稳定性同位素质谱技术在微量物证检验中的应用研究进展
Research Progress on the Application of Stable Isotope Mass Spectrometry in Trace Physical Evidence Analysis
摘 要
综述了稳定性同位素质谱技术，主要包括元素分析-稳定同位素比值质谱法（EA-IRMS）和气相色谱-稳定同位素比值质谱法（GC-IRMS），在法庭科学微量物证（包括助燃剂、爆炸物、油漆、土壤、纤维、胶带、塑料以及纸张等）分析中应用的研究进展，主要涉及物证的样品区分、产地溯源和同一认定等（引用文献54篇）。
微量物证
区分
同一认定
溯源
stable isotope mass spectrometry
trace material evidence
differentiation
identification
traceability
Abstract
Research progress of the application of stable isotope mass spectrometry techniques[including elemental analysis-stable isotope ratio mass spectrometry (EA-IRMS) and gas chromatography-stable isotope ratio mass spectrometry (GC-IRMS)] in the analysis of trace material evidence (i.e., combustion improver, explosive, paint, soil, fiber, tape, plastic, paper, etc.) in forensic science, was reviewed. Main applications involved the sample identification, origin traceability and identical authentication for trace material evidence (54 references cited).
中图分类号 O657.63 DOI 10.11973/lhjy-hx202011019
所属栏目 综述
基金项目 贵州警察学院自然科学青年项目（18QNZK01）；贵州省科技厅计划项目（黔科合支撑[2019]2884号）
收稿日期 2020/2/29
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备注赵志东,硕士,讲师,从事毒物毒品与微量物证分析
引用该论文: ZHAO Zhidong,MENG Jiao,GONG Jinghui,WANG Xiaohui,ZHANG Xianqiang. Research Progress on the Application of Stable Isotope Mass Spectrometry in Trace Physical Evidence Analysis[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2020, 56(11): 1235～1244
赵志东,孟娇,巩京慧,王晓卉,张显强. 稳定性同位素质谱技术在微量物证检验中的应用研究进展[J]. 理化检验－化学分册, 2020, 56(11): 1235～1244
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参考文献
【1】陈天金.基于稳定同位素及矿物元素分析的稻米产地溯源技术研究[D].北京:中国农业科学院, 2017.
【2】SUZUKI Y, CHIKARAISHI Y, OGAWA N O, et al. Geographical origin of polished rice based on multiple element and stable isotope analyses[J]. Food Chemistry, 2008,109(2):470-475.
【3】KORENAGA T, MUSASHI M, NAKASHITA R, et al. Statistical analysis of rice samples for compositions of multiple light elements (H, C, N and O) and their stable isotopes[J]. Analytical Sciences, 2010,26(8):873-878.
【4】钟敏.用碳氮稳定同位素对大米产地溯源的研究[D].大连:大连海事大学, 2013.
【5】SYED A W.小麦及其制品产地溯源技术研究[D].北京:中国农业科学院, 2019.
【6】WADOOD S A, GUO B L, LIU H Y, et al. Study on the variation of stable isotopic fingerprints of wheat kernel along with milling processing[J]. Food Control, 2018,91:427-433.
【7】陈辉.基于微量元素和稳定同位素比值的蜂蜜检测与溯源技术研究[D].秦皇岛:燕山大学, 2014.
【8】WU Z B, CHEN L Z, WU L M, et al. Classification of Chinese honeys according to their floral origins using elemental and stable isotopic compositions[J]. Journal of Agricultural and Food Chemistry, 2015,63(22):5388-5394.
【9】占茉莉.茶叶产地及铅污染溯源技术研究[D].无锡:江南大学, 2008.
【10】王洁.基于稳定同位素比率与矿质元素指纹的扁形茶产地溯源技术研究[D].北京:中国农业科学院, 2016.
【11】王燕.内蒙古绵羊肉碳氮稳定同位素产地溯源可行性[D].呼和浩特:内蒙古农业大学, 2018.
【12】刘泽鑫.关中地区牛肉产地同位素溯源技术的研究[D].无锡:江南大学, 2008.
【13】郭波莉.牛肉产地同位素与矿物元素指纹溯源技术研究[D].北京:中国农业科学院, 2007.
