Microbiologically Influenced Corrosion Characteristics of Marine Q235 Carbon Steel Induced by Attachment of Marine Microalgae
摘 要
研究了在含三角褐指藻的人工海水(含藻海水)中,循环光照12 h/黑暗12 h、光照、黑暗条件下船用Q235碳钢的腐蚀行为,以及腐蚀7 d后的电化学性能,并与无藻海水中的进行了对比,分析了三角褐指藻的生命活动对碳钢腐蚀行为的影响。结果表明:在含藻海水中,光照条件下,氧气的去极化反应占主导,碳钢表面发生点蚀,腐蚀产物主要为γ-FeOOH;黑暗条件下,CO2腐蚀导致碳钢表面发生均匀腐蚀,腐蚀产物主要为FeCO3;循环光照12 h/黑暗12 h条件下两种腐蚀方式共同作用,腐蚀产物由γ-FeOOH、Fe3O4和FeCO3组成;与在无藻海水中浸泡7 d后的相比,在含藻海水中,不同光照条件下浸泡7 d后,碳钢的电荷转移电阻减小,自腐蚀电流密度增大。
Abstract
The corrosion behavior of marine Q235 carbon steel in artificial seawater with Phaeodactylum tricornutum (seawater with algae) under cyclic light 12 h/dark 12 h, continuous light, and continuous dark conditions, and the electrochemistry performance after corrosion for 7 days were studied, compared with that in the seawater without algae. The effects of the life activity of Phaeodactylum tricornutum on the corrosion behavior of carbon steel were analyzed. The results show that in the seawater with algae, the depolarization reaction of oxygen was dominant under continuous light condition, resulting in pitting on the carbon steel surface, and the corrosion product was γ-FeOOH. Under the condition of continuous dark, carbon dioxide corrosion caused uniform corrosion of Q235 carbon steel surface, and the corrosion product was FeCO3. The two types of corrosion methods were combined under the cyclic light 12 h/dark 12 h condition, and the corrosion products consisted of γ-FeOOH, Fe3O4 and FeCO3. In the seawater with algae, the charge transfer resistance of carbon steel decreased and the self-corrosion current density increased after immersion under different light conditions for 7 days, compared with that in the seawater without algae.
中图分类号 TB304 DOI 10.11973/jxgccl202004002
所属栏目 试验研究
基金项目 工业和信息化部高技术船舶科研计划资助项目(工信部联装[2016]547号)
收稿日期 2019/11/6
修改稿日期 2020/3/6
网络出版日期
作者单位点击查看
备注张晗(1993-),男,山东济南人,硕士研究生
引用该论文: ZHANG Han,BAI Xiuqin,HE Xiaoyan,YUAN Chengqing. Microbiologically Influenced Corrosion Characteristics of Marine Q235 Carbon Steel Induced by Attachment of Marine Microalgae[J]. Materials for mechancial engineering, 2020, 44(4): 7~15
张晗,白秀琴,贺小燕,袁成清. 船用Q235碳钢的海洋微藻附着诱导微生物腐蚀特性[J]. 机械工程材料, 2020, 44(4): 7~15
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参考文献
【1】BAI P P, ZHAO H, ZHENG S Q, et al. Initiation and developmental stages of steel corrosion in wet H2S environments[J]. Corrosion Science, 2015, 93:109-119.
【2】LV L, YUAN S J, ZHENG Y, et al. Surface modification of mild steel with thermally cured antibacterial poly(vinylbenzyl chloride)-polyaniline bilayers for effective protection against sulfate reducing bacteria induced corrosion[J]. Industrial & Engineering Chemistry Research, 2014, 53(31):12363-12378.
【3】HERNANDEZ M, STAIA M H, PUCHI-CABRERA E S. Evaluation of microstructure and mechanical properties of nitrided steels[J]. Surface and Coatings Technology, 2008, 202(10):1935-1943.
【4】尹衍升, 董丽华,刘涛.海洋材料的微生物附着腐蚀[M]. 北京:科学出版社, 2012.
【5】LIU H W,XU D K,DAO A Q, et al. Study of corrosion behavior and mechanism of carbon steel in the presence of Chlorella vulgaris[J].Corrosion Science, 2015,101:84-93.
【6】CHAMBERS L D, STOKES K R, WALSH F C, et al. Modern approaches to marine antifouling coatings[J]. Surface and Coatings Technology, 2006, 201(6):3642-3652.
