钛酸铅系功能陶瓷改性的研究现状及改性陶瓷的应用现状
Research Status of Modification of Lead Titanate Series Functional Ceramics and Application of Modified Ceramics
摘 要
钛酸铅系陶瓷是一种重要的功能材料，在压电领域应用广泛。该陶瓷存在烧结、极化困难，压电性能低的问题，其烧结和压电性能是目前的研究热点。综述了通过元素掺杂和组元添加对钛酸铅系陶瓷进行改性以改善烧结性能和压电性能的研究现状，以及改性后陶瓷的应用现状。指出了未来的研究方向，包括烧结工艺的优化、元素复合掺杂以及准同型相界区的成分设计等。
掺杂改性
组元添加
压电性能
lead titanate series ceramics
doping modification
component addition
piezoelectric property
Abstract
Lead titanate series ceramics are important functional materials and are widely used in piezoelectric field. The ceramics are difficult to sinter and polarize, and the piezoelectric property is relatively low. The sintering and piezoelectric properties are research focus at present. The research status of modifying lead titanate series ceramics by element doping and component addition to improve the sintering property and piezoelectric property, and the application of modified ceramics are reviewed. The future research directions are pointed out, including optimization of sintering process, element composite doping and composition design of quasi-homotype phase boundary.
中图分类号 TM282 DOI 10.11973/jxgccl202106017
所属栏目 专题报道（电子陶瓷）
基金项目 上海市科学技术委员会国际科技合作项目（20520730600）；上海材料研究所技术创新项目（20181303）
收稿日期 2021/4/9
修改稿日期 2021/5/10
网络出版日期
作者单位点击查看
备注黄建(1995-),男,山东淄博人,硕士研究生
引用该论文: HUANG Jian,ZHANG Xuewu,ZHAO Cheng,ZENG Tao,ZHUANG Xuning. Research Status of Modification of Lead Titanate Series Functional Ceramics and Application of Modified Ceramics[J]. Materials for mechancial engineering, 2021, 45(6): 94～98
黄建,张学伍,赵程,曾涛,庄绪宁. 钛酸铅系功能陶瓷改性的研究现状及改性陶瓷的应用现状[J]. 机械工程材料, 2021, 45(6): 94～98
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参考文献
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【2】张素芳.钛酸铅系电子陶瓷的制备及其电性能[D].石家庄:河北师范大学,2003. ZHANG S F.Preparation and electric properties of lead-based titanate ceramics[D].Shijiazhuang:Hebei Normal University,2003.
【3】WU J G,SHI H D,ZHAO T L,et al.High-temperature BiScO3-PbTiO3 piezoelectric vibration energy harvester[J].Advanced Functional Materials,2016,26(39):7186-7194.
【4】吕笑梅,黄凤珍,朱劲松.铁电材料中的电畴:形成、结构、动性及相关性能[J].物理学报,2020,69(12):33-50. LV X M,HUANG F Z,ZHU J S.Domains in ferroelectrics:Formation,structure,mobility and related properties[J].Acta Physica Sinica,2020,69(12):33-50.
【5】胡亚伟.钙掺杂钛酸铅陶瓷纤维的制备与表征[J].中国陶瓷,2018,54(5):52-58. HU Y W.Preparation and characterization of calcium doped PbTiO3 ceramic fibers[J].China Ceramics,2018,54(5):52-58.
【6】ROY M,DAVE P,BARBAR S K,et al.X-ray,SEM,and DSC studies of ferroelectric Pb1-xBaxTiO3 ceramics[J].Journal of Thermal Analysis and Calorimetry,2010,101(3):833-837.
【7】BAJAJ N,NEGI P,RAWAT S,et al.Sol-gel synthesis,dielectric,and morphological characterization of Pb1-xSrxTiO3 (x=0.8) ferroelectric perovskite[J].Journal of Sol-Gel Science and Technology,2019,90(3):589-598.
【8】张衡,赵晶,韩康,等.镧掺杂对钛酸铅粉体形貌及粒径的影响[J].无机盐工业,2011,43(8):18-20. ZHANG H,ZHAO J,HAN K,et al.Effects of lanthanum doping on morphology and particle size of lead titanate powders[J].Inorganic Chemicals Industry,2011,43(8):18-20.
【9】张衡.稀土掺杂钛酸铅系电子陶瓷的制备与表征[D].石家庄:河北师范大学,2005. ZHANG H.Preparation and properties of rare earth-doped lead-based titanate piezoelectric ceramics[D].Shijiazhuang:Hebei Normal University,2005.
【10】SAHU N.Morphological,elemental and diffused phase transition of La modified PbTiO3 Ceramics[J].International Journal of Research in Engineering and Applied Sciences, 2017, 7(4):29-37.
【11】CHU S Y,CHEN C H.Effect of calcium on the piezoelectric and dielectric properties of Sm-modified PbTiO3 ceramics[J].Sensors and Actuators A:Physical,2001,89(3):210-214.
【12】姚国华,崔丰慧,朱金良,等.PbTiO3压电陶瓷掺杂改性研究[J].电子元件与材料,2014,33(12):14-16. YAO G H,CUI F H,ZHU J L,et al.Study of doping modifying property on PbTiO3 ceramics[J].Electronic Components and Materials,2014,33(12):14-16.
