铝合金表面自修复防护膜的研究进展
Research Progress in Self-healing Protective Film for Aluminum Alloy
摘 要
采用表面处理可以减缓铝合金的腐蚀，延长服役时间。近年来国内外开发了一种新型的铝合金表面自修复防护膜，这类表面防护膜发生腐蚀时，能够自行修复破损处，恢复原有的防护效果，是一种新型的智能防护涂层。根据作用机理，自修复防护膜可分为自发型和非自发型两类，阐述了不同种类防护膜的自修复原理。在此基础上重点介绍了近年来应用于铝合金表面的自修复防护膜，探讨了目前存在的问题并对其发展趋势进行了展望。
自修复防护膜
耐蚀性
研究进展
aluminum alloy
self-healing protective film
corrosion resistance
research progress
Abstract
Surface treatment can slow down the corrosion of aluminum alloy and prolong the service time. A new type of aluminum alloy surface self-healing protective film has been developed in recent years at home and abroad. This type of protective film would repair the damaged area by itself and restore the original protective effect when the film on the surface of aluminum alloy was corroded, and thus is considered as a new type of intelligent protective coating. According to the mechanism of action, the self-healing protective film can be divided into two sorts: spontaneous and non-spontaneous, and the self-repairing principles of different sorts of protective films are described in this paper. In addition, the applications of self-healing protective film for aluminum alloy are mainly introduced, the existing problems are discussed and the development trend is prospected.
中图分类号 TG178 DOI 10.11973/fsyfh-202011001
所属栏目 专论
基金项目 广东省重点研发计划（2020B010186001）；国家自然科学基金（21671038）；江西省重点领域研发计划（20201BBE51009）
收稿日期 2020/5/15
修改稿日期
网络出版日期
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引用该论文: MA Ji,CHANG Menglei,WEI Hongyang,HUANG Yinchun,CHEN Dongchu. Research Progress in Self-healing Protective Film for Aluminum Alloy[J]. Corrosion & Protection, 2020, 41(11): 1
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参考文献
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【2】LIANG W J,ROMETSCH P A,CAO L F,et al. General aspects related to the corrosion of 6xxx series aluminium alloys:exploring the influence of Mg/Si ratio and Cu[J]. Corrosion Science,2013,76:119-128.
【3】卞贵学,陈跃良,张勇,等. 飞机用铝合金腐蚀行为和腐蚀预测研究现状及问题分析[J]. 装备环境工程,2018,15(5):48-55.
【4】花天顺,宋仁国,宗玙,等. 恒载荷下的微弧氧化后7050铝合金在不同pH值NaCl溶液中的腐蚀行为[J]. 表面技术,2020,49(5):269-278.
【5】ZUBILLAGA O,CANO F J,AZKARATE I,et al. Corrosion performance of anodic films containing polyaniline and TiO2 nanoparticles on AA3105 aluminium alloy[J]. Surface and Coatings Technology,2008,202(24):5936-5942.
【6】SHEN D J,LI G L,GUO C H,et al. Microstructure and corrosion behavior of micro-arc oxidation coating on 6061 aluminum alloy pre-treated by high-temperature oxidation[J]. Applied Surface Science,2013,287:451-456.
【7】李海丰,任伊锦,李亚斌. ADC12铝合金表面Co-Mn化学转化膜耐蚀性的研究[J]. 电镀与环保,2019,39(5):61-64.
【8】丁运虎,黄兴林,邓华才,等. 高硅铝合金电镀环保前处理技术研究[J]. 材料保护,2017,50(4):55-57,72.
【9】潘梦秋,王伦滔,丁璇,等. 自修复防腐涂层研究进展[J]. 中国材料进展,2018,37(1):19-27.
【10】ZHANG F,JU P F,PAN M Q,et al. Self-healing mechanisms in smart protective coatings:a review[J]. Corrosion Science,2018,144:74-88.
【11】ZHONG X,WU X S,JIA Y Y,et al. Self-repairing vanadium-zirconium composite conversion coating for aluminum alloys[J]. Applied Surface Science,2013,280:489-493.
【12】李方强,徐文雷. 一种水溶剂自修复压铸铝合金防腐处理的方法:CN107604396A[P]. 2018-01-19.
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【14】ZHANG C X,LUO X H,PAN X Y,et al. Self-healing Li-Al layered double hydroxide conversion coating modified with aspartic acid for 6N01 Al alloy[J]. Applied Surface Science,2017,394:275-281.
【15】LIN K D,LUO X H,PAN X Y,et al. Enhanced corrosion resistance of LiAl-layered double hydroxide (LDH) coating modified with a Schiff base salt on aluminum alloy by one step in situ synthesis at low temperature[J]. Applied Surface Science,2019,463:1085-1096.
【16】LI J,LIN K D,LUO X H,et al. Enhanced corrosion protection property of Li-Al layered double hydroxides (LDHs) film modified by 2-guanidinosuccinic acid with excellent self-repairing and self-antibacterial properties[J]. Applied Surface Science,2019,480:384-394.
