粮食中农药残留检测的主要前处理方法的介绍及应用
Introduction and Application of Main Pretreatment Methods for Detection of Pesticide Residues in Grain
摘 要
介绍了固相萃取法、分散液液微萃取法、QuEChERS等前处理方法及新型纳米材料（磁性纳米材料、分子印迹聚合物、碳纳米管基复合材料）及其在粮食农药残留检测时的优缺点、工作原理、研究现状及未来的发展方向（引用文献61篇），并建议：1 针对粮食中农药残留量低、粮食种类繁多及基质复杂等情况，应根据基质类型、仪器种类和检测要求选择合适的前处理方法；2 应用于粮食中农药检测的前处理方法各有优劣，可联合运用不同的前处理方法。
农药残留
前处理方法
综述
grain
pesticide residue
pretreatment method
review
Abstract
Pretreatment methods including of solid phase extraction, dispersive liquid-liquid microextraction and QuEChERS, as well as new nanocomposites including magnetic nanomaterials, moleculorly imprinted polymers and carbon nanotube-based composites, and their advantages and disadvantages, working principles, research status and future development directions in the detection of pesticide residues in grain were introduced (61 references cited). It was suggested that: 1 appropriate pretreatment methods should be selected according to matrix types, instrument types and detection requirements in response to low pesticide residues, various types of grain and complex matrix of grain; 2 the pretreatment methods used for the detection of pesticides in grain had their own advantages and disadvantages, and different pretreatment methods could be used in combination.
中图分类号 O65 DOI 10.11973/lhjy-hx202109011
所属栏目 综述
基金项目
收稿日期 2020/10/9
修改稿日期
网络出版日期
作者单位点击查看
联系人作者曹慧(caohuian@126.com)
备注孔亚南,硕士研究生,主要从事粮食中有机磷、氨基甲酸酯、拟除虫菊酯等农药提取等方面研究工作
引用该论文: KONG Ya,CAO Hui,XU Fei,YUAN Min,YE Tai,YU Jinsong,HAO Liling. Introduction and Application of Main Pretreatment Methods for Detection of Pesticide Residues in Grain[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2021, 57(9): 816～823
孔亚南,曹慧,徐斐,袁敏,叶泰,于劲松,郝丽玲. 粮食中农药残留检测的主要前处理方法的介绍及应用[J]. 理化检验－化学分册, 2021, 57(9): 816～823
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参考文献
【1】ZHOU P P, CHEN K, GAO M, et al. Magnetic effervescent tablets containing ionic liquids as a non-conventional extraction and dispersive agent for determination of pyrethroids in milk[J]. Food Chemistry, 2018, 268:468-475.
【2】MOURTZINIS S, CONLEY S P, GASKA J M. Agronomic management and fungicide effects on oat yield and quality[J]. Crop Science, 2015, 55(3):1290-1294.
【3】SUN X, ZHAN F P, YU R Q, et al. Bio-accumulation of organic contaminants in Indo-Pacific humpback dolphins:Preliminary unique features of the brain and testes[J]. Environmental Pollution, 2020, 267:115511.
【4】FU D J, LI P, SONG J, et al. Mechanisms of synergistic neurotoxicity induced by two high risk pesticide residues - Chlorpyrifos and carbofuran via oxidative stress[J]. Toxicology in Vitro, 2019, 54:338-344.
【5】PAYNE-STURGES D, COHEN J, CASTORINA R, et al. Evaluating cumulative organophosphorus pesticide body burden of children:A national case study[J]. Environmental Science & Technology, 2009, 43(20):7924-7930.
【6】CHEN L, WANG D Z, ZHOU Z Q, et al. Comparing alpha-cypermethrin induced dose/gender-dependent responses of lizards in hepatotoxicity and nephrotoxicity in a food chain[J]. Chemosphere, 2020, 256:127069.
【7】GIUDICE L C. Environmental toxicants:Hidden players on the reproductive stage[J]. Fertility and Sterility, 2016, 106(4):791-794.
