Structure of Zeolitic Imidazolate Frameworks Derived Carbon-based Compositeand Properties of Its Supercapacitor
摘 要
通过原位生长方法将沸石咪唑酯骨架颗粒镶嵌在聚吡咯管(质量分别为30,60,120 mg)上,再经一步热处理法碳化和活化后制备得到碳基复合材料,研究了该材料的微观结构和电化学性能,以及其组装的双电层超级电容器的电化学性能。结果表明:复合材料由碳纳米管和管外表面的氮掺杂碳颗粒组成,具有较大的比表面积和高的氮元素含量,微孔孔径集中分布在1 nm左右;复合材料具有良好的充放电可逆性和倍率性能,并表现出典型的双电层电容行为。在相同条件下,聚吡咯管质量为60 mg时复合材料的电化学性能最优,其在1 A·g-1电流密度下的比电容最大,为283 F·g-1;由该复合材料组装的对称型超级电容器具有优异的循环稳定性,在2 A·g-1充放电电流密度下循环3 000次后,其比电容保持率为91.5%,能量密度高达9.15 Wh·kg-1。
Abstract
Zeolite imidazolate framework particles were embedded into polypyrrole tubes (mass of 30,60,120 mg) by in-situ growth method, and then carbon-based composites were prepared by carbonization and activation with one-step heat treatment. The microstructure and electrochemical properties of the materials and the electrochemical performance of the assembled double-layer supercapacitor were studied. The results show that the composites were composed of carbon nanotubes and nitrogen-doped carbon particles on the outer surface of the tubes; the composites had large specific surface area and high nitrogen content, and the micropore diameter was concentrated at about 1 nm. The composites had good charge-discharge reversibility and rate performance, and exhibited typical double-layer capacitance behavior. The electrochemical performance of the composites with 60 mg polypyrrole tubes was the best under the same condition, and the composite had the largest specific capacitance of 283 F·g-1 at current density of 1 A·g-1. The symmetrical supercapacitor assembled by the composite had excellent cycle stability with specific capacitance retention rate of 91.5% after 3 000 cycles at charge-discharge current density of 2 A·g-1 and with energy density of 9.15 Wh·kg-1.
中图分类号 TM242 DOI 10.11973/jxgccl202107010
所属栏目 材料性能及应用
基金项目
收稿日期 2020/8/24
修改稿日期 2021/5/20
网络出版日期
作者单位点击查看
备注叶艳秋(1985-),女,河南周口人,讲师,学士
引用该论文: YE Yanqiu. Structure of Zeolitic Imidazolate Frameworks Derived Carbon-based Compositeand Properties of Its Supercapacitor[J]. Materials for mechancial engineering, 2021, 45(7): 51~56
叶艳秋. 沸石咪唑酯骨架衍生碳基复合材料的结构及其超级电容器的性能[J]. 机械工程材料, 2021, 45(7): 51~56
共有人对该论文发表了看法,其中:
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】ZHANG L L,ZHAO X S.Carbon-based materials as supercapacitor electrodes[J].Chemical Society Reviews,2009,38(9):2520-2531.
【2】NITTA N, WU F, LEE J T, et al. Li-ion battery materials:Present and future[J]. Materials Today, 2015, 18:252-264.
【3】ZHAI Y,DOU Y,ZHAO D,et al.Carbon materials for chemical capacitive energy storage[J].Advanced Materials,2011,23(42):4828-4850.
【4】ZHONG C,ZHONG C,DENG Y,et al.A review of electrolyte materials and compositions for electrochemical supercapacitors[J].Chemical Society Reviews,2015,44(21):7484-7539.
【5】WANG Q, ASTRUC D. State of the art and prospects in metal-organic framework (MOF)-based and MOF-derived nanocatalysis[J].Chemical reviews, 2019, 120(2):1438-1551.
【6】GU M L, WU M K, WANG S C, et al. Morphology control of nanoscale metal-organic frameworks for high-performance supercapacitors[J].Electrochimica Acta, 2020, 343:135617.
【7】JAVED M S,SHAHEEN N,HUSSAIN S,et al.An ultra-high energy density flexible asymmetric supercapacitor based on hierarchical fabric decorated with 2D bimetallic oxide nanosheets and MOF-derived porous carbon polyhedra[J].Journal of Materials Chemistry A,2019,7(3):946-957.