【14】孙淑敏.羊肉产地指纹图谱溯源技术研究[D].杨凌:西北农林科技大学, 2012.
【15】ZHANG D M, SUN W, YUAN Z P, et al. Origin differentiation of a heroin sample and its acetylating agent with 13C isotope ratio mass spectrometry[J]. European Journal of Mass Spectrometry, 2005,11(3):277-285.
【16】孙伟,张大明,宋朝锦,等.同位素比值质谱法鉴别海洛因来源——1.海洛因水解制备吗啡的研究[J].中国司法鉴定, 2003(2):21-24.
【17】汪聪慧,孙伟,张大明,等.同位素比值质谱法鉴别缴获的海洛因来源——2.海洛因的碳同位素比值质谱法研究[J].中国司法鉴定, 2003(4):19-22.
【18】SMALLWOOD B J, PAUL P R, ALLEN J D. Stable carbon isotopic composition of gasolines determined by isotope ratio monitoring gas chromatography mass spectrometry[J]. Organic Geochemistry, 2002,33(2):149-159.
【19】O'SULLIVAN G, KALIN R M. Investigation of the range of carbon and hydrogen isotopes within a global set of gasolines[J]. Environmental Forensics, 2008,9(2/3):166-176.
【20】MUHAMMAD S A, FREW R D, HAYMAN A R. Forensic differentiation of diesel fuels using hydrocarbon isotope fingerprints[J]. Central European Geology, 2013,56(1):19-37.
【21】SUN Y G, CHEN Z Y, XU S P, et al. Stable carbon and hydrogen isotopic fractionation of individual n-alkanes accompanying biodegradation:Evidence from a group of progressively biodegraded oils[J]. Organic Geochemistry, 2005,36(2):225-238.
【22】MUHAMMAD S A, HAYMAN A R, VAN HALE R, et al. Assessing carbon and hydrogen isotopic fractionation of diesel fuel n-alkanes during progressive evaporation[J]. Journal of Forensic Sciences, 2015,60:56-65.
【23】SCHWARTZ Z, AN Y, KONSTANTYNOVA K I, et al. Analysis of household ignitable liquids and their post-combustion weathered residues using compound-specific gas chromatography-combustion-isotope ratio mass spectrometry[J]. Forensic Science International, 2013,233(1/2/3):365-373.
【24】BENSON S J, LENNARD C J, MAYNARD P, et al. Forensic analysis of explosives using isotope ratio mass spectrometry (IRMS) - Preliminary study on TATP and PETN[J]. Science & Justice, 2009,49(2):81-86.
【25】BEZEMER K D B, KOEBERG M, VAN DER HEIJDEN A E D M, et al. The potential of isotope ratio mass spectrometry (IRMS) and gas chromatography-IRMS analysis of triacetone triperoxide in forensic explosives investigations[J]. Journal of Forensic Sciences, 2016,61(5):1198-1207.
【26】HOWA J D, LOTT M J, EHLERINGER J R. Observations and sources of carbon and nitrogen isotope ratio variation of pentaerythritol tetranitrate (PETN)[J]. Forensic Science International, 2014,244:152-157.
【27】CHESSON L A, HOWA J D, LOTT M J, et al. Development of a methodological framework for applying isotope ratio mass spectrometry to explosive components[J]. Forensic Chemistry, 2016,2:9-14.
【28】HOWA J D, LOTT M J, CHESSON L A, et al. Isolation of components of plastic explosives for isotope ratio mass spectrometry[J]. Forensic Chemistry, 2016,1:6-12.
【29】LOCK C M, MEIER-AUGENSTEIN W. Investigation of isotopic linkage between precursor and product in the synthesis of a high explosive[J]. Forensic Science International, 2008,179(2/3):157-162.
【30】HOWA J D, LOTT M J, CHESSON L A, et al. Carbon and nitrogen isotope ratios of factory-produced RDX and HMX[J]. Forensic Science International, 2014,240:80-87.
【31】GENTILE N, SIEGWOLF R T W, DELÉMONT O. Study of isotopic variations in black powder:Reflections on the use of stable isotopes in forensic science for source inference[J]. Rapid Communications in Mass Spectrometry, 2009,23(16):2559-2567.