【8】MONTEMURRO M, BRASCA R, CULZONI M J, et al. High-performance organized media-enhanced spectrofluorimetric determination of pirimiphos-methyl in maize[J]. Food Chemistry, 2019, 278:711-719.
【9】KIM Y A, LEE E H, KIM K O, et al. Competitive immunochromatographic assay for the detection of the organophosphorus pesticide chlorpyrifos[J]. Analytica Chimica Acta, 2011, 693(1/2):106-113.
【10】MOHAMMADI P, GHORBANI M, MOHAMMADI P, et al. Dispersive micro solid-phase extraction with gas chromatography for determination of diazinon and ethion residues in biological, vegetables and cereal grain samples, employing D-optimal mixture design[J]. Microchemical Journal, 2021, 160:105680.
【11】DA SILVA L P, MADUREIRA F, DE AZEVEDO VARGAS E, et al. Development and validation of a multianalyte method for quantification of mycotoxins and pesticides in rice using a simple dilute and shoot procedure and UHPLC-MS/MS[J]. Food Chemistry, 2019, 270:420-427.
【12】FRANCESQUETT J Z, RIZZETTI T M, CADAVAL T R S JR, et al. Simultaneous determination of the quaternary ammonium pesticides paraquat, diquat, chlormequat, and mepiquat in barley and wheat using a modified quick polar pesticides method, diluted standard addition calibration and hydrophilic interaction liquid chromatography coupled to tandem mass spectrometry[J]. Journal of Chromatography A, 2019, 1592:101-111.
【13】孙聪.农残检测中基质效应的研究[J]. 现代农村科技, 2020(3):117-118.
【14】罗远洲.气液色谱法测定大米中六六六、DDT残留量的比较试验[J]. 粮食贮藏, 1982, 11(6):42-45.
【15】刘敏.毛细管色谱柱检测粮食中15种有机氯农药残留量[J]. 粮食与饲料工业, 2017(4):58-60.
【16】孟玲芝, 刘坤, 刘荣光, 等. 固相萃取技术在农药残留检测中的应用[J]. 吉林农业, 2018(12):55-55.
【17】PŁOTKA-WASYLKA J, SZCZEPAHSKA N, DE LA G M, et al. Modern trends in solid phase extraction:New sorbent media[J]. TrAC Trends in Analytical Chemistry, 2016, 77:23-43.
【18】林星辰, 余彬彬, 叶丹霞.固相萃取技术新发展及其在环境分析中的应用[J]. 化工时刊, 2014, 28(9):28-34.
【19】JI W H, DING H, GENG Y L, et al. Monodisperse cobalt(Ⅱ) based metal-organic coordination polymer beads as a sorbent for solid-phase extraction of chlorophenoxy acid herbicides prior to their quantitation by HPLC[J]. Microchimica Acta, 2019, 186(12):1-8.
【20】MICHEL M, GNUSOWSKI B, BUSZEWSKI B. Comparison of various extraction techniques to determine fungicide residue in wheat grain[J]. Journal of Liquid Chromatography & Related Technologies, 2006, 29(2):247-261.
【21】LAWAL A, WONG R C S, TAN G H, et al. Recent modifications and validation of QuEChERS-dSPE coupled to LC-MS and GC-MS instruments for determination of pesticide/agrochemical residues in fruits and vegetables:Review[J]. Journal of Chromatographic Science, 2018, 56(7):656-669.
【22】ANASTASSIADES M, LEHOTAY S J, ŠTAJNBAHER D, et al. Fast and easy multiresidue method employing acetonitrile extraction/partitioning and "dispersive solid-phase extraction" for the determination of pesticide residues in produce[J]. Journal of AOAC INTERNATIONAL, 2003, 86(2):412-431.
【23】PERESTRELO R, SILVA P, PORTO-FIGUEIRA P, et al. QuEChERS-Fundamentals, relevant improvements, applications and future trends[J]. Analytica Chimica Acta, 2019, 1070:1-28.
