激光诱导击穿光谱技术在钢渣分析的研究进展
Research Progress on Laser-Induced Breakdown Spectroscopy Application to Steel Slag Analysis
摘 要
对近年来激光诱导击穿光谱技术（LIBS）用于钢渣分析的国内外研究现状、系统参数优化、光谱数据预处理、定量分析方法、钢渣的分类和识别等5个方面进行了综述，并对LIBS在钢渣快速检测方面做出展望（引用文献52篇）。
钢渣
信号稳定性
数据预处理
定量分析
综述
laser induced breakdown spectroscopy
slag
stability of signal
data preprocessing
qualitative analysis
review
Abstract
A review on the application of laser induced breakdown spectroscopy (LIBS) to the analysis to steel slag during the recent years, including the following five aspects:research progress at home and abroad, system parameter optimization, spectral data preprocessing, quantitative analysis methods, and classification and identification of steel slag, was given. And a brief prospect of future progress of LIBS technology in the rapid detection of steel slag was proposed (52 ref. cited).
中图分类号 O433.5 DOI 10.11973/lhjy-hx202009019
所属栏目 专题报道(矿物及金属材料分析)
基金项目 河北省自然科学基金（E2016318007）
收稿日期 2020/4/27
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备注刘艳丽,工程师,硕士,研究方向为激光等离子体光谱技术,liuyanli01@hbisco.com
引用该论文: LIU Yanli. Research Progress on Laser-Induced Breakdown Spectroscopy Application to Steel Slag Analysis[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2020, 56(9): 1035～1044
刘艳丽. 激光诱导击穿光谱技术在钢渣分析的研究进展[J]. 理化检验－化学分册, 2020, 56(9): 1035～1044
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参考文献
【1】DONG F Z, CHEN X L, WANG Q, et al. Recent progress on the application of LIBS for metallurgical online analysis in China[J]. Frontiers of Physics, 2012,7(6):679-689.
【2】吴金泉,林兆祥,刘林美,等.LIBS技术在线检测重金属污染物的应用研究[J].中南民族大学学报:自然科学版, 2013,32(3):68-71.
【3】陈添兵,姚明印,周华茂,等.激光诱导击穿光谱结合PLS检测土壤中的铅[J].激光与红外, 2014,44(5):482-486.
【4】NOLL R. Laser-induced breakdown spectroscopy fundamentals and applications[M]. Berlin:Springer Berlin Heidelberg, 2012.
【5】MORENO C L, PALANCO S, LASERNA J J. Quantitative analysis of samples at high temperature with remote laser induced breakdown spectrometry using a room-temperature calibration plot[J]. Spectrochimica Acta Part B Atomic Spectroscopy, 2005,60(7/8):1034-1039.
【6】WANG Z, YUAN T B, HOU Z Y, et al. Laser-induced breakdown spectroscopy in China[J]. Frontiers of Physics, 2014,9(4):419-438.
【7】余克强,赵艳茹,刘飞,等.应用激光诱导击穿光谱对土壤中多元素同时定量分析[J]. 光谱学与光谱分析, 2017,37(9):2879-2884.
【8】BHATT C R, GOUEGUEL C L, JAIN J C, et al. Analysis of charcoal blast furnace slags by laser-induced breakdown spectroscopy[J]. Applied Optics, 2017,56(28):7789-7795.
【9】王哲,董凤忠,周卫东. A Rising Force for the World-Wide Development of Laser-Induced Breakdown Spectroscopy[J]. Plasma Science and Technology, 2015,17(8):617-620.
【10】SUN L X, YU H B, CONG Z B, et al. On-line semi-quantitative analysis of molten steel composition using laser-induced breakdown spectroscopy[J]. Chinese Journal of entific Instrument, 2011,32(11):2602-2608.
【11】潘从元.基于激光诱导等离子体光谱的真空环境熔融金属成分在线检测技术研究[D].合肥:中国科学技术大学, 2015.
【12】王海舟.冶金分析前沿[M].北京:科学出版社, 2004.
【13】王海舟.炉渣分析[M].北京:科学出版社, 2006.
【14】郭家林,赵俊学,黄敏.钢渣综合利用技术综述及建议[J].中国冶金, 2009,19(2):35-38.
