Conductivity of Lithium Bromide Modified Conductive Mortar and Its Application Effect in Corrosion Protection
摘 要
为提高牺牲阳极-导电砂浆阴极保护系统中导电砂浆的导电性,通过在导电砂浆中掺加溴化锂对其进行改性,研究了导电砂浆电阻率与溴化锂掺量及养护龄期的关系,并通过飞溅区腐蚀模拟试验对该牺牲阳极-导电砂浆阴极保护系统的腐蚀防护效果进行了验证。结果表明:溴化锂能显著降低导电砂浆的电阻率,随溴化锂掺量的增加,导电砂浆电阻率降低;用溴化锂145.4 g、水泥450 g、砂子1 350 g、水270 g配合比制备的高溴化锂掺量导电砂浆,其导电性几乎不受养护龄期影响,且电阻率均小于100 Ω·cm;该牺牲阳极-导电砂浆阴极保护系统能够为飞溅区钢结构提供全面的防护。
Abstract
In order to improve the conductivity of conductive mortar in sacrificial anode and conductive mortar cathodic protection system, the conductive mortar was modified by adding lithium bromide. The relationships between resistivity of conductive mortar and dosage of lithium bromide, curing age were studied. And the corrosion protection effect of the sacrificial anode and conductive mortar cathodic protection system was verified through corrosion simulation test in splash area. The results show that lithium bromide significantly reduced the resistivity of conductive mortar, and the resistivity decreased with the increase of lithium bromide dosage. Curing age had almost no effect on the conductivity of the conductive mortar with high lithium bromide dosage prepared at the mixing ratio of 145.4 g lithium bromide, 450 g cement, 1 350 g sand, and 270 g water, and corresponding resistivity was all less than 100 Ω·cm. The steel pipe pile in splash could be well protected by this sacrificial anode and conductive mortar cathodic protection system.
中图分类号 TG174.41 DOI 10.11973/fsyfh-202105002
所属栏目 试验研究
基金项目 中国交通建设集团科技研发项目(2017-ZJKJ-PTJS04);国家重点研发计划项目(2019YFB1600700)
收稿日期 2019/9/17
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引用该论文: ZHANG Dongfang,FANG Xiang,FAN Zhihong,CHEN Long,WANG Shengnian,WU Qingfa. Conductivity of Lithium Bromide Modified Conductive Mortar and Its Application Effect in Corrosion Protection[J]. Corrosion & Protection, 2021, 42(5): 8
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参考文献
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【4】程明山. 东海大桥钢管桩在役牺牲阳极性能分析及剩余寿命评定[J]. 腐蚀与防护,2016,37(12):994-998.
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【7】PRESUEL-MORENO F J,KRANC S C,SAGVÉS A A. Cathodic prevention distribution in partially sub- merged reinforced concrete[J]. Corrosion,2005,61(6):548-558.
【8】SERGI G. Ten-year results of galvanic sacrificial anodes in steel reinforced concrete[J]. Materials and Corrosion,2011,62(2):98-104.
【9】NORAMBUENA-CONTRERAS J,GONZALEZ A,CONCHA J L,et al. Effect of metallic waste addition on the electrical,thermophysical and microwave crack-healing properties of asphalt mixtures[J]. Construction and Building Materials,2018,187:1039-1050.
【10】赵若红,区浩文,傅继阳,等. 掺工业废弃料导电砂浆电阻率稳定性研究[J]. 材料导报,2015,29(12):129-134.
【11】罗宝,赵若红,袁迪,等. 不同施工工艺对钢纤维-石墨导电混凝土薄板电阻率的影响[J]. 新型建筑材料,2017,44(8):123-126.
【12】詹树林,王磊. 用于牺牲阳极法的碳纤维导电砂浆的导电性能研究[J]. 中国水运,2013(1):58-59.
【13】叶嘉诚,刘宇彬,齐曾清,等. 三相导电混凝土拌和工艺及配合比试验研究[J]. 新型建筑材料,2019,46(3):13-17,35.
【14】李岩,蔡跃波,葛燕,等. 用交流阻抗谱研究活性砂浆胶结材料的电化学行为[J]. 硅酸盐学报,2013,41(2):199-204.
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【17】LI W G,LI X Y,CHEN S J,et al. Effects of graphene oxide on early-age hydration and electrical resistivity of Portland cement paste[J]. Construction and Building Materials,2017,136:506-514.
【18】黄振风,郭建章,刘广义,等. 海水干湿交替环境对铝合金牺牲阳极性能的影响[J]. 腐蚀与防护,2016,37(2):160-164.
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