【24】MUSARURWA H, CHIMUKA L, PAKADE V E, et al. Recent developments and applications of QuEChERS based techniques on food samples during pesticide analysis[J]. Journal of Food Composition and Analysis, 2019, 84:103314.
【25】WILKOWSKA A, BIZIUK M. Determination of pesticide residues in food matrices using the QuEChERS methodology[J]. Food Chemistry, 2011, 125(3):803-812.
【26】WANG P, YANG X, WANG J, et al. Multi-residue method for determination of seven neonicotinoid insecticides in grains using dispersive solid-phase extraction and dispersive liquid-liquid micro-extraction by high performance liquid chromatography[J]. Food Chemistry, 2012, 134(3):1691-1698.
【27】HE Z Y, WANG L, PENG Y, et al. Multiresidue analysis of over 200 pesticides in cereals using a QuEChERS and gas chromatography-tandem mass spectrometry-based method[J]. Food Chemistry, 2015, 169:372-380.
【28】HERRMANN S S, POULSEN M E. Clean-up of cereal extracts for gas chromatography-tandem quadrupole mass spectrometry pesticide residues analysis using primary secondary amine and C18[J]. Journal of Chromatography A, 2015, 1423:47-53.
【29】NI Y X, YANG H, ZHANG H T, et al. Analysis of four sulfonylurea herbicides in cereals using modified quick, easy, cheap, effective, rugged, and safe sample preparation method coupled with liquid chromatography-tandem mass spectrometry[J]. Journal of Chromatography A, 2018, 1537:27-34.
【30】LEE Y J, RAHMAN M M, ABD EL-ATY A M, et al. Detection of three herbicide, and one metabolite, residues in brown rice and rice straw using various versions of the QuEChERS method and liquid chromatography-tandem mass spectrometry[J]. Food Chemistry, 2016, 210:442-450.
【31】LEHOTAY S J, COLLABORATORS, O'NEIL M, et al. Determination of pesticide residues in foods by acetonitrile extraction and partitioning with magnesium sulfate:Collaborative study[J]. Journal of AOAC INTERNATIONAL, 2007, 90(2):485-520.
【32】LU Z, FANG N, ZHANG Z B, et al. Residue analysis of fungicides fenpicoxamid, isofetamid, and mandestrobin in cereals using zirconium oxide disposable pipette extraction clean-up and ultrahigh-performance liquid chromatography-tandem mass spectrometry[J]. Journal of Chromatography A, 2020, 1620:461004.
【33】REZAEE M, ASSADI Y, MILANI H M R, et al. Determination of organic compounds in water using dispersive liquid-liquid microextraction[J]. Journal of Chromatography A, 2006, 1116(1/2):1-9.
【34】CAMPONE L, PICCINELLI A L, CELANO R, et al. Application of dispersive liquid-liquid microextraction for the determination of aflatoxins B1, B2, G1 and G2 in cereal products[J]. Journal of Chromatography A, 2011, 1218(42):7648-7654.
【35】王进, 魏丹丹, 王嵩, 等. 分散液液微萃取技术及其在食品和环境农药残留检测中的运用[J]. 现代食品, 2019(15):183-185.
【36】徐豪, 陈伟, 韩青, 等. 分散液液微萃取技术在农药残留分析中的应用概述[J]. 食品安全质量检测学报, 2020, 11(10):3221-3227.
【37】CUNHA S C, FERNANDES J O. Multipesticide residue analysis in maize combining acetonitrile-based extraction with dispersive liquid-liquid microextraction followed by gas chromatography-mass spectrometry[J]. Journal of Chromatography A, 2011, 1218(43):7748-7757.
【38】ZHANG L Y, YU R Z, YU Y B, et al. Determination of four acetanilide herbicides in brown rice juice by ionic liquid/ionic liquid-homogeneous liquid-liquid micro-extraction high performance liquid chromatography[J]. Microchemical Journal, 2019, 146:115-120.