【15】李广田,陈敏,杜成武.钢铁冶金辅助材料[M].北京:化学工业出版社, 2010.
【16】KRAUSHAAR M, NOLL R, SCHMITZ H U. Slag analysis with laser-induced breakdown spectrometry[J]. Applied Spectroscopy, 2003,57(10):1282-1287.
【17】马云望,马翠红.LIBS技术在检测炉渣中的最佳实验参数的研究[J].激光杂志, 2019,40(6):18-20.
【18】王琦.基于LIBS技术的炉渣在线分析实验研究[D].合肥:中国科学院大学, 2012.
【19】刘艳丽.激光诱导击穿光谱快速分析炉渣[J].理化检验-化学分册, 2019,55(8):887-891.
【20】刘艳丽,胡志刚.激光诱导击穿光谱分析钢铁[J].理化检验-化学分册, 2017,53(11):1271-1275.
【21】BRENCH. Optical micro emission stimulated by a ruby laser[J]. Applied Spectroscopy, 1962(16):59-64.
【22】CREMERS D A. The analysis of metals at a distance using laser-induced breakdown spectroscopy[J]. Applied Spectroscopy, 1987,41(4):572-579.
【23】DOUJAK G, MERTENS R, RAMB W. Slag analysis by laser-induced breakdown spectroscopy[J]. Stahl und Eisen, 2001,121(3):53-58.
【24】STURM V, SCHMITZ H U, REUTER T, et al. Fast vacuum slag analysis in a steel works by laser-induced breakdown spectroscopy[J]. Spectrochimica Acta Part B:Atomic Spectroscopy, 2008,63(10):1167-1170.
【25】BENGTSON A, THOMAS B.激光诱导击穿光谱技术对冶金样品中钢及炉渣的同时分析[J].冶金分析, 2009,29(2):8-13.
【26】MONFORT G, BELLAVIA L G, VANDERHEYDEN B, et al.基于在线激光诱导击穿光谱监控高炉流道中铁水组成的传感器研究[J].冶金分析, 2012,32(11):6-11.
【27】SANGHAPI H K, AYYALASOMAYAJULA K K, YUEHA F Y, et al. Analysis of slags using laser-induced breakdown spectroscopy[J]. Spectrochimica Acta Part B:Atomic Spectroscopy, 2016,115:40-50.
【28】陈兴龙,董凤忠,王琦,等.自由定标激光诱导击穿光谱技术在炉渣成分定量分析中的应用[J].光谱学与光谱分析, 2011,31(12):3289-3293.
【29】梁云仙,陈兴龙,王琦,等.神经网络在测定炉渣中Ca和Mg含量的应用[J].大气与环境光学学报, 2012,7(2):124-130.
【30】倪志波,董凤忠,陈兴龙,等.基于多粒子LIBS谱线的自吸收校正方法研究[J].光谱学与光谱分析, 2014,34(9):2523-2528.
【31】王静鸽,陈兴龙,付洪波,等.透镜到样品的距离对激光诱导等离子体的影响[J].光学学报, 2014,34(9):326-333.
【32】WANG J G, FU H B, NI Z B, et al. Temporal and Spatial Evolution of Laser-Induced Plasma from a Slag Sample[J]. Plasma Science and Technology, 2015,17(8):649-655.
【33】张天龙,吴珊,汤宏胜,等.化学计量学在激光诱导击穿光谱分析中的研究进展[J].分析化学, 2015,43(6):939-948.
【34】张天龙. 激光诱导击穿光谱中化学计量学方法研究及其在冶金分析的应用[D].西安:西北大学, 2015.
【35】马翠红,马云望.激光诱导击穿光谱结合GA-BP-ANN检测炉渣中Ca[J].激光与红外, 2019,49(12):1408-1413.
【36】崔执凤,张先狱,姚关心,等.铅黄铜合金激光诱导击穿谱特性的实验研究[J]. 原子与分子物理学报, 2007,24(1):25-30.
【37】ZHANG T L, TANG H S, LI H, et al. Chemometrics in laser-induced breakdown spectroscopy[J]. Journal of Chemometrics, DOI:10.1002/cem.2983.
