Establishment of Near-Infrared Prediction Models for Toluene Insoluble Substance and Other 3 Indexes of Medium Temperature Coal Pitch
摘 要
采用仪器所配的积分球分析模块采集了中温煤沥青样品的近红外漫反射光谱图,采用一阶导数(SG1D)、标准正态变化(SNV)等方法对所得的原始光谱进行了预处理。分别采用GB/T 2292-2018、GB/T 2293-2019、GB/T 2294-2019、GB/T 8727-2008测定了样品的甲苯不溶物(TI)含量、喹啉不溶物(QI)含量、软化点和结焦值等4项指标。以4项指标的光谱数据为自变量,测定值为因变量,采用偏最小二乘法(PLS)分别建立了测定值与光谱数据的预测模型。结果表明:4项指标的预测值和测定值的相关性较好,决定系数(R2)分别为0.82,0.79,0.71,0.96,校正均方根误差(RMSEC)分别为0.48%,0.35%,1.11℃,0.35%,预测均方根误差(RMSEP)分别为0.59%,0.45%,1.10℃,0.52%,模型具有较好的预测能力,可满足煤沥青制成过程质量控制的需求。
Abstract
Near-infrared diffuse reflectance spectra of medium temperature coal pitch samples were collected with integrating sphere analysis mode.SG1D, SNV and their combined methods were applied for pretreatments of the original spectra. Determined results of 4 indexes including TI content, QI content, softening point and coking value were obtained by GB/T 2292-2018, GB/T 2293-2019, GB/T 2294-2019 and GB/T 8727-2008. With values of NIR spectrum as independent variable and determined values as dependent variable, prediction models of 4 indexes were established by PLS. As found by results that the correlation between the predicted values and determined values was good, giving values of R2 of 0.82, 0.79, 0.71, 0.96, and values of RMSEC found were 0.48%, 0.35%, 1.11℃, 0.35%, with values of RMSEP of 0.59%, 0.45%, 1.10℃, 0.52%, respectively. The model had a good predictive ability and could be applied in the quality control of the manufacturing process of coal pitch.
中图分类号 O657.33 DOI 10.11973/lhjy-hx202008008
所属栏目 工作简报
基金项目 辽宁省自然科学基金指导计划项目(20180550682,2019-ZD-08933)
收稿日期 2019/11/8
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备注金丹,高级工程师,硕士,主要从事煤焦油系新材料单体、碳材料、精细化工等领域分析检测技术的相关研究,jd781124@163.com
引用该论文: JIN Dan,MU Chunfeng,ZHANG Dakui,WANG Shaohui,WANG Haiyang,WANG Shoukai. Establishment of Near-Infrared Prediction Models for Toluene Insoluble Substance and Other 3 Indexes of Medium Temperature Coal Pitch[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2020, 56(8): 893~896
金丹,穆春丰,张大奎,王绍辉,王海洋,王守凯. 中温煤沥青甲苯不溶物等4项指标的近红外预测模型的建立[J]. 理化检验-化学分册, 2020, 56(8): 893~896
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参考文献
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【2】MISHRA A, SAHA M, BHATIA G, et al. A comparative study on the development of pitch precursor for general-purpose carbon fibres[J]. Journal of Materials Processing Technology, 2005,168(2):316-320.
【3】UTKIN Y A, YANKO E A, NOSYREV V S, et al. Assessing the petroleum coke used in aluminum production[J]. Coke and Chemistry, 2011,54(6):204-207.
【4】曹雪娟,毛鑫勃,胡森,等.煤沥青及改性煤沥青研究应用进展[J].化工新型材料, 2019,47(4):222-225.
【5】胡法竹,王凤春.对粘结剂用中温煤沥青品质的评价之讨论[J].炭素, 1998(4):43-48.
【6】朱亚明,赵雪飞,程俊霞,等.中温沥青中甲苯可溶组分的热解特性及热转化产物的性质[J].材料导报, 2017,31(2):109-114.
【7】MOCHIDA I, OYAMA T, KORAI Y, et al. Study of carbonization using a tube bomb:Evaluation of lump needle coke, carbonization mechanism and optimization[J]. Fuel, 1988,67(9):1171-1181.
【8】杜一平.分子光谱的快检技术解决方案[J].光谱学与光谱分析, 2018,38(增刊1):357-358.
【9】胡晓峰,林敏,刘辉军,等.应用近红外漫反射光谱法的猕猴桃品质无损检测[J].理化检验-化学分册, 2018,54(1):8-12.
【10】白钢,丁国钰,侯媛媛,等.引进近红外技术用于中药材品质的快速评价[J].中国中药杂志, 2016,41(19):3501-3505.
【11】叶彦斐,郑源,张向荣,等.沥青针入度的快速检测方法研究[J].炼油与化工, 2014,25(6):13-16.
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