【39】LU W D, LIU S J, WU Z L. Recent application of deep eutectic solvents as green solvent in dispersive liquid-liquid microextraction of trace level chemical contaminants in food and water[J]. Critical Reviews in Analytical Chemistry, 2020. DOI:doi.org/10.1080/10408347.2020.1808947.
【40】AHMAD W, AL-SIBAAI A A, BASHAMMAKH A S, et al. Recent advances in dispersive liquid-liquid microextraction for pesticide analysis[J]. TrAC Trends in Analytical Chemistry, 2015, 72:181-192.
【41】WU L J, LI Z C, ZHANG H Q, et al. Microwave absorption medium-assisted extraction coupled with reversed-phase dispersive liquid-liquid microextraction of triazine herbicides in corn and soybean samples[J]. Journal of Separation Science, 2020, 43(21):4058-4066.
【42】HERNÁNDEZ-HERNÁNDEZ A A, ÁLVAREZ-ROMERO G A, CONTRERAS-LÓPEZ E, et al. Food analysis by microextraction methods based on the use of magnetic nanoparticles as supports:Recent advances[J]. Food Analytical Methods, 2017, 10(9):2974-2993.
【43】ŠAFA ÍKOVÁ M, ŠAFA ÍK I. Magnetic solid-phase extraction[J]. Journal of Magnetism and Magnetic Materials, 1999, 194(1/2/3):108-112.
【44】LIU Z Z, QI P P, WANG X Y, et al. Multi-pesticides residue analysis of grains using modified magnetic nanoparticle adsorbent for facile and efficient cleanup[J]. Food Chemistry, 2017, 230:423-431.
【45】LI N, CHEN J, SHI Y P. Magnetic polyethyleneimine functionalized reduced graphene oxide as a novel magnetic solid-phase extraction adsorbent for the determination of polar acidic herbicides in rice[J]. Analytica Chimica Acta, 2017, 949:23-34.
【46】MACIEL E V S, TOFFOLI A L, LANÇAS F M. Recent trends in sorption-based sample preparation and liquid chromatography techniques for food analysis[J]. Electrophoresis, 2018, 39(13):1582-1596.
【47】HOU X D, TANG S, WANG J. Recent advances and applications of graphene-based extraction materials in food safety[J]. TrAC Trends in Analytical Chemistry, 2019, 119:115603.
【48】MOHD N I, GOPAL K, RAOOV M, et al. Evaluation of a magnetic activated charcoal modified with non-ionic silicone surfactant as a new magnetic solid phase extraction sorbent with triazine herbicides as model compounds in selected milk and rice samples[J]. Talanta, 2019, 196:217-225.
【49】WULFF G, SARHAN A, ZABROCKI K. Enzyme-analogue built polymers and their use for the resolution of racemates[J]. Tetrahedron Letters, 1973, 14(44):4329-4332.
【50】刘亚强, 王大伟.分子印迹原理及其聚合物的合成[J]. 渭南师范学院学报, 2004, 19(2):30-32.
【51】HU Y L, PAN J L, ZHANG K G, et al. Novel applications of molecularly-imprinted polymers in sample preparation[J]. TrAC Trends in Analytical Chemistry, 2013, 43:37-52.
【52】SUEDEE R, SRICHANA T, SAELIM J, et al. Chiral determination of various adrenergic drugs by thin-layer chromatography using molecularly imprinted chiral stationary phases prepared with alpha-agonists[J]. The Analyst, 1999, 124(7):1003-1009.
【53】DOWLATSHAH S, SARAJI M. A silica-based three-dimensional molecularly imprinted coating for the selective solid-phase microextraction of difenoconazole from wheat and fruits samples[J]. Analytica Chimica Acta, 2020, 1098:37-46.
【54】HUANG X C, MA J K, FENG R X, et al. Simultaneous determination of five organophosphorus pesticide residues in different food samples by solid-phase microextraction fibers coupled with high-performance liquid chromatography[J]. Journal of the Science of Food and Agriculture, 2019, 99(15):6998-7007.