【38】NI Z B, CHEN X L, FU H B, et al. Study on quantitative analysis of slag based on spectral normalization of laser-induced plasma image[J]. Frontiers of physics, 2014,9(4):439-445.
【39】陈兴龙.激光诱导击穿光谱在炉渣成分分析中的应用研究[D].中国科学院大学,中国科学院研究生院, 2011.
【40】LASHERAS R J, BELLO-GÁLVEZ C, ANZANO J M. Quantitative analysis of oxide materials by laser-induced breakdown spectroscopy with argon as an internal standard. Spectrochim Acta B, 2013,82(4):65-70.
【41】陈兴龙,董凤忠,王静鸽,等.PLS算法在激光诱导击穿光谱分析炉渣成分中的应用[J].光子学报, 2014,43(9):120-124.
【42】贺文干,董凤忠,陈兴龙,等.非线性定标方法在炉渣成分分析中的应用[J].量子电子学报, 2014,31(2):213-221.
【43】ZHANG T, WU S, DONG J, et al. Quantitative and classification analysis of slag samples by laser-induced breakdown spectroscopy (LIBS) coupled with support vector machine (SVM) and partial least square (PLS) methods[J]. Joumal of Analytical Atomic Spectrometry, 2015,30(2):368-374.
【44】吴珊.激光诱导击穿光谱技术结合化学计量学对钢铁定量分析方法的研究[D].西安:西北大学, 2016.
【45】CIUCCI A, CORSI M, PALLESCHI V, et al. New procedure for quantitative elemental analysis by laser-induced plasma spectroscopy[J]. Applied Spectroscopy, 1999,53(8):960-964.
【46】PRAHER B, ROSSLER R, HEITZ J, et al. Quantitative determination of element concentrations in industrial oxide materials by laser-induced breakdown spectroscopy[J].Analytical and Bioanalytical Chemistry, 2011,400(10):3367-3375.
【47】倪志波,董凤忠,陈兴龙,等.基于多粒子LIBS谱线的自吸收校正方法研究[J].光谱学与光谱分析, 2014,34(9):2523-2528.
【48】付洪波.激光诱导击穿光谱无标分析方法研究[D].合肥:中国科学技术大学, 2017.
【49】AHAMER C M, ESCHLBÖCK-FUCHS S, KOLMHOFER P J, et al. Laser-induced breakdown spectroscopy of major and minor oxides in steel slags:Influence of detection geometry and signal normalization[J]. Spectrochimica Acta Part B:Atomic Spectroscopy, 2016,122:157-164.
【50】DEMIDOV A, ESCHLBÖCK-FUCHS S, KAZAKOV A Y, et al. Monte carlo standardless approach for laser induced breakdown spectroscopy based on massive parallel graphic processing unit computing[J]. Spectrochim Acta B, 2016,125:97-102.
【51】TANG H, ZHANG T, YANG X, et al. Classification of different types of slag samples by laser-induced breakdown spectroscopy (LIBS) coupled with random forest based on variable importance (VIRF)[J]. Analytical Methods, 2015,7(21):9171-9176.
【2】吴金泉,林兆祥,刘林美,等.LIBS技术在线检测重金属污染物的应用研究[J].中南民族大学学报:自然科学版, 2013,32(3):68-71.
【3】陈添兵,姚明印,周华茂,等.激光诱导击穿光谱结合PLS检测土壤中的铅[J].激光与红外, 2014,44(5):482-486.
【4】NOLL R. Laser-induced breakdown spectroscopy fundamentals and applications[M]. Berlin:Springer Berlin Heidelberg, 2012.
【5】MORENO C L, PALANCO S, LASERNA J J. Quantitative analysis of samples at high temperature with remote laser induced breakdown spectrometry using a room-temperature calibration plot[J]. Spectrochimica Acta Part B Atomic Spectroscopy, 2005,60(7/8):1034-1039.
【6】WANG Z, YUAN T B, HOU Z Y, et al. Laser-induced breakdown spectroscopy in China[J]. Frontiers of Physics, 2014,9(4):419-438.
【7】余克强,赵艳茹,刘飞,等.应用激光诱导击穿光谱对土壤中多元素同时定量分析[J]. 光谱学与光谱分析, 2017,37(9):2879-2884.