【8】CAO X H, TAN C L, SINDORO M, et al. Hybrid micro-/nano-structures derived from metal-organic frameworks:Preparation and applications in energy storage and conversion[J].Chemical Society reviews, 2017, 46:2660-2677.
【9】YANG Y,LI S,HUANG W,et al.Effective synthetic strategy for Zn0.76Co0.24S encapsulated in stabilized N-doped carbon nanoarchitecture towards ultra-long-life hybrid supercapacitors[J].Journal of Materials Chemistry A,2019,7(24):14670-14680.
【10】FAIREN-JIMENEZ D,MOGGACH S A,WHARMBY M T,et al.Opening the gate:Framework flexibility in ZIF-8 explored by experiments and simulations[J].Journal of the American Chemical Society,2011,133(23):8900-8902.
【11】LEI Z W,DENG Y H,WANG C Y.Multiphase surface growth of hydrophobic ZIF-8 on melamine sponge for excellent oil/water separation and effective catalysis in a Knoevenagel reaction[J].Journal of Materials Chemistry A,2018,6(7):3258-3263.
【12】SONG Y, WANG H, YU W S, et al. Synergistic stabilizing lithium sulfur battery via nanocoating polypyrrole on cobalt sulfide nanobox[J].Journal of Power Sources, 2018, 405:51-60.
【13】MENG J S,NIU C J,XU L H,et al.General oriented formation of carbon nanotubes from metal-organic frameworks[J].Journal of the American Chemical Society,2017,139(24):8212-8221.
【14】MIAO C X,XIAO X H,GONG Y,et al.Facile synthesis of metal-organic framework-derived CoSe2 nanoparticles embedded in the N-doped carbon nanosheet array and application for supercapacitors[J].ACS Applied Materials & Interfaces,2020,12(8):9365-9375.
【15】CHENG D D, ZHAO Y L, Tang X W, et al. Densely integrated Co, N-Co doped graphene@carbon nanotubes porous hybrids for high-performance lithium-sulfur batteries[J].Carbon, 2019, 149:750-759.
【16】WANG Z, HUANG J H, GUO Z W, et al. A metal-organic framework host for highly reversible dendrite-free zinc metal anodes[J]. Joule, 2019, 3(5):1289-1300.
【17】WANG Z S, SHEN J D, JI S M, et al. B, N Co doped graphitic nanotubes loaded with Co nanoparticles as superior sulfur host for advanced Li-S batteries[J]. Small, 2020,16:1906634.
【18】MA C, CHEN X Y, LONG D H, et al. High-surface-area and high-nitrogen-content carbon microspheres prepared by a pre-oxidation and mild KOH activation for superior supercapacitor[J].Carbon, 2017, 118:699-708.
【19】ZHONG S,ZHAN C X,CAO D P.Zeolitic imidazolate framework-derived nitrogen-doped porous carbons as high performance supercapacitor electrode materials[J].Carbon,2015,85:51-59.
【20】QIU Y,ZHANG X,YANG S.High performance supercapacitors based on highly conductive nitrogen-doped graphene sheets[J].Physical Chemistry Chemical Physics,2011,13(27):12554-12558.
【21】BÉGUIN F, SZOSTAK K, LOTA G, et al. A self-supporting electrode for supercapacitors prepared by one-step pyrolysis of carbon nanotube/polyacrylonitrile blends[J].Advanced materials,2005, 17:2380-2384.
【22】DENG X Y, ZHU S, LI J J, et al. Bio-inspired three-dimensional carbon network with enhanced mass-transfer ability for supercapacitors[J].Carbon, 2019, 143:728-735.
【2】NITTA N, WU F, LEE J T, et al. Li-ion battery materials:Present and future[J]. Materials Today, 2015, 18:252-264.
【3】ZHAI Y,DOU Y,ZHAO D,et al.Carbon materials for chemical capacitive energy storage[J].Advanced Materials,2011,23(42):4828-4850.
【4】ZHONG C,ZHONG C,DENG Y,et al.A review of electrolyte materials and compositions for electrochemical supercapacitors[J].Chemical Society Reviews,2015,44(21):7484-7539.