【55】WANG S S, SHE Y X, HONG S H, et al. Dual-template imprinted polymers for class-selective solid-phase extraction of seventeen triazine herbicides and metabolites in agro-products[J]. Journal of Hazardous Materials, 2019, 367:686-693.
【56】ⅡJIMA S. Helical microtubules of graphitic carbon[J]. Nature, 1991, 354(6348):56-58.
【57】PYRZYNSKA K. Carbon nanotubes as sorbents in the analysis of pesticides[J]. Chemosphere, 2011, 83(11):1407-1413.
【58】QIN Z C, JIANG Y X, PIAO H L, et al. MIL-101(Cr)/MWCNTs-functionalized melamine sponges for solid-phase extraction of triazines from corn samples, and their subsequent determination by HPLC-MS/MS[J]. Talanta, 2020, 211:120676.
【59】TIAN J Y, XU J Q, ZHU F, et al. Application of nanomaterials in sample preparation[J]. Journal of Chromatography A, 2013, 1300:2-16.
【60】FRESCO-CALA B, CÁRDENAS S, VALCÁRCEL M. Improved microextraction of selected triazines using polymer monoliths modified with carboxylated multi-walled carbon nanotubes[J]. Microchimica Acta, 2016, 183(1):465-474.
【2】MOURTZINIS S, CONLEY S P, GASKA J M. Agronomic management and fungicide effects on oat yield and quality[J]. Crop Science, 2015, 55(3):1290-1294.
【3】SUN X, ZHAN F P, YU R Q, et al. Bio-accumulation of organic contaminants in Indo-Pacific humpback dolphins:Preliminary unique features of the brain and testes[J]. Environmental Pollution, 2020, 267:115511.
【4】FU D J, LI P, SONG J, et al. Mechanisms of synergistic neurotoxicity induced by two high risk pesticide residues - Chlorpyrifos and carbofuran via oxidative stress[J]. Toxicology in Vitro, 2019, 54:338-344.
【5】PAYNE-STURGES D, COHEN J, CASTORINA R, et al. Evaluating cumulative organophosphorus pesticide body burden of children:A national case study[J]. Environmental Science & Technology, 2009, 43(20):7924-7930.
【6】CHEN L, WANG D Z, ZHOU Z Q, et al. Comparing alpha-cypermethrin induced dose/gender-dependent responses of lizards in hepatotoxicity and nephrotoxicity in a food chain[J]. Chemosphere, 2020, 256:127069.
【7】GIUDICE L C. Environmental toxicants:Hidden players on the reproductive stage[J]. Fertility and Sterility, 2016, 106(4):791-794.
【8】MONTEMURRO M, BRASCA R, CULZONI M J, et al. High-performance organized media-enhanced spectrofluorimetric determination of pirimiphos-methyl in maize[J]. Food Chemistry, 2019, 278:711-719.
【9】KIM Y A, LEE E H, KIM K O, et al. Competitive immunochromatographic assay for the detection of the organophosphorus pesticide chlorpyrifos[J]. Analytica Chimica Acta, 2011, 693(1/2):106-113.
【10】MOHAMMADI P, GHORBANI M, MOHAMMADI P, et al. Dispersive micro solid-phase extraction with gas chromatography for determination of diazinon and ethion residues in biological, vegetables and cereal grain samples, employing D-optimal mixture design[J]. Microchemical Journal, 2021, 160:105680.
【11】DA SILVA L P, MADUREIRA F, DE AZEVEDO VARGAS E, et al. Development and validation of a multianalyte method for quantification of mycotoxins and pesticides in rice using a simple dilute and shoot procedure and UHPLC-MS/MS[J]. Food Chemistry, 2019, 270:420-427.
【12】FRANCESQUETT J Z, RIZZETTI T M, CADAVAL T R S JR, et al. Simultaneous determination of the quaternary ammonium pesticides paraquat, diquat, chlormequat, and mepiquat in barley and wheat using a modified quick polar pesticides method, diluted standard addition calibration and hydrophilic interaction liquid chromatography coupled to tandem mass spectrometry[J]. Journal of Chromatography A, 2019, 1592:101-111.