【8】BHATT C R, GOUEGUEL C L, JAIN J C, et al. Analysis of charcoal blast furnace slags by laser-induced breakdown spectroscopy[J]. Applied Optics, 2017,56(28):7789-7795.
【9】王哲,董凤忠,周卫东. A Rising Force for the World-Wide Development of Laser-Induced Breakdown Spectroscopy[J]. Plasma Science and Technology, 2015,17(8):617-620.
【10】SUN L X, YU H B, CONG Z B, et al. On-line semi-quantitative analysis of molten steel composition using laser-induced breakdown spectroscopy[J]. Chinese Journal of entific Instrument, 2011,32(11):2602-2608.
【11】潘从元.基于激光诱导等离子体光谱的真空环境熔融金属成分在线检测技术研究[D].合肥:中国科学技术大学, 2015.
【12】王海舟.冶金分析前沿[M].北京:科学出版社, 2004.
【13】王海舟.炉渣分析[M].北京:科学出版社, 2006.
【14】郭家林,赵俊学,黄敏.钢渣综合利用技术综述及建议[J].中国冶金, 2009,19(2):35-38.
【15】李广田,陈敏,杜成武.钢铁冶金辅助材料[M].北京:化学工业出版社, 2010.
【16】KRAUSHAAR M, NOLL R, SCHMITZ H U. Slag analysis with laser-induced breakdown spectrometry[J]. Applied Spectroscopy, 2003,57(10):1282-1287.
【17】马云望,马翠红.LIBS技术在检测炉渣中的最佳实验参数的研究[J].激光杂志, 2019,40(6):18-20.
【18】王琦.基于LIBS技术的炉渣在线分析实验研究[D].合肥:中国科学院大学, 2012.
【19】刘艳丽.激光诱导击穿光谱快速分析炉渣[J].理化检验-化学分册, 2019,55(8):887-891.
【20】刘艳丽,胡志刚.激光诱导击穿光谱分析钢铁[J].理化检验-化学分册, 2017,53(11):1271-1275.
【21】BRENCH. Optical micro emission stimulated by a ruby laser[J]. Applied Spectroscopy, 1962(16):59-64.
【22】CREMERS D A. The analysis of metals at a distance using laser-induced breakdown spectroscopy[J]. Applied Spectroscopy, 1987,41(4):572-579.
【23】DOUJAK G, MERTENS R, RAMB W. Slag analysis by laser-induced breakdown spectroscopy[J]. Stahl und Eisen, 2001,121(3):53-58.
【24】STURM V, SCHMITZ H U, REUTER T, et al. Fast vacuum slag analysis in a steel works by laser-induced breakdown spectroscopy[J]. Spectrochimica Acta Part B:Atomic Spectroscopy, 2008,63(10):1167-1170.
【25】BENGTSON A, THOMAS B.激光诱导击穿光谱技术对冶金样品中钢及炉渣的同时分析[J].冶金分析, 2009,29(2):8-13.
【26】MONFORT G, BELLAVIA L G, VANDERHEYDEN B, et al.基于在线激光诱导击穿光谱监控高炉流道中铁水组成的传感器研究[J].冶金分析, 2012,32(11):6-11.
【27】SANGHAPI H K, AYYALASOMAYAJULA K K, YUEHA F Y, et al. Analysis of slags using laser-induced breakdown spectroscopy[J]. Spectrochimica Acta Part B:Atomic Spectroscopy, 2016,115:40-50.
【28】陈兴龙,董凤忠,王琦,等.自由定标激光诱导击穿光谱技术在炉渣成分定量分析中的应用[J].光谱学与光谱分析, 2011,31(12):3289-3293.
【29】梁云仙,陈兴龙,王琦,等.神经网络在测定炉渣中Ca和Mg含量的应用[J].大气与环境光学学报, 2012,7(2):124-130.
【30】倪志波,董凤忠,陈兴龙,等.基于多粒子LIBS谱线的自吸收校正方法研究[J].光谱学与光谱分析, 2014,34(9):2523-2528.
【31】王静鸽,陈兴龙,付洪波,等.透镜到样品的距离对激光诱导等离子体的影响[J].光学学报, 2014,34(9):326-333.
