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淬火温度对40Cr13塑料模具钢耐腐蚀性能的影响
          
Effect of Quenching Temperature on Corrosion Resistance of 40Cr13 Plastic Die Steel

摘    要
对40Cr13塑料模具钢进行不同温度(960,1 020,1 080,1 140℃)淬火处理,研究了淬火温度对该钢组织与硬度的影响,然后进行200℃的低温回火处理,通过浸泡试验与电化学测试研究了其耐腐蚀性能。结果表明:不同温度淬火后,试验钢组织均为淬火马氏体、碳化物与少量残余奥氏体;随着淬火温度的升高,组织变得粗大,碳化物减少,当淬火温度为1 140℃时,组织中存在沿奥氏体晶界析出的网状碳化物;随着淬火温度的升高,试验钢的硬度先增加后减小。当淬火温度由960℃升高到1 080℃,经回火后试验钢在FeCl3溶液中的腐蚀速率减小,试验钢表面点蚀孔直径变小,数量增多,但深度变浅;试验钢在NaCl溶液中的自腐蚀电位增大,自腐蚀电流密度降低,腐蚀速率减小,腐蚀倾向降低;最佳淬火温度为1 020℃,此时淬火马氏体组织较细小,硬度最大,回火后试验钢的耐腐蚀性能较好。
标    签 淬火温度   40Cr13塑料模具钢   耐腐蚀性能   硬度   显微组织   quenching temperature   40Cr13 plastic die steel   corrosion resistance   hardness   microstructure  
 
Abstract
40Cr13 plastic die steel was quenched at different temperatures (960,1 020,1 080,1 140 ℃), and the effect of quenching temperature on microstructure and hardness was studied. The steel was tempered at 200 ℃,and the corrosion resistance of the steel was studied by immersion test and electrochemical test. The results show that the microstructure of the test steel after quenching at different temperatures was composed of quenched martensite, carbides and a small amount of retained austenite. The microstructure became coarse with increasing quenching temperature, and the number of carbides decreased. When the quenching temperature was 1 140 ℃, network carbides precipitated on austenite grain boundaries in the microstructure. The hardness of the test steel increased first and then decreased with increasing quenching temperature. When the quenching temperature increased from 960 ℃to 1 080 ℃, the corrosion rate of the test steel after tempering in FeCl3 solution decreased; the diameter and depth of pitting holes on the surface of the test steel decreased, and the number increased. The free-corrosion potential of the test steel in NaCl solution increased, and the free-corrosion current density decreased; the corrosion rate decreased and the corrosion tendency decreased. The optimum the quenching temperature was 1 020 ℃; at this point, the quenched martensite was relatively small, and the hardness was the largest; the corrosion resistance was relatively good.

中图分类号 TG156.3   DOI 10.11973/jxgccl202101013

 
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所属栏目 材料性能及应用

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收稿日期 2019/10/8

修改稿日期 2020/8/5

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备注张艳(1984-),女,江苏徐州人,实验师,硕士

引用该论文: ZHANG Yan,WANG Zhenxu,XU Yu,SUN Chichi,XU Ruirui. Effect of Quenching Temperature on Corrosion Resistance of 40Cr13 Plastic Die Steel[J]. Materials for mechancial engineering, 2021, 45(1): 80~84
张艳,王振旭,徐豫,孙驰驰,徐瑞瑞. 淬火温度对40Cr13塑料模具钢耐腐蚀性能的影响[J]. 机械工程材料, 2021, 45(1): 80~84


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参考文献
【1】陈再枝, 蓝德年. 模具钢手册[M]. 北京:冶金工业出版社, 2002. CHEN Z Z, LAN D N.Die steel manual[M]. Beijing:Metallurgical Industry Press, 2002.
 
【2】刘小瑞, 汪若晨.4Cr13不锈钢热处理后组织及耐蚀性能研究[J].内江科技, 2016, 37(6):61-62. LIU X R, WANG R C. Study on microstructure and corrosion resistance of 4Cr13 stainless steel after heat treatment[J].Neijiang Technology, 2016, 37(6):61-62.
 
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【4】刑珂, 云璐. 淬火温度对30Cr13模具钢组织与耐蚀性的影响[J]. 腐蚀与防护, 2018, 39(4):289-292. XING K, YUN L. Effects of quenching temperature on microstructure and corrosion resistance of die steel 30Cr13[J]. Corrosion & Protection, 2018, 39(4):289-292.
 
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