铁电材料光伏机理及其光伏性能的调控机制
Photovoltaic Mechanism and Regulation Mechanism of Photovoltaic Properties of Ferroelectric Materials
摘 要
铁电材料因自身极化电场的存在而具有独特的光伏性能，在诸多领域应用广泛，特别是在光伏发电方面。从窄带隙铁电材料的制备方法、氧缺位自掺杂增强可见光吸收、复合异质结构建、多极轴分子铁电体制备、外加极化场调控铁电材料内部电畴朝向与分布等方面综述了铁电材料内电场的产生机理（光伏机理）及其调控机制对铁电材料光伏性能的影响，指出了通过调控内电场提高光伏性能的研究方向。
自发极化
内建电场
异质结
氧缺位
分子铁电体
ferroelectric material
spontaneous polarization
internal electric field
heterojunction
oxygen deficiency
molecular ferroelectric
Abstract
Ferroelectric materials have unique photovoltaic properties due to their polarized electric field, and are widely used in many fields, especially in photovoltaic power generation. The generation mechanism of internal electric field (photovoltaic mechanism) in ferroelectric materials, and the effects of electric field regulation mechanism on photovoltaic properties of ferroelectric materials are reviewed from aspects of the preparation of narrow band gap ferroelectric materials, enhancing visible light absorption by self-doping of oxygen deficiency constructing composite heterojunction, preparing multipole axial molecular ferroelectrics, and regulating the domain orientation and distribution in ferroelectric materials by external polarization field. The research direction of improving photovoltaic performance by regulating internal electric field is pointed out.
中图分类号 TN384 DOI 10.11973/jxgccl202106014
所属栏目 专题报道（电子陶瓷）
基金项目 国家自然科学基金资助项目（51772184）
收稿日期 2021/3/15
修改稿日期 2121/4/29
网络出版日期
作者单位点击查看
备注朱明君(1990-),男,湖北黄冈人,硕士研究生
引用该论文: ZHU Mingjun,ZHANG Ganghua,LI Shasha,ZENG Tao. Photovoltaic Mechanism and Regulation Mechanism of Photovoltaic Properties of Ferroelectric Materials[J]. Materials for mechancial engineering, 2021, 45(6): 79～84
朱明君,张刚华,李莎莎,曾涛. 铁电材料光伏机理及其光伏性能的调控机制[J]. 机械工程材料, 2021, 45(6): 79～84
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【37】LI J,ZHANG G H,HAN S F,et al.Enhanced solar absorption and visible-light photocatalytic and photoele-ctrochemical properties of aluminium-reduced BaTiO3 nanoparticles[J].Chemical Communications,2018,54(7):723-726.
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