【13】孙聪.农残检测中基质效应的研究[J]. 现代农村科技, 2020(3):117-118.
【14】罗远洲.气液色谱法测定大米中六六六、DDT残留量的比较试验[J]. 粮食贮藏, 1982, 11(6):42-45.
【15】刘敏.毛细管色谱柱检测粮食中15种有机氯农药残留量[J]. 粮食与饲料工业, 2017(4):58-60.
【16】孟玲芝, 刘坤, 刘荣光, 等. 固相萃取技术在农药残留检测中的应用[J]. 吉林农业, 2018(12):55-55.
【17】PŁOTKA-WASYLKA J, SZCZEPAHSKA N, DE LA G M, et al. Modern trends in solid phase extraction:New sorbent media[J]. TrAC Trends in Analytical Chemistry, 2016, 77:23-43.
【18】林星辰, 余彬彬, 叶丹霞.固相萃取技术新发展及其在环境分析中的应用[J]. 化工时刊, 2014, 28(9):28-34.
【19】JI W H, DING H, GENG Y L, et al. Monodisperse cobalt(Ⅱ) based metal-organic coordination polymer beads as a sorbent for solid-phase extraction of chlorophenoxy acid herbicides prior to their quantitation by HPLC[J]. Microchimica Acta, 2019, 186(12):1-8.
【20】MICHEL M, GNUSOWSKI B, BUSZEWSKI B. Comparison of various extraction techniques to determine fungicide residue in wheat grain[J]. Journal of Liquid Chromatography & Related Technologies, 2006, 29(2):247-261.
【21】LAWAL A, WONG R C S, TAN G H, et al. Recent modifications and validation of QuEChERS-dSPE coupled to LC-MS and GC-MS instruments for determination of pesticide/agrochemical residues in fruits and vegetables:Review[J]. Journal of Chromatographic Science, 2018, 56(7):656-669.
【22】ANASTASSIADES M, LEHOTAY S J, ŠTAJNBAHER D, et al. Fast and easy multiresidue method employing acetonitrile extraction/partitioning and "dispersive solid-phase extraction" for the determination of pesticide residues in produce[J]. Journal of AOAC INTERNATIONAL, 2003, 86(2):412-431.
【23】PERESTRELO R, SILVA P, PORTO-FIGUEIRA P, et al. QuEChERS-Fundamentals, relevant improvements, applications and future trends[J]. Analytica Chimica Acta, 2019, 1070:1-28.
【24】MUSARURWA H, CHIMUKA L, PAKADE V E, et al. Recent developments and applications of QuEChERS based techniques on food samples during pesticide analysis[J]. Journal of Food Composition and Analysis, 2019, 84:103314.
【25】WILKOWSKA A, BIZIUK M. Determination of pesticide residues in food matrices using the QuEChERS methodology[J]. Food Chemistry, 2011, 125(3):803-812.
【26】WANG P, YANG X, WANG J, et al. Multi-residue method for determination of seven neonicotinoid insecticides in grains using dispersive solid-phase extraction and dispersive liquid-liquid micro-extraction by high performance liquid chromatography[J]. Food Chemistry, 2012, 134(3):1691-1698.
【27】HE Z Y, WANG L, PENG Y, et al. Multiresidue analysis of over 200 pesticides in cereals using a QuEChERS and gas chromatography-tandem mass spectrometry-based method[J]. Food Chemistry, 2015, 169:372-380.
【28】HERRMANN S S, POULSEN M E. Clean-up of cereal extracts for gas chromatography-tandem quadrupole mass spectrometry pesticide residues analysis using primary secondary amine and C18[J]. Journal of Chromatography A, 2015, 1423:47-53.