【7】KRISHNAN S,WANG N,OBER C K, et al. Comparison of the fouling release properties of hydrophobic fluorinated and hydrophilic PEGylated block copolymer surfaces:Attachment strength of the Diatom Navicula and the green alga Ulva[J].Biomacromolecules, 2006,7(5):1449-1462.
【8】MARCONNET C, DAGBERT C, ROY M, et al. Stainless steel ennoblement in freshwater:From exposure tests to mechanisms[J]. Corrosion Science, 2008, 50(8):2342-2352.
【9】BAI P P, ZHENG S Q, CHEN C F. Electrochemical characteristics of the early corrosion stages of API X52 steel exposed to H2S environments[J]. Materials Chemistry and Physics, 2015, 149/150:295-301.
【10】XIAO K, DONG C F, LI X G, et al. Corrosion products and formation mechanism during initial stage of atmospheric corrosion of carbon steel[J]. Journal of Iron and Steel Research International, 2008, 15(5):42-48.
【11】MCLNTIRE G, LIPPERT J, YUDELSON J. The effect of dissolved CO2 and O2 on the corrosion of iron[J]. Corrosion, 1990, 46(2):91-95.
【12】OGUNDELE G I, WHITE W E. Some observations on corrosion of carbon steel in aqueous environments containing carbon dioxide[J]. Corrosion, 1986,42(2):71-78.
【13】DEWAARD C, WILLIAMS D E. Prediction of carbonic acid corrosion in natural gas pipelines[J]. Industrial Finishing and Surface Coatings, 1976, 28(340):24-26.
【2】LV L, YUAN S J, ZHENG Y, et al. Surface modification of mild steel with thermally cured antibacterial poly(vinylbenzyl chloride)-polyaniline bilayers for effective protection against sulfate reducing bacteria induced corrosion[J]. Industrial & Engineering Chemistry Research, 2014, 53(31):12363-12378.
【3】HERNANDEZ M, STAIA M H, PUCHI-CABRERA E S. Evaluation of microstructure and mechanical properties of nitrided steels[J]. Surface and Coatings Technology, 2008, 202(10):1935-1943.
【4】尹衍升, 董丽华,刘涛.海洋材料的微生物附着腐蚀[M]. 北京:科学出版社, 2012.
【5】LIU H W,XU D K,DAO A Q, et al. Study of corrosion behavior and mechanism of carbon steel in the presence of Chlorella vulgaris[J].Corrosion Science, 2015,101:84-93.
【6】CHAMBERS L D, STOKES K R, WALSH F C, et al. Modern approaches to marine antifouling coatings[J]. Surface and Coatings Technology, 2006, 201(6):3642-3652.
【7】KRISHNAN S,WANG N,OBER C K, et al. Comparison of the fouling release properties of hydrophobic fluorinated and hydrophilic PEGylated block copolymer surfaces:Attachment strength of the Diatom Navicula and the green alga Ulva[J].Biomacromolecules, 2006,7(5):1449-1462.
【8】MARCONNET C, DAGBERT C, ROY M, et al. Stainless steel ennoblement in freshwater:From exposure tests to mechanisms[J]. Corrosion Science, 2008, 50(8):2342-2352.
【9】BAI P P, ZHENG S Q, CHEN C F. Electrochemical characteristics of the early corrosion stages of API X52 steel exposed to H2S environments[J]. Materials Chemistry and Physics, 2015, 149/150:295-301.
【10】XIAO K, DONG C F, LI X G, et al. Corrosion products and formation mechanism during initial stage of atmospheric corrosion of carbon steel[J]. Journal of Iron and Steel Research International, 2008, 15(5):42-48.
【11】MCLNTIRE G, LIPPERT J, YUDELSON J. The effect of dissolved CO2 and O2 on the corrosion of iron[J]. Corrosion, 1990, 46(2):91-95.
【12】OGUNDELE G I, WHITE W E. Some observations on corrosion of carbon steel in aqueous environments containing carbon dioxide[J]. Corrosion, 1986,42(2):71-78.
【13】DEWAARD C, WILLIAMS D E. Prediction of carbonic acid corrosion in natural gas pipelines[J]. Industrial Finishing and Surface Coatings, 1976, 28(340):24-26.
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