Microscale Quasi-Static Contact Mechanical Properties of Plasma Molybdenum Gradient Modified Layer on Pure Titanium Surface
摘 要
采用双层辉光等离子表面合金化技术,在TA2纯钛基体表面制备钼梯度改性层,对改性层截面形貌和元素分布进行分析,并研究改性层的微尺度准静态接触力学性能。结果表明:钼梯度改性层均匀致密,厚度约为12.0 μm,由厚度2.7 μm的沉积层与厚度9.3 μm的扩散层组成;钼、钛元素含量沿厚度方向呈梯度变化,改性层与基体形成良好的冶金结合;改性层的硬度和弹性模量分别为13.82,264.00 GPa,比基体的分别增大了10.87,142.38 GPa,改性层具有较高的强度和良好的塑性;当试验载荷为15 N时,微米压入深度接近15 μm,复合硬度和弹性模量与基体的相近,改性层的强化作用完全失效。
Abstract
The molybdenum gradient modified layer was prepared on the surface of TA2 pure titanium substrate by double glow plasma surface alloying technique. The cross section morphology and element distribution of the modified layer were analyzed, and the microscale quasi-static contact mechanical property of the modified layer were studied. The results show that the molybdenum gradient modified layer was uniform and compact with the thickness of 12 μm, and was composed of the deposition layer with 2.7 μm thickness and the diffusion layer with 9.3 μm thickness. The content of Mo and Ti element changed in gradient along the thickness direction, and the modified layer had a good metallurgical bond with the substrate. The hardness and elastic modulus of the modified layer were 13.82, 142.96 GPa, which were 10.87, 142.38 GPa larger than those of the substrate, respectively, indicating that the modified layer had high strength and good plasticity. When the test load was 15 N, the micro-indentation depth was nearly 15 μm, and the composite hardness and elastic modulus were close to those of the substrate, indicating that the strengthening effect of the modified layer was completely ineffective.
中图分类号 TG146.2 DOI 10.11973/jxgccl202005015
所属栏目 专题报道(金属材料表面处理)
基金项目 国家自然科学基金资助项目(51671140,21878201);山西省重大专项项目(20181102013)
收稿日期 2019/12/5
修改稿日期 2020/4/2
网络出版日期
作者单位点击查看
备注杨曌(1994-),女,山西运城人,硕士研究生
引用该论文: YANG Zhao,DONG Yaqian,WANG Shuaikang,MA Yong,YU Shengwang,WU Yucheng,TANG Bin. Microscale Quasi-Static Contact Mechanical Properties of Plasma Molybdenum Gradient Modified Layer on Pure Titanium Surface[J]. Materials for mechancial engineering, 2020, 44(5): 77~81
杨曌,董雅倩,王帅康,马永,于盛旺,吴玉程,唐宾. 纯钛表面等离子渗钼梯度改性层的微尺度准静态接触力学性能[J]. 机械工程材料, 2020, 44(5): 77~81
共有人对该论文发表了看法,其中:
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】WEI D B,ZHANG P Z,YAO Z J,et al.Double glow plasma chromizing of Ti6Al4V alloys:Impact of working time,substrate-target distance,argon pressure and surface temperature of substrate[J].Vacuum, 2015,121:81-87.
【2】王泽莹,张峰,王振霞,等.纯钛表面等离子渗镍合金层的显微组织及摩擦学性能[J].机械工程材料,2012,36(4):73-76.
【3】安月平,于东升,王从曾,等.钛合金表面离子渗钼及耐磨性研究[J].热处理,2011,26(1):50-53.
【4】QIN L,QIN Y M,LIU X P,et al.Mechanism of enhanced wear-resistance of the Ti-Mo modification layer[J].Materials Science Forum, 2005,475:3947-3950.
【5】YAO X H,TANG B,FAN A L,et al.Structure and corrosion behaviours of Mo modified titanium in saliva[J].Journal of Wuhan University of Technology (Materials Science Edition), 2010,25(4):570-573.
【6】徐重.等离子表面冶金学[M].北京:科学出版社,2008:22-39.
【7】WANG Z X,HE Z Y,WANG Y Q,et al.Microstructure and tribological behaviors of Ti6Al4V alloy treated by plasma Ni alloying[J].Applied Surface Science, 2011,257(23):10267-10272.