【17】任魏巍,梁思琰,符殿宝,等. 铝合金PEO涂层表面原位制备Mg-Al LDH膜及其耐蚀性能研究[J]. 表面技术,2020,49(4):254-262.
【18】周秉涛,王友彬,黄秋雨,等. 水热预处理对铝合金表面ZnAl-LDHs涂层防腐蚀性能的影响[J]. 表面技术,2020,49(4):315-323.
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【20】HAMDY A S,DOENCH I,MÖHWALD H. Intelligent self-healing corrosion resistant vanadia coating for AA2024[J]. Thin Solid Films,2011,520(5):1668-1678.
【21】PIRHADY TAVANDASHTI N,GHORBANI M,SHOJAEI A,et al. pH responsive Ce(Ⅲ) loaded polyaniline nanofibers for self-healing corrosion protection of AA2024-T3[J]. Progress in Organic Coatings,2016,99:197-209.
【22】CARNEIRO J,TEDIM J,FERNANDES S C M,et al. Chitosan-based self-healing protective coatings doped with cerium nitrate for corrosion protection of aluminum alloy 2024[J]. Progress in Organic Coatings,2012,75(1/2):8-13.
【23】KARTSONAKIS I A,ATHANASOPOULOU E,SNIHIROVA D,et al. Multifunctional epoxy coatings combining a mixture of traps and inhibitor loaded nanocontainers for corrosion protection of AA2024-T3[J]. Corrosion Science,2014,85:147-159.
【24】马利纳,郑齐,王亚轩,等. 机械冷却通风塔风机叶片用水性自修复涂料及其制备方法:CN107474686A[P]. 2017-12-15.
【25】NAJJAR R,KATOURANI S A,HOSSEINI M G. Self-healing and corrosion protection performance of organic resin core-shell nanoparticles in epoxy/PANI/ZnO nanocomposite coatings on anodized aluminum alloy[J]. Progress in Organic Coatings,2018,124:110-121.
【26】YABUKI A,NAGAYAMA Y,FATHONA I W. Porous anodic oxide film with self-healing ability for corrosion protection of aluminum[J]. Electrochimica Acta,2019,296:662-668.
【27】MANASA S,JYOTHIRMAYI A,SIVA T,et al. Effect of inhibitor loading into nanocontainer additives of self-healing corrosion protection coatings on aluminum alloy A356.0[J]. Journal of Alloys and Compounds,2017,726:969-977.
【28】NGUYEN A S,PÉBÉRE N. A local electrochemical impedance study of the self-healing properties of waterborne coatings on 2024 aluminium alloy[J]. Electrochimica Acta,2016,222:1806-1817.
【29】TRENTIN A,HARB S V,UVIDA M C,et al. Dual role of lithium on the structure and self-healing ability of PMMA-silica coatings on AA7075 alloy[J]. ACS Applied Materials & Interfaces,2019,11(43):40629-40641.
【30】HUANG Q,LIU L L,WU Z Z,et al. Corrosion-resistant plasma electrolytic oxidation coating modified by Zinc phosphate and self-healing mechanism in the salt-spray environment[J]. Surface and Coatings Technology,2020,384:125321.
【31】ZHANG D Q,YUAN T H,WEI G A,et al. Preparation of self-healing hydrophobic coating on AA6061 alloy surface and its anti-corrosion property[J]. Journal of Alloys and Compounds,2019,774:495-501.
【32】PETROVIC Z S,MILIC J,ZHANG F,et al. Fast-responding bio-based shape memory thermoplastic polyurethanes[J]. Polymer,2017,121:26-37.
【33】HORNAT C C,URBAN M W. Shape memory effects in self-healing polymers[J]. Progress in Polymer Science,2020,102:101208.
【34】Bayer Material Science. Self-healing coatings:more than just scratch-resistant[J]. AdCoTec Newsletter,2010,3:3-4.
【35】FAN W J,LI W H,ZHANG Y,et al. Cooperative self-healing performance of shape memory polyurethane and Alodine-containing microcapsules[J]. RSC Adv,2017,7(74):46778-46787.
【36】GREGORITZA M,BRANDL F P. The Diels-Alder reaction:a powerful tool for the design of drug delivery systems and biomaterials[J]. European Journal of Pharmaceutics and Biopharmaceutics,2015,97:438-453.
【37】DIELEMAN C D,DENISSEN P J,GARCIA S J. Long-term active corrosion protection of damaged coated-AA2024-T3 by embedded electrospun inhibiting nanonetworks[J]. Advanced Materials Interfaces,2018,5(12):1800176.
【38】CASTRO Y,ÖZMEN E,DURÁN A. Integrated self-healing coating system for outstanding corrosion protection of AA2024[J]. Surface and Coatings Technology,2020,387:125521.
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