【32】BENSON S J, LENNARD C J, MAYNARD P, et al. Forensic analysis of explosives using isotope ratio mass spectrometry (IRMS) - Discrimination of ammonium nitrate sources[J]. Science & Justice, 2009,49(2):73-80.
【33】HOWA J D, LOTT M J, EHLERINGER J R. Isolation and stable nitrogen isotope analysis of ammonium ions in ammonium nitrate prills using sodium tetraphenylborate[J]. Rapid Communications in Mass Spectrometry, 2014,28(13):1530-1534.
【34】BRUST H, KOEBERG M, HEIJDEN V D A, et al. Isotopic and elemental profiling of ammonium nitrate in forensic explosives investigations[J]. Forensic Science International, 2015,248:101-112.
【35】WIDORY D, MINET J J, BARBE-LEBORGNE M. Sourcing explosives:A multi-isotope approach[J]. Science & Justice, 2009,49(2):62-72.
【36】LOCK C M. Stable isotope profiling of energetic materials and their precursors[D]. Belfast:The Queen's University of Belfast, 2009.
【37】REIDY L J, MEIER-AUGENSTEIN W, KALIN R M. 13C-Isotope ratio mass spectrometry as a potential tool for the forensic analysis of white architectural paint:A preliminary study[J]. Rapid Communications in Mass Spectrometry, 2005,19(13):1899-1905.
【38】FARMER N, MEIER-AUGENSTEIN W, LUCY D. Stable isotope analysis of white paints and likelihood ratios[J]. Science & Justice, 2009,49(2):114-119.
【39】葛露露,孟庆权,林宇,等.滨海沙地不同树种人工林叶片和土壤表层稳定碳氮同位素及水分利用效率研究[J].西北植物学报, 2018,38(3):544-552.
【40】邓文平,余新晓,贾国栋,等.北京西山鹫峰地区氢氧稳定同位素特征分析[J].水科学进展, 2013,24(5):642-650.
【41】PYE K, BLOTT S J, CROFT D J, et al. Forensic comparison of soil samples:Assessment of small-scale spatial variability in elemental composition, carbon and nitrogen isotope ratios, colour, and particle size distribution[J]. Forensic Science International, 2006,163(1/2):59-80.
【42】CROFT D J, PYE K. The potential use of continuous-flow isotope-ratio mass spectrometry as a tool in forensic soil analysis:A preliminary report[J]. Rapid Communications in Mass Spectrometry, 2003,17(23):2581-2584.
【43】CROFT D J, PYE K. Multi-technique comparison of source and primary transfer soil samples:An experimental investigation[J]. Science & Justice, 2004,44(1):21-28.
【44】DAÉID N N, MEIER-AUGENSTEIN W, KEMP H F. Investigating the provenance of un-dyed spun cotton fibre using multi-isotope profiles and chemometric analysis[J]. Rapid Communications in Mass Spectrometry, 2011,25(13):1812-1816.
【45】MEIER-AUGENSTEIN W, KEMP H F, SCHENK E R, et al. Discrimination of unprocessed cotton on the basis of geographic origin using multi-element stable isotope signatures[J]. Rapid Communications in Mass Spectrometry, 2014,28(5):545-552.
【46】CARTER J F, DOYLE S, PHASUMANE B L, et al. The role of isotope ratio mass spectrometry as a tool for the comparison of physical evidence[J]. Science & Justice, 2014,54(5):327-334.
【47】HORACEK M, MIN J S, HEO S, et al. The application of isotope ratio mass spectrometry for discrimination and comparison of adhesive tapes[J]. Rapid Communications in Mass Spectrometry, 2008,22(11):1763-1766.
【48】DIETZ M E, STERN L A, MEHLTRETTER A H, et al. Forensic utility of carbon isotope ratio variations in PVC tape backings[J]. Science & Justice, 2012,52(1):25-32.
【49】QUIRK A T, BELLERBY J M, CARTER J F, et al. An initial evaluation of stable isotopic characterisation of post-blast plastic debris from improvised explosive devices[J]. Science & Justice, 2009,49(2):87-93.