【8】张云露,骆心怡,何斐.Ti6Al4V钛合金表面双层辉光等离子W-Mo共渗及其腐蚀磨损性能研究[J].稀有金属材料与工程,2013,42(1):204-210.
【9】郑亮,李东,贺聪聪,等.钛合金表面激光熔覆Ti-Mo-Si涂层组织研究[J].稀有金属,2016,40(11):1094-1099.
【10】UREÑA J,TSIPAS S,PINTO A M,et al.Corrosion and tribocorrosion behaviour of β-type Ti-Nb and Ti-Mo surfaces designed by diffusion treatments for biomedical applications[J].Corrosion Science, 2018,140:51-60.
【11】秦林,唐宾,刘道新,等.钛合金Ti6Al4V表面Mo-N改性层的摩擦性能研究[J].稀有金属材料与工程,2005,34(9):1465-1468.
【12】于海峰,马永,张翔宇,等.纯钛表面钼改性层的抗磨损性能[J].热加工工艺,2013,42(20):174-178.
【13】TANG B,WU P Q,LI X Y,et al.Tribological behavior of plasma Mo-N surface modified Ti-6Al-4V alloy[J].Surface and Coatings Technology, 2004,179(2/3):333-339.
【14】何维,钟海长,夏秀文,等. Ti-Mo-Sn三元系合金相图473 K等温截面[C]//第十四届全国相图会议暨国际相图与材料设计研讨会论文集.长沙:中国物理学会相图专业委员会, 2008:271-274.
【2】王泽莹,张峰,王振霞,等.纯钛表面等离子渗镍合金层的显微组织及摩擦学性能[J].机械工程材料,2012,36(4):73-76.
【3】安月平,于东升,王从曾,等.钛合金表面离子渗钼及耐磨性研究[J].热处理,2011,26(1):50-53.
【4】QIN L,QIN Y M,LIU X P,et al.Mechanism of enhanced wear-resistance of the Ti-Mo modification layer[J].Materials Science Forum, 2005,475:3947-3950.
【5】YAO X H,TANG B,FAN A L,et al.Structure and corrosion behaviours of Mo modified titanium in saliva[J].Journal of Wuhan University of Technology (Materials Science Edition), 2010,25(4):570-573.
【6】徐重.等离子表面冶金学[M].北京:科学出版社,2008:22-39.
【7】WANG Z X,HE Z Y,WANG Y Q,et al.Microstructure and tribological behaviors of Ti6Al4V alloy treated by plasma Ni alloying[J].Applied Surface Science, 2011,257(23):10267-10272.
【8】张云露,骆心怡,何斐.Ti6Al4V钛合金表面双层辉光等离子W-Mo共渗及其腐蚀磨损性能研究[J].稀有金属材料与工程,2013,42(1):204-210.
【9】郑亮,李东,贺聪聪,等.钛合金表面激光熔覆Ti-Mo-Si涂层组织研究[J].稀有金属,2016,40(11):1094-1099.
【10】UREÑA J,TSIPAS S,PINTO A M,et al.Corrosion and tribocorrosion behaviour of β-type Ti-Nb and Ti-Mo surfaces designed by diffusion treatments for biomedical applications[J].Corrosion Science, 2018,140:51-60.
【11】秦林,唐宾,刘道新,等.钛合金Ti6Al4V表面Mo-N改性层的摩擦性能研究[J].稀有金属材料与工程,2005,34(9):1465-1468.
【12】于海峰,马永,张翔宇,等.纯钛表面钼改性层的抗磨损性能[J].热加工工艺,2013,42(20):174-178.
【13】TANG B,WU P Q,LI X Y,et al.Tribological behavior of plasma Mo-N surface modified Ti-6Al-4V alloy[J].Surface and Coatings Technology, 2004,179(2/3):333-339.
【14】何维,钟海长,夏秀文,等. Ti-Mo-Sn三元系合金相图473 K等温截面[C]//第十四届全国相图会议暨国际相图与材料设计研讨会论文集.长沙:中国物理学会相图专业委员会, 2008:271-274.
相关信息