【29】NI Y X, YANG H, ZHANG H T, et al. Analysis of four sulfonylurea herbicides in cereals using modified quick, easy, cheap, effective, rugged, and safe sample preparation method coupled with liquid chromatography-tandem mass spectrometry[J]. Journal of Chromatography A, 2018, 1537:27-34.
【30】LEE Y J, RAHMAN M M, ABD EL-ATY A M, et al. Detection of three herbicide, and one metabolite, residues in brown rice and rice straw using various versions of the QuEChERS method and liquid chromatography-tandem mass spectrometry[J]. Food Chemistry, 2016, 210:442-450.
【31】LEHOTAY S J, COLLABORATORS, O'NEIL M, et al. Determination of pesticide residues in foods by acetonitrile extraction and partitioning with magnesium sulfate:Collaborative study[J]. Journal of AOAC INTERNATIONAL, 2007, 90(2):485-520.
【32】LU Z, FANG N, ZHANG Z B, et al. Residue analysis of fungicides fenpicoxamid, isofetamid, and mandestrobin in cereals using zirconium oxide disposable pipette extraction clean-up and ultrahigh-performance liquid chromatography-tandem mass spectrometry[J]. Journal of Chromatography A, 2020, 1620:461004.
【33】REZAEE M, ASSADI Y, MILANI H M R, et al. Determination of organic compounds in water using dispersive liquid-liquid microextraction[J]. Journal of Chromatography A, 2006, 1116(1/2):1-9.
【34】CAMPONE L, PICCINELLI A L, CELANO R, et al. Application of dispersive liquid-liquid microextraction for the determination of aflatoxins B1, B2, G1 and G2 in cereal products[J]. Journal of Chromatography A, 2011, 1218(42):7648-7654.
【35】王进, 魏丹丹, 王嵩, 等. 分散液液微萃取技术及其在食品和环境农药残留检测中的运用[J]. 现代食品, 2019(15):183-185.
【36】徐豪, 陈伟, 韩青, 等. 分散液液微萃取技术在农药残留分析中的应用概述[J]. 食品安全质量检测学报, 2020, 11(10):3221-3227.
【37】CUNHA S C, FERNANDES J O. Multipesticide residue analysis in maize combining acetonitrile-based extraction with dispersive liquid-liquid microextraction followed by gas chromatography-mass spectrometry[J]. Journal of Chromatography A, 2011, 1218(43):7748-7757.
【38】ZHANG L Y, YU R Z, YU Y B, et al. Determination of four acetanilide herbicides in brown rice juice by ionic liquid/ionic liquid-homogeneous liquid-liquid micro-extraction high performance liquid chromatography[J]. Microchemical Journal, 2019, 146:115-120.
【39】LU W D, LIU S J, WU Z L. Recent application of deep eutectic solvents as green solvent in dispersive liquid-liquid microextraction of trace level chemical contaminants in food and water[J]. Critical Reviews in Analytical Chemistry, 2020. DOI:doi.org/10.1080/10408347.2020.1808947.
【40】AHMAD W, AL-SIBAAI A A, BASHAMMAKH A S, et al. Recent advances in dispersive liquid-liquid microextraction for pesticide analysis[J]. TrAC Trends in Analytical Chemistry, 2015, 72:181-192.
【41】WU L J, LI Z C, ZHANG H Q, et al. Microwave absorption medium-assisted extraction coupled with reversed-phase dispersive liquid-liquid microextraction of triazine herbicides in corn and soybean samples[J]. Journal of Separation Science, 2020, 43(21):4058-4066.
【42】HERNÁNDEZ-HERNÁNDEZ A A, ÁLVAREZ-ROMERO G A, CONTRERAS-LÓPEZ E, et al. Food analysis by microextraction methods based on the use of magnetic nanoparticles as supports:Recent advances[J]. Food Analytical Methods, 2017, 10(9):2974-2993.
【43】ŠAFA ÍKOVÁ M, ŠAFA ÍK I. Magnetic solid-phase extraction[J]. Journal of Magnetism and Magnetic Materials, 1999, 194(1