【50】JONES K, BENSON S, ROUX C. The forensic analysis of office paper using carbon isotope ratio mass spectrometry-Part 1:Understanding the background population and homogeneity of paper for the comparison and discrimination of samples[J]. Forensic Science International, 2013,231(1/2/3):354-363.
【51】JONES K, BENSON S, ROUX C. The forensic analysis of office paper using carbon isotope ratio mass spectrometry-Part 2:Method development, validation and sample handling[J]. Forensic Science International, 2013,231(1/2/3):364-374.
【52】JONES K, BENSON S, ROUX C. The forensic analysis of office paper using carbon isotope ratio mass spectrometry. Part 3:Characterizing the source materials and the effect of production and usage on the δ13C values of paper[J]. Forensic Science International, 2013,233(1/2/3):355-364.
【53】JONES K, BENSON S, ROUX C. The forensic analysis of office paper using oxygen isotope ratio mass spectrometry. Part 1:Understanding the background population and homogeneity of paper for the comparison and discrimination of samples[J]. Forensic Science International, 2016,262:97-107.
【2】SUZUKI Y, CHIKARAISHI Y, OGAWA N O, et al. Geographical origin of polished rice based on multiple element and stable isotope analyses[J]. Food Chemistry, 2008,109(2):470-475.
【3】KORENAGA T, MUSASHI M, NAKASHITA R, et al. Statistical analysis of rice samples for compositions of multiple light elements (H, C, N and O) and their stable isotopes[J]. Analytical Sciences, 2010,26(8):873-878.
【4】钟敏.用碳氮稳定同位素对大米产地溯源的研究[D].大连:大连海事大学, 2013.
【5】SYED A W.小麦及其制品产地溯源技术研究[D].北京:中国农业科学院, 2019.
【6】WADOOD S A, GUO B L, LIU H Y, et al. Study on the variation of stable isotopic fingerprints of wheat kernel along with milling processing[J]. Food Control, 2018,91:427-433.
【7】陈辉.基于微量元素和稳定同位素比值的蜂蜜检测与溯源技术研究[D].秦皇岛:燕山大学, 2014.
【8】WU Z B, CHEN L Z, WU L M, et al. Classification of Chinese honeys according to their floral origins using elemental and stable isotopic compositions[J]. Journal of Agricultural and Food Chemistry, 2015,63(22):5388-5394.
【9】占茉莉.茶叶产地及铅污染溯源技术研究[D].无锡:江南大学, 2008.
【10】王洁.基于稳定同位素比率与矿质元素指纹的扁形茶产地溯源技术研究[D].北京:中国农业科学院, 2016.
【11】王燕.内蒙古绵羊肉碳氮稳定同位素产地溯源可行性[D].呼和浩特:内蒙古农业大学, 2018.
【12】刘泽鑫.关中地区牛肉产地同位素溯源技术的研究[D].无锡:江南大学, 2008.
【13】郭波莉.牛肉产地同位素与矿物元素指纹溯源技术研究[D].北京:中国农业科学院, 2007.
【14】孙淑敏.羊肉产地指纹图谱溯源技术研究[D].杨凌:西北农林科技大学, 2012.
【15】ZHANG D M, SUN W, YUAN Z P, et al. Origin differentiation of a heroin sample and its acetylating agent with 13C isotope ratio mass spectrometry[J]. European Journal of Mass Spectrometry, 2005,11(3):277-285.
【16】孙伟,张大明,宋朝锦,等.同位素比值质谱法鉴别海洛因来源——1.海洛因水解制备吗啡的研究[J].中国司法鉴定, 2003(2):21-24.
【17】汪聪慧,孙伟,张大明,等.同位素比值质谱法鉴别缴获的海洛因来源——2.海洛因的碳同位素比值质谱法研究[J].中国司法鉴定, 2003(4):19-22.
【18】SMALLWOOD B J, PAUL P R, ALLEN J D. Stable carbon isotopic composition of gasolines determined by isotope ratio monitoring gas chromatography mass spectrometry[J]. Organic Geochemistry, 2002,33(2):149-159.