【32】WANG J G, FU H B, NI Z B, et al. Temporal and Spatial Evolution of Laser-Induced Plasma from a Slag Sample[J]. Plasma Science and Technology, 2015,17(8):649-655.
【33】张天龙,吴珊,汤宏胜,等.化学计量学在激光诱导击穿光谱分析中的研究进展[J].分析化学, 2015,43(6):939-948.
【34】张天龙. 激光诱导击穿光谱中化学计量学方法研究及其在冶金分析的应用[D].西安:西北大学, 2015.
【35】马翠红,马云望.激光诱导击穿光谱结合GA-BP-ANN检测炉渣中Ca[J].激光与红外, 2019,49(12):1408-1413.
【36】崔执凤,张先狱,姚关心,等.铅黄铜合金激光诱导击穿谱特性的实验研究[J]. 原子与分子物理学报, 2007,24(1):25-30.
【37】ZHANG T L, TANG H S, LI H, et al. Chemometrics in laser-induced breakdown spectroscopy[J]. Journal of Chemometrics, DOI:10.1002/cem.2983.
【38】NI Z B, CHEN X L, FU H B, et al. Study on quantitative analysis of slag based on spectral normalization of laser-induced plasma image[J]. Frontiers of physics, 2014,9(4):439-445.
【39】陈兴龙.激光诱导击穿光谱在炉渣成分分析中的应用研究[D].中国科学院大学,中国科学院研究生院, 2011.
【40】LASHERAS R J, BELLO-GÁLVEZ C, ANZANO J M. Quantitative analysis of oxide materials by laser-induced breakdown spectroscopy with argon as an internal standard. Spectrochim Acta B, 2013,82(4):65-70.
【41】陈兴龙,董凤忠,王静鸽,等.PLS算法在激光诱导击穿光谱分析炉渣成分中的应用[J].光子学报, 2014,43(9):120-124.
【42】贺文干,董凤忠,陈兴龙,等.非线性定标方法在炉渣成分分析中的应用[J].量子电子学报, 2014,31(2):213-221.
【43】ZHANG T, WU S, DONG J, et al. Quantitative and classification analysis of slag samples by laser-induced breakdown spectroscopy (LIBS) coupled with support vector machine (SVM) and partial least square (PLS) methods[J]. Joumal of Analytical Atomic Spectrometry, 2015,30(2):368-374.
【44】吴珊.激光诱导击穿光谱技术结合化学计量学对钢铁定量分析方法的研究[D].西安:西北大学, 2016.
【45】CIUCCI A, CORSI M, PALLESCHI V, et al. New procedure for quantitative elemental analysis by laser-induced plasma spectroscopy[J]. Applied Spectroscopy, 1999,53(8):960-964.
【46】PRAHER B, ROSSLER R, HEITZ J, et al. Quantitative determination of element concentrations in industrial oxide materials by laser-induced breakdown spectroscopy[J].Analytical and Bioanalytical Chemistry, 2011,400(10):3367-3375.
【47】倪志波,董凤忠,陈兴龙,等.基于多粒子LIBS谱线的自吸收校正方法研究[J].光谱学与光谱分析, 2014,34(9):2523-2528.
【48】付洪波.激光诱导击穿光谱无标分析方法研究[D].合肥:中国科学技术大学, 2017.
【49】AHAMER C M, ESCHLBÖCK-FUCHS S, KOLMHOFER P J, et al. Laser-induced breakdown spectroscopy of major and minor oxides in steel slags:Influence of detection geometry and signal normalization[J]. Spectrochimica Acta Part B:Atomic Spectroscopy, 2016,122:157-164.
【50】DEMIDOV A, ESCHLBÖCK-FUCHS S, KAZAKOV A Y, et al. Monte carlo standardless approach for laser induced breakdown spectroscopy based on massive parallel graphic processing unit computing[J]. Spectrochim Acta B, 2016,125:97-102.
【51】TANG H, ZHANG T, YANG X, et al. Classification of different types of slag samples by laser-induced breakdown spectroscopy (LIBS) coupled with random forest based on variable importance (VIRF)[J]. Analytical Methods, 2015,7(21):9171-9176.
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