磁场对车轴钢在含氯离子碳酸氢钠溶液中阳极过程的影响
Effect of Magnetic Field on Anodic Process of Axle Steel in Sodium Bicarbonate Solution with Chlorides
摘 要
采用电化学测试结合表面形貌观察研究了0.4 T磁场对车轴钢在碳酸氢钠溶液及含氯离子碳酸氢钠溶液中阳极过程的影响。极化曲线测试结果表明：0.4 T磁场显著增加预钝化区的电流密度；对碳酸氢钠溶液中的过钝化区无显著影响，但增加含氯离子碳酸氢钠溶液中过钝化区的阳极电流；试样在施加磁场的溶液中经极化曲线测试后的表面点蚀情况比无磁场条件下的严重。恒电位极化测试结果表明：在极化曲线预钝化区内，磁场会使电流衰减速率变缓慢；在钝化区内，磁场会使初始电流密度增大、点蚀数量增多；在过钝化区内，磁场显著增大电流密度并导致更多和更大的点蚀。
磁场
阳极溶解
碳酸氢钠
氯离子
点蚀
axle steel
magnetic field
anodic dissolution
sodium bicarbonate
chloride
pitting corrosion
Abstract
The effect of 0.4 T magnetic field on the anodic process of axle steel in sodium bicarbonate solution with or without chloride ions was studied by electrochemical test combined with surface morphology observation. Results of potentiodynamic polarization curves showed that 0.4 T magnetic field increased the anodic current density in the prepassive range, didn't affect the transpassive range in sodium bicarbonate solution, but increased the current density in the transpassive range in sodium bicarbonate solution with chlorides. Pitting on the surface of the sample after the polarization curve test in the solution to which the magnetic field was applied was more serious than that without the magnetic field. Results of potentiostatic polarization test showed that: in the pre-passivation zone of the polarization curve, the magnetic field slowed the current decay rate. In the passivation zone, the magnetic field increased the initial current density and increased the number of pitting. In the transpassive zone, the magnetic field significantly increased the current density and caused more and larger pitting.
中图分类号 TG174 DOI 10.11973/fsyfh-202007008
所属栏目 试验研究
基金项目 国家重点研发计划（2017YFB0703002）；国家自然科学基金（51571183）
收稿日期 2019/10/15
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引用该论文: NING Fei,ZHANG Kun,CAI Shuangwei,Lü Zhanpeng,TANG Yuanjie,DONG Haiying,MA Jiarong,CUI Tongming. Effect of Magnetic Field on Anodic Process of Axle Steel in Sodium Bicarbonate Solution with Chlorides[J]. Corrosion & Protection, 2020, 41(7): 49
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参考文献
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【2】TACKEN R A,JANSSEN L J J. Applications of magnetoelectrolysis[J]. Journal of Applied Electrochemistry,1995,25(1):1-5.
【3】MONZON L M A,COEY J M D. Magnetic fields in electrochemistry:The Lorentz force. A mini-review[J]. Electrochemistry Communications,2014,42(5):38-41.
【4】MONZON L M A,COEY J. Magnetic fields in electrochemistry:The Kelvin force. A mini-review[J]. Electrochemistry Communications,2014,42(5):42-45.
【5】WANG X P,ZHAO J J,HU Y P,et al. Effects of the Lorentz force and the gradient magnetic force on the anodic dissolution of nickel in HNO3+NaCl solution[J]. Electrochimica Acta,2014,117:113-119.
【6】LINHARDT P,BALL G,SCHLEMMER E. Electrochemical investigation of chloride induced pitting of stainless steel under the influence of a magnetic field[J]. Corrosion Science,2005,47(7):1599-1603.
【7】LU Z P,HUANG D L,YANG WU,et al. Effects of an applied magnetic field on the dissolution and passivation of iron in sulphuric acid[J]. Corrosion Science,2003,45(10):2233-2249.
【8】LU Z P,HUANG D L,YANG W. Probing into the effects of a magnetic field on the electrode processes of iron in sulphuric acid solutions with dichromate based on the fundamental electrochemistry kinetics[J]. Corrosion Science,2005,47(6):1471-1492.
【9】LU Z P,SHOJI T,YANG W. Anomalous surface morphology of iron generated after anodic dissolution under magnetic fields[J]. Corrosion Science,2010,52(8):2680-2686.
【10】LU Z P,HUANG C B,HUANG D L,et al. Effects of a magnetic field on the anodic dissolution,passivation and transpassivation behaviour of iron in weakly alkaline solutions with or without halides[J]. Corrosion Science,2006,48(10):3049-3077.
【11】LI H J,XIONG Q,LU Z P,et al. A magnetic field induced undulated surface and the shift of the active/passivation transition threshold of iron in a sulfuric acid solution[J]. Corrosion Science,2017,129:179-191.
【12】WANG C. Anodic dissolution of iron in a magnetic field with holographic microphotography[J]. Journal of the Electrochemical Society,1996,143(12):L283.
【13】SUEPTITZ R,KOZA J,UHLEMANN M,et al. Magnetic field effect on the anodic behaviour of a ferromagnetic electrode in acidic solutions[J]. Electrochimica Acta,2009,54(8):2229-2233.
【14】LU Z P,CHEN J M. Magnetic field effects on anodic polarisation behaviour of iron in neutral aqueous solutions[J]. British Corrosion Journal,2000,35(3):224-228.
【15】陈珍,吕战鹏,肖茜,等. 磁场对铁在含亚硝酸根的氯化钠溶液中不同电位下极化电流的影响[J]. 腐蚀与防护,2017,38(1):6-10.
【16】LIU Y M,LIU L M,STRATMAN B,et al. Multiaxial fatigue reliability analysis of railroad wheels[J]. Reliability Engineering & System Safety,2008,93(3):456-467.
【17】BERNASCONI A,FILIPPINI M,FOLETTI S,et al. Multiaxial fatigue of a railway wheel steel under non-proportional loading[J]. International Journal of Fatigue,2006,28(5/6):663-672.
【18】REN X C,WU F,XIAO F,et al. Corrosion induced fatigue failure of railway wheels[J]. Engineering Failure Analysis,2015,55:300-316.
【19】ZERBST U,BERETTA S. Failure and damage tolerance aspects of railway components[J]. Engineering Failure Analysis,2011,18(2):534-542.
【20】BERETTA S,CARBONI M,FIORE G,et al. Corrosion-fatigue of A1N railway axle steel exposed to rainwater[J]. International Journal of Fatigue,2010,32(6):952-961.
【21】MOON A,SANGAL S,MONDAL K. Corrosion behaviour of new railway axle steels[J]. Transactions of the Indian Institute of Metals,2013,66(1):33-41.
【22】李杰,李启磊. 高铁与城际列车并列运行电磁射频辐射发射测试分析[J]. 南京工业职业技术学院学报,2017,17(1):1-3.
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