【19】O'SULLIVAN G, KALIN R M. Investigation of the range of carbon and hydrogen isotopes within a global set of gasolines[J]. Environmental Forensics, 2008,9(2/3):166-176.
【20】MUHAMMAD S A, FREW R D, HAYMAN A R. Forensic differentiation of diesel fuels using hydrocarbon isotope fingerprints[J]. Central European Geology, 2013,56(1):19-37.
【21】SUN Y G, CHEN Z Y, XU S P, et al. Stable carbon and hydrogen isotopic fractionation of individual n-alkanes accompanying biodegradation:Evidence from a group of progressively biodegraded oils[J]. Organic Geochemistry, 2005,36(2):225-238.
【22】MUHAMMAD S A, HAYMAN A R, VAN HALE R, et al. Assessing carbon and hydrogen isotopic fractionation of diesel fuel n-alkanes during progressive evaporation[J]. Journal of Forensic Sciences, 2015,60:56-65.
【23】SCHWARTZ Z, AN Y, KONSTANTYNOVA K I, et al. Analysis of household ignitable liquids and their post-combustion weathered residues using compound-specific gas chromatography-combustion-isotope ratio mass spectrometry[J]. Forensic Science International, 2013,233(1/2/3):365-373.
【24】BENSON S J, LENNARD C J, MAYNARD P, et al. Forensic analysis of explosives using isotope ratio mass spectrometry (IRMS) - Preliminary study on TATP and PETN[J]. Science & Justice, 2009,49(2):81-86.
【25】BEZEMER K D B, KOEBERG M, VAN DER HEIJDEN A E D M, et al. The potential of isotope ratio mass spectrometry (IRMS) and gas chromatography-IRMS analysis of triacetone triperoxide in forensic explosives investigations[J]. Journal of Forensic Sciences, 2016,61(5):1198-1207.
【26】HOWA J D, LOTT M J, EHLERINGER J R. Observations and sources of carbon and nitrogen isotope ratio variation of pentaerythritol tetranitrate (PETN)[J]. Forensic Science International, 2014,244:152-157.
【27】CHESSON L A, HOWA J D, LOTT M J, et al. Development of a methodological framework for applying isotope ratio mass spectrometry to explosive components[J]. Forensic Chemistry, 2016,2:9-14.
【28】HOWA J D, LOTT M J, CHESSON L A, et al. Isolation of components of plastic explosives for isotope ratio mass spectrometry[J]. Forensic Chemistry, 2016,1:6-12.
【29】LOCK C M, MEIER-AUGENSTEIN W. Investigation of isotopic linkage between precursor and product in the synthesis of a high explosive[J]. Forensic Science International, 2008,179(2/3):157-162.
【30】HOWA J D, LOTT M J, CHESSON L A, et al. Carbon and nitrogen isotope ratios of factory-produced RDX and HMX[J]. Forensic Science International, 2014,240:80-87.
【31】GENTILE N, SIEGWOLF R T W, DELÉMONT O. Study of isotopic variations in black powder:Reflections on the use of stable isotopes in forensic science for source inference[J]. Rapid Communications in Mass Spectrometry, 2009,23(16):2559-2567.
【32】BENSON S J, LENNARD C J, MAYNARD P, et al. Forensic analysis of explosives using isotope ratio mass spectrometry (IRMS) - Discrimination of ammonium nitrate sources[J]. Science & Justice, 2009,49(2):73-80.
【33】HOWA J D, LOTT M J, EHLERINGER J R. Isolation and stable nitrogen isotope analysis of ammonium ions in ammonium nitrate prills using sodium tetraphenylborate[J]. Rapid Communications in Mass Spectrometry, 2014,28(13):1530-1534.
【34】BRUST H, KOEBERG M, HEIJDEN V D A, et al. Isotopic and elemental profiling of ammonium nitrate in forensic explosives investigations[J]. Forensic Science International, 2015,248:101-112.
【35】WIDORY D, MINET J J, BARBE-LEBORGNE M. Sourcing explosives:A multi-isotope approach[J]. Science & Justice, 2009,49(2):62-72.
【36】LOCK C M. Stable isotope profiling of energetic materials and their precursors[D]. Belfast:The Queen's University of Belfast, 2009.
