japan Society of Powder and Powder Metallurgy, 2001,48(1):51-60.
【8】KOBAYASHI M, KITAMURA K, KINOSHITA S.Plate-crystalline tungsten carbide containing hard alloy, composition for forming plate-crystalline tungstencarbide and process for preparing said hard alloy:EP0759480A1[P]. 1997-02-26.
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【11】张卫兵,吴志坚,袁红梅.片晶增韧硬质合金研究进展[J].硬质合金, 2013, 30(6):343-350.
【12】ZHANG L,TIAN W,CHEN Y, et al. Fine platelet-like grained WC-Co cemented carbides:Preparation, characterization, properties and application in PVD coating substrates[J].International Journal of Refractory Metals and Hard Materials, 2017,64:135-142.
【13】ZHANG L,CHEN S,WANG Y J, et al.Tungsten carbide platelet-containing cemented carbide with yttrium containing dispersed phase[J].Transactions of Nonferrous Metals Society of China, 2008, 18(1):104-108.
【14】朱丽慧,刘坤,李志林.含板状WC晶粒硬质合金的强韧化机制研究[J].稀有金属材料与工程,2011,40(增刊2):443-446.
【15】吴恩熙,汪秀全,曾青,等.含板状WC晶粒硬质合金制备方法的研究[J].硬质合金,2006,23(2):75-78.
【16】BRUN M K, NEURGAONKAR R R, STUBICAN V S. Precipitation studies in the system WC-TiC[J].Journal of the American Ceramic Society,1975,58(9/10):392-395.
【17】李志林,朱丽慧.含板状WC晶粒WC-10%Co硬质合金的组织和性能[J].中南大学学报(自然科学版),2010,41(2):521-525.
【18】SHATOV A V,FIRSTOV S A,SHATOVA I V.The shape of WC crystals in cemented carbides[J].Materials Science and Engineering:A, 1998,242(1/2):7-14.
【19】张立,陈述,张传福,等.含板状晶WC双模组织结构硬质合金的研究[J].稀有金属,2004,28(6):979-982.
【20】汪秀全.含板状WC晶粒硬质合金的制备[D].长沙:中南大学, 2006.
【21】SHI Z X, LI J R, LIU S Z, et al. Effect of Hf on the microstructures and stress rupture properties of DD6 single crystal superalloy[J]. Rare Metal Materials and Engineering, 2010,39(8):1334-1338.
【22】雷纯鹏,马运柱,刘文胜,等.新型含片状晶WC-10%Co硬质合金的制备及其性能研究[J].稀有金属,2017,41(4):337-342.
【23】KINOSHITA S, KOBAYASHI M, HAYASHI K. High temperature strength of WC-Co base cemented carbide having highly oriented plate-like triangular prismatic WC grains[J]. Journal of the Japan Society of Powder and Powder Metallurgy, 2002, 49(4):299-305.
【24】李炯义,曹顺华,林信平.盘状WC晶粒硬质合金研究进展[J].粉末冶金技术,2005,23(5):378-382.
【25】张立, 吴厚平, 陈述,等.一种具有高硬度高韧性双高性能WC基硬质合金的制备方法:102061401A[P]. 2011-05-18.
【26】ZHANG L,CHEN S,CHENG X,et al.Effects of cubic carbides and La additions on WC grain morphology,hardness and toughness of WC-Co alloys[J].Transactions of Nonferrous Metals Society of China, 2012,22(7):1680-1685.
【27】KITAMURA K,KOBAYASHI M,HAYASHI K.Microstructural development and properties of new WC-Co base hardmetal prepared from CoxWyCz+C instead of WC[J].Journal of the Japan Society of Powder and Powder Metallurgy, 2001,48(7):621-628.
【28】SOMMER M,SCHUBERT W D,ZOBETZ E,et al.On the formation of very large WC crystals during sintering of ultrafine WC-Co alloys[J].International Journal of Refractory Metals and Hard Materials, 2002,20(1):41-50.
【29】郭瑜,李志友,熊慧文.η相粉末的加入对WC-10Co硬质合金组织与性能的影响[J].粉末冶金材料科学与工程,2016,21(5):702-709.
【30】BAUD S,THÉVENOT F.Microstructures and mechanical properties of liquid-phase sintered seeded silicon carbide[J].Materials Chemistry and Physics, 2001,67(1/2/3):165-174.
【31】YANG Q M,DENG D F,LI J Z,et al.Fabrication and mechanical properties of WC-10Co cemented carbides with plate-like WC grains[J].Journal of Alloys and Compounds, 2019,803:860-865.
【32】雷纯鹏,唐建成,刘刚,等.W粉末的形貌结构对板状晶硬质合金的组织与性能的影响[J].稀有金属材料与工程,2016,45(8):2146-2149.
【33】朱敏,戴乐阳,曹彪, 等.一种电晕放电等离子体辅助高能球磨机:2780327Y[P]. 2006-5-17.
【34】朱敏,鲁忠臣,胡仁宗, 等.介质阻挡放电等离子体辅助球磨及其在材料制备中的应用[J].金属学报, 2016, 52(10):1239-1248.
【35】陈志鸿.放电等离子体辅助球磨机的改进及其效能的研究[D].广州:华南理工大学, 2016.
【36】DAI L Y,LIN S F,CHEN J F,et al.Synthesis of nano-WC by high-energy ball milling[J].Materials Science Forum, 2013,745/746:327-334.
【37】王为.WC-Co硬质合金中WC的形态和双尺度结构对其力学性能的影响[D].广州:华南理工大学, 2017.
【38】KOBAYASHI M, YAMAYA S.Investigation of cemented tungsten carbides with twinned WC grains[C]//10th Plansee Seminar. Reutte:Plansee A G, 1981:597-612.
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