【13】XIN H,PANG Q,GAO D L,et al.Effect of Mn doping defect on 180° domain wall in ferroelectric PbTiO3[J].Physics Letters A,2020,384(14):126279.
【14】杜刚,梁瑞虹,李涛,等.压电材料中缺陷偶极子特性的研究进展[J].无机材料学报,2013,28(2):123-130. DU G,LIANG R H,LI T,et al.Recent progress on defect dipoles characteristics in piezoelectric materials[J].Journal of Inorganic Materials,2013,28(2):123-130.
【15】TANG S W,ZHU L H,LIU Q F,et al.Effect of Sb,Mn-dopant on microstructure and properties of Pb0.80Ca0.20TiO3 ceramics[J].Journal of the Chinese Ceramic Society,2015,43(9):1261-1265.
【16】ZHAO T L,FEI C L,DAI X Y,et al.Structure and enhanced piezoelectric performance of BiScO3-PbTiO3-Pb(Ni1/3Nb2/3)O3 ternary high temperature piezoelectric ceramics[J].Journal of Alloys and Compounds,2019,806:11-18.
【17】EITEL R E,RANDALL C A,SHROUT T R,et al.New high temperature morphotropic phase boundary piezoelectrics based on Bi(Me)O3-PbTiO3 ceramics[J].Japanese Journal of Applied Physics,2001,40(10):5999-6002.
【18】褚涛,王五松,张元松,等.Bi(Me)O3-PbTiO3型高温压电陶瓷研究进展[J].陶瓷,2019(2):61-65. CHU T,WANG W S,ZHANG Y S,et al.Research progress of piezoelectric ceramics based on Bi(Me)O3-PbTiO3 with high curie temperature[J].Ceramics,2019(2):61-65.
【19】DAI Z H,XIE J L,LIU W G,et al.High piezoelectricity of BiScO3-PbTiO3 ceramics prepared by two step sintering[J].Materials Letters,2019,241:55-59.
【20】ZHAO T L,FEI C L,PU K W,et al.Structure evolution and enhanced electrical performance for BiScO3-Bi(Ni1/2Zr1/2)O3-PbTiO3 solid solutions near the morphotropic phase boundary[J].Journal of Alloys and Compounds,2021,873:159844.
【21】刘康,蓝振成,陈开远,等.钪酸铋-钛酸铅高温压电陶瓷的相结构和高温压电稳定性[J].陶瓷学报,2020,41(6):935-944. LIU K,LAN Z C,CHEN K Y,et al.Phase structure and high temperature piezoelectric stability of BiScO3-PbTiO3 high temperature piezoelectric ceramics[J].Journal of Ceramics,2020,41(6):935-944.
【22】YU Y,YANG J K,WU J G,et al.Ultralow dielectric loss of BiScO3-PbTiO3 ceramics by Bi(Mn1/2Zr1/2)O3 modification[J].Journal of the European Ceramic Society,2020,40(8):3003-3010.
【23】QAISER M A,MA X Z,MA R T,et al.High-temperature multilayer actuators based on CuO added BiScO3 -PbTiO3 piezoceramics and Ag electrodes[J].Journal of the American Ceramic Society,2019,102(9):5424-5431.
【24】欧阳明智,朱满康,侯育冬,等.高频压电器件用Co2O3改性PbTiO3基压电陶瓷[J].压电与声光,2011,33(1):130-132. OUYANG M Z,ZHU M K,HOU Y D,et al.The development of Co2O3-modified PbTiO3-based piezoelectric ceramic for high frequency devices[J].Piezoelectrics & Acoustooptics,2011,33(1):130-132.
【25】KE Q,LIEW W H,ZHANG L,et al.Broadband ultrasonic array transducer from multilayer piezoelectric ceramic with lowered co-firing temperature[J].IEEE Transactions on Ultrasonics,Ferroelectrics,and Frequency Control,2020,67(5):968-974.
【26】LIN P F,FEI C L,HOU S,et al.0.36BiScO3-0.64PbTiO3/epoxy 1-3 composite for ultrasonic transducer applications[J].IEEE Sensors Journal,2018,18(14):5685-5690.
【27】田玥.弛豫铁电薄膜PMN-0.26PT的制备及其性能的研究[D].上海:上海师范大学,2011. TIAN Y.Preparation and characterization of relaxor ferroelectric PMN-0.26PT thin films[D].Shanghai:Shanghai Normal University,2011.
【28】CHI Q G,WANG X,LI W L,et al.Enhanced performance of Pb0.8La0.1Ca0.1Ti0.975O3/Pb(Nb0.01Zr0.2Ti0.8)O3 multilayer thin films for pyroelectric applications[J].Applied Physics Letters,2011,98(24):242903.
【29】阳攀,王五松,雷涛.Mn含量对Al掺杂PMN-PMS-PZT陶瓷介电性能的影响[J].中国陶瓷,2020,56(1):41-46. YANG P,WANG W S,LEI T.Effect of Mn content on dielectric properties of Al-doped PMN-PMS-PZT ceramics[J].China Ceramics,2020,56(1):41-46.
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