【37】REIDY L J, MEIER-AUGENSTEIN W, KALIN R M. 13C-Isotope ratio mass spectrometry as a potential tool for the forensic analysis of white architectural paint:A preliminary study[J]. Rapid Communications in Mass Spectrometry, 2005,19(13):1899-1905.
【38】FARMER N, MEIER-AUGENSTEIN W, LUCY D. Stable isotope analysis of white paints and likelihood ratios[J]. Science & Justice, 2009,49(2):114-119.
【39】葛露露,孟庆权,林宇,等.滨海沙地不同树种人工林叶片和土壤表层稳定碳氮同位素及水分利用效率研究[J].西北植物学报, 2018,38(3):544-552.
【40】邓文平,余新晓,贾国栋,等.北京西山鹫峰地区氢氧稳定同位素特征分析[J].水科学进展, 2013,24(5):642-650.
【41】PYE K, BLOTT S J, CROFT D J, et al. Forensic comparison of soil samples:Assessment of small-scale spatial variability in elemental composition, carbon and nitrogen isotope ratios, colour, and particle size distribution[J]. Forensic Science International, 2006,163(1/2):59-80.
【42】CROFT D J, PYE K. The potential use of continuous-flow isotope-ratio mass spectrometry as a tool in forensic soil analysis:A preliminary report[J]. Rapid Communications in Mass Spectrometry, 2003,17(23):2581-2584.
【43】CROFT D J, PYE K. Multi-technique comparison of source and primary transfer soil samples:An experimental investigation[J]. Science & Justice, 2004,44(1):21-28.
【44】DAÉID N N, MEIER-AUGENSTEIN W, KEMP H F. Investigating the provenance of un-dyed spun cotton fibre using multi-isotope profiles and chemometric analysis[J]. Rapid Communications in Mass Spectrometry, 2011,25(13):1812-1816.
【45】MEIER-AUGENSTEIN W, KEMP H F, SCHENK E R, et al. Discrimination of unprocessed cotton on the basis of geographic origin using multi-element stable isotope signatures[J]. Rapid Communications in Mass Spectrometry, 2014,28(5):545-552.
【46】CARTER J F, DOYLE S, PHASUMANE B L, et al. The role of isotope ratio mass spectrometry as a tool for the comparison of physical evidence[J]. Science & Justice, 2014,54(5):327-334.
【47】HORACEK M, MIN J S, HEO S, et al. The application of isotope ratio mass spectrometry for discrimination and comparison of adhesive tapes[J]. Rapid Communications in Mass Spectrometry, 2008,22(11):1763-1766.
【48】DIETZ M E, STERN L A, MEHLTRETTER A H, et al. Forensic utility of carbon isotope ratio variations in PVC tape backings[J]. Science & Justice, 2012,52(1):25-32.
【49】QUIRK A T, BELLERBY J M, CARTER J F, et al. An initial evaluation of stable isotopic characterisation of post-blast plastic debris from improvised explosive devices[J]. Science & Justice, 2009,49(2):87-93.
【50】JONES K, BENSON S, ROUX C. The forensic analysis of office paper using carbon isotope ratio mass spectrometry-Part 1:Understanding the background population and homogeneity of paper for the comparison and discrimination of samples[J]. Forensic Science International, 2013,231(1/2/3):354-363.
【51】JONES K, BENSON S, ROUX C. The forensic analysis of office paper using carbon isotope ratio mass spectrometry-Part 2:Method development, validation and sample handling[J]. Forensic Science International, 2013,231(1/2/3):364-374.
【52】JONES K, BENSON S, ROUX C. The forensic analysis of office paper using carbon isotope ratio mass spectrometry. Part 3:Characterizing the source materials and the effect of production and usage on the δ13C values of paper[J]. Forensic Science International, 2013,233(1/2/3):355-364.
【53】JONES K, BENSON S, ROUX C. The forensic analysis of office paper using oxygen isotope ratio mass spectrometry. Part 1:Understanding the background population and homogeneity of paper for the comparison and discrimination of samples[J]. Forensic Science International, 2016,262:97-107.
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