Determination of Acrylic Acid in Water by Ion Chromatography with Gradient Elution of Hydroxide Ion
摘 要
建立了氢氧根梯度淋洗离子色谱法测定水中丙烯酸的方法。用塑料瓶或玻璃瓶采集水样,于10 ℃以下保存,48 h内完成分析。将水样pH调至7以上后依次经Na柱、Ag柱和C18柱快速净化,然后通过氢氧根淋洗液自动发生器梯度淋洗以分离丙烯酸,流量为1.0 mL·L-1,柱温为30 ℃。以抑制型电导检测器测定,外标法定量。在优化的条件下,丙烯酸的质量浓度在20.0 mg·L-1以内与其峰面积呈线性关系,检出限为0.02 mg·L-1。不同质量浓度实际样品测定值的相对标准偏差(n=6)为1.6%~7.2%。对地下水、地表水、工业废水、生活污水进行加标回收试验,回收率为96.8%~124%。
Abstract
A method for the determination of acrylic acid in water by ion chromatography with gradient elution of hydroxide ion was established. The water sample was collected in plastic bottles or glass bottles, and could be stored below 10 ℃ and analyzed within 48 h. The water sample with pH above 7 was purified quickly by Na column, Ag column and C18 column in sequence. Acrylic acid was separated by gradient leaching with an automatic hydroxide ion eluent generator at flow rate of 1.0 mL·L-1 and column temperature of 30 ℃, and then determined by suppressed conductivity detector and quantified by external standard method. Under the optimal conditions, linear relationship between values of peak area and mass concentration of acrylic acid was found within 20.0 mg·L-1, with detection limit of 0.02 mg·L-1. RSDs (n=6) of the determined values for the actual samples with different mass concentration ranged from 1.6% to 7.2%. Recovery test was made for groundwater, surface water, industrial wastewater and domestic sewage, giving results in the range of 96.8%-124%.
中图分类号 O652.63 DOI 10.11973/lhjy-hx202108010
所属栏目 工作简报
基金项目 生态环境部标准编制项目(2020-20)
收稿日期 2021/2/21
修改稿日期
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联系人作者韩少强(hsq8699@126.com)
备注杨璟爱,工程师,研究方向为环境监测领域有机分析和理化分析
引用该论文: YANG Jing'ai,HAN Shaoqiang,GUAN Yuchun,ZHAO Li,WANG Jilu,CHEN Chen,ZHANG Yani. Determination of Acrylic Acid in Water by Ion Chromatography with Gradient Elution of Hydroxide Ion[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2021, 57(8): 726~731
杨璟爱,韩少强,关玉春,赵莉,王记鲁,陈晨,张亚尼. 氢氧根梯度淋洗离子色谱法测定水中丙烯酸[J]. 理化检验-化学分册, 2021, 57(8): 726~731
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参考文献
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【4】曾芳,陈泽宏,蔡云梅,等.废气中丙烯酸测定方法对比研究[J].山东工业技术, 2015(16):286-286.
【5】CASELLA I G, PIERRI M, CONTURSI M. Determination of acrylamide and acrylic acid by isocratic liquid chromatography with pulsed electrochemical detection[J]. Journal of Chromatography A, 2006,1107(1/2):198-203.
【6】王华,张爱平.气相色谱法测定丙烯酸研究[J].分析科学学报, 2006,22(4):461-463.
【7】VAIRAVAMURTHY A, ANDREAE M O, BROOKS J M. Determination of acrylic acid in aqueous samples by electron capture gas chromatography after extraction with tri-n-octylphosphine oxide and derivatization with pentafluorobenzyl bromide[J]. Analytical Chemistry, 1986,58(13):2684-2687.
【8】王华,谭亚南,韩伟,等.色谱法测定丙烷氧化制丙烯酸液相组分含量[J].四川化工, 2018,21(5):36-38.
【9】LEE Z Y, RAGHAVAN S S, GHADESSY F J, et al. Rapid and sensitive detection of acrylic acid using a novel fluorescence assay[J]. RSC Advance, 2014,4(104):60216-60220.
【10】CUTIÉ S S, KALLOS G J, SMITH P B. Separation and characterization of acrylic acid oligomers by nuclear magnetic resonance spectroscopy and thermospray ion-exchange liquid chromatography-mass spectrometry[J]. Journal of Chromatography A, 1987,408:349-355.
【11】余家胜,贺婕,钟乃飞,等.离子色谱法同时测定纺织业退浆料中的丙烯酸和对苯二甲酸[J].浙江大学学报(理学版), 2015,42(3):325-329.
【12】石海宁,王辉,陶丽芝,等.阴离子交换离子色谱法测定乳酸催化制备的丙烯酸[J].色谱, 2010,28(6):628-631.
【13】陈霞,栾建平.离子色谱法测定饮用水中6种有机酸[J].理化检验-化学分册, 2015,51(9):1336-1338.
【14】范志庆,宋玉栋,周岳溪.离子色谱法测定丙烯酸丁酯生产废水中丙烯酸和对甲基苯磺酸[J].中国环境监测, 2010,26(3):26-29.
【15】黄桂荣,刁小冬.离子色谱法测定废气中的丙烯酸[J].环境监测管理与技术, 2012,24(5):61-63.
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