复合镀液中Al2O3掺杂量对Ni-P-Al2O3-PTFE复合镀层性能的影响
Effect of Al2O3 Doping Content in Composite Plating Solution on Properties ofNi-P-Al2O3-PTFE Composite Plating
摘 要
在复合镀液中添加不同含量的Al2O3，采用化学镀方法制备Ni-P-Al2O3-PTFE （聚四氟乙烯）复合镀层，研究了复合镀液中Al2O3质量浓度（0~3.0 g·L-1）对复合镀层显微组织、硬度、耐磨性能的影响。结果表明：随着复合镀液中Al2O3掺杂量的增加，化学镀Ni-P-Al2O3-PTFE复合镀层中Al2O3含量先升高后降低，Ni-P基质的结晶性先增强后减弱，硬度先升高后降低，磨损质量损失先减小后增加；当Al2O3质量浓度为2.0 g·L-1时，Ni-P基质结晶性优良，Ni-P-Al2O3-PTFE层与Ni-P过渡层结合良好，复合镀层中Al2O3的含量最高，PTFE、Al2O3粒子均匀弥散地镶嵌在Ni-P基质中，复合镀层的硬度最高，为7.6 GPa，磨损质量损失最低，复合镀层具有优异的耐磨性能。
化学镀
Ni-P-Al2O3-PTFE复合镀层
耐磨性能
Al2O3 doping
electroless plating
Ni-P-Al2O3-PTFE composite plating
wear resistance
Abstract
A Ni-P-Al2O3-PTFE (polytetrafluoroethylene) composite plating was prepared by electroless plating method with different content of Al2O3 in the composite plating solution. The effects of mass concentration (0-3.0 g·L-1) of Al2O3 in the composite plating solution on the microstructure, hardness and wear resistance of the composite plating were studied. The results show that with increasing doping content of Al2O3 in the composite plating solution, the content of Al2O3 in the electroless plating Ni-P-Al2O3-PTFE composite plating increased first and then decreased, the crystallinity of the Ni-P matrix increased first and then decreased, the hardness increased first and then decreased, and the wear mass loss decreased first and then increased. When the mass concentration of Al2O3 was 2.0 g·L-1, the crystallinity of the Ni-P matrix was good, the Ni-P-Al2O3-PTFE plating and Ni-P transition layer were bonded well, the content of Al2O3 in the composite plating was the highest, the PTFE and Al2O3 particles were uniformly dispersed in the Ni-P matrix, and the composite plating had the highest hardness of 7.6 GPa, and the smallest wear mass loss, indicating the composite plating had excellent wear resistance.
中图分类号 TB333 DOI 10.11973/jxgccl202106002
所属栏目 试验研究
基金项目
收稿日期 2020/4/21
修改稿日期 2021/2/8
网络出版日期
作者单位点击查看
备注郁水峰(1987-),男,江苏南通人,工程师,大专
引用该论文: YU Shuifeng,YANG Yuming. Effect of Al2O3 Doping Content in Composite Plating Solution on Properties ofNi-P-Al2O3-PTFE Composite Plating[J]. Materials for mechancial engineering, 2021, 45(6): 8～13
郁水峰,杨玉明. 复合镀液中Al2O3掺杂量对Ni-P-Al2O3-PTFE复合镀层性能的影响[J]. 机械工程材料, 2021, 45(6): 8～13
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【16】CHEN S Y, SHI Y, HONG F, et al. Synthesis of Ni-P-PTFE-nano-Al2O3 composite plating coating on 45 steel by electroless plating[J]. Journal of Composite Materials, 2012, 46(12):1405-1416.
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【18】王勇, 杜克勤, 郭兴华,等.化学镀Ni-P-Al2O3复合镀层的研究[J].电镀与环保, 2013, 33(4):22-25. WANG Y, DU K Q, GUO X H, et al.A study of electroless Ni-P-Al2O3 composite coating[J].Electroplating & Pollution Control,2013, 33(4):22-25.
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【20】李亚敏, 王丽波, 刘洪军.机械研磨化学复合镀Ni-P-Al2O3工艺[J].兰州理工大学学报, 2012, 38(3):13-17. LI Y M, WANG L B, LIU H J. Technology of mechanical attrition and chemical composite plating with Ni-P-Al2O3[J].Journal of Lanzhou University of Technology,2012, 38(3):13-17.
【21】吴庆利, 吴蒙华, 黄树涛,等.超声-电沉积Ni-纳米Al2O3复合镀层耐蚀性能研究[J].表面技术, 2007, 36(1):1-4. WU Q L, WU M H, HUANG S T, et al. Study on the performance of corrosion resistance of ultrasonic-electrodeposited Ni-nano Al2O3 composite coatings[J]. Surface Technology, 2007, 36(1):1-4.
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【24】CHENG Y H, CHEN H Y, HAN D T, et al. Effect of PTFE addition on the properties of electroless Ni-Cu-P-PTFE deposits[J].Rare Metal Materials and Engineering, 2014,43(5):1025-1030.
【25】CHANG C S, HOU K H, GER M D, et al. Effects of annealing temperature on microstructure, surface roughness, mechanical and tribological properties of Ni-P and Ni-P/SiC films[J]. Surface & Coatings Technology, 2016, 288:135-143.
【26】BALARAJU J N,RAJAM K S.Electroless deposition of Ni-Cu-P,Ni-W-P and Ni-W-Cu-P alloys[J].Surface and Coatings Technology,2005,195(2/3):154-161.
【27】严芳芳, 牛克忠. Al2O3含量对Ni-P-Al2O3化学镀层性能的影响[J]. 新乡学院学报(自然科学版), 2013(3):186-188. YAN F F, NIU K Z. Effect of Al2O3 content on performance of electroless coating Ni-P-Al2O3[J].Journal of Xinxiang University(Natural Science Edition), 2013(3):186-188.
【28】周长海,刘爱莲,许玉容,等.Ni-P-Al2O3化学复合镀层的制备及其耐磨性能[J].黑龙江科技大学学报,2015,25(3):261-264. ZHOU C H, LIU A L, XU Y R, et al. Researches on fabrication and wear properties of electroless Ni-P-Al2O3 composite coatings[J].Journal of Heilongjiang University of Science and Technology, 2015,25(3):261-264.
【29】宫玉梅. 化学复合镀Ni-P/Al2O3制备工艺及耐蚀性能的研究[D]. 哈尔滨:哈尔滨工业大学, 2009. GONG Y M.Preparation and corrosion properties of electroless composite Ni-P/Al2O3 alloy[D].Harbin:Harbin Institute of Technology,2009.
【30】刘静,范永哲,曹晓明,等.AZ91D镁合金Ni-P-Al2O3纳米化学复合镀的研究[J].热加工工艺,2009,38(6):116-118. LIU J, FAN Y Z, CAO X M, et al. Study on electroless Ni-P-Al2O3compound coating on AZ91D alloy[J].Hot Working Technology,2009,38(6):116-118.
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