【5】WANG Q, ASTRUC D. State of the art and prospects in metal-organic framework (MOF)-based and MOF-derived nanocatalysis[J].Chemical reviews, 2019, 120(2):1438-1551.
【6】GU M L, WU M K, WANG S C, et al. Morphology control of nanoscale metal-organic frameworks for high-performance supercapacitors[J].Electrochimica Acta, 2020, 343:135617.
【7】JAVED M S,SHAHEEN N,HUSSAIN S,et al.An ultra-high energy density flexible asymmetric supercapacitor based on hierarchical fabric decorated with 2D bimetallic oxide nanosheets and MOF-derived porous carbon polyhedra[J].Journal of Materials Chemistry A,2019,7(3):946-957.
【8】CAO X H, TAN C L, SINDORO M, et al. Hybrid micro-/nano-structures derived from metal-organic frameworks:Preparation and applications in energy storage and conversion[J].Chemical Society reviews, 2017, 46:2660-2677.
【9】YANG Y,LI S,HUANG W,et al.Effective synthetic strategy for Zn0.76Co0.24S encapsulated in stabilized N-doped carbon nanoarchitecture towards ultra-long-life hybrid supercapacitors[J].Journal of Materials Chemistry A,2019,7(24):14670-14680.
【10】FAIREN-JIMENEZ D,MOGGACH S A,WHARMBY M T,et al.Opening the gate:Framework flexibility in ZIF-8 explored by experiments and simulations[J].Journal of the American Chemical Society,2011,133(23):8900-8902.
【11】LEI Z W,DENG Y H,WANG C Y.Multiphase surface growth of hydrophobic ZIF-8 on melamine sponge for excellent oil/water separation and effective catalysis in a Knoevenagel reaction[J].Journal of Materials Chemistry A,2018,6(7):3258-3263.
【12】SONG Y, WANG H, YU W S, et al. Synergistic stabilizing lithium sulfur battery via nanocoating polypyrrole on cobalt sulfide nanobox[J].Journal of Power Sources, 2018, 405:51-60.
【13】MENG J S,NIU C J,XU L H,et al.General oriented formation of carbon nanotubes from metal-organic frameworks[J].Journal of the American Chemical Society,2017,139(24):8212-8221.
【14】MIAO C X,XIAO X H,GONG Y,et al.Facile synthesis of metal-organic framework-derived CoSe2 nanoparticles embedded in the N-doped carbon nanosheet array and application for supercapacitors[J].ACS Applied Materials & Interfaces,2020,12(8):9365-9375.
【15】CHENG D D, ZHAO Y L, Tang X W, et al. Densely integrated Co, N-Co doped graphene@carbon nanotubes porous hybrids for high-performance lithium-sulfur batteries[J].Carbon, 2019, 149:750-759.
【16】WANG Z, HUANG J H, GUO Z W, et al. A metal-organic framework host for highly reversible dendrite-free zinc metal anodes[J]. Joule, 2019, 3(5):1289-1300.
【17】WANG Z S, SHEN J D, JI S M, et al. B, N Co doped graphitic nanotubes loaded with Co nanoparticles as superior sulfur host for advanced Li-S batteries[J]. Small, 2020,16:1906634.
【18】MA C, CHEN X Y, LONG D H, et al. High-surface-area and high-nitrogen-content carbon microspheres prepared by a pre-oxidation and mild KOH activation for superior supercapacitor[J].Carbon, 2017, 118:699-708.
【19】ZHONG S,ZHAN C X,CAO D P.Zeolitic imidazolate framework-derived nitrogen-doped porous carbons as high performance supercapacitor electrode materials[J].Carbon,2015,85:51-59.
【20】QIU Y,ZHANG X,YANG S.High performance supercapacitors based on highly conductive nitrogen-doped graphene sheets[J].Physical Chemistry Chemical Physics,2011,13(27):12554-12558.
【21】BÉGUIN F, SZOSTAK K, LOTA G, et al. A self-supporting electrode for supercapacitors prepared by one-step pyrolysis of carbon nanotube/polyacrylonitrile blends[J].Advanced materials,2005, 17:2380-2384.
【22】DENG X Y, ZHU S, LI J J, et al. Bio-inspired three-dimensional carbon network with enhanced mass-transfer ability for supercapacitors[J].Carbon, 2019, 143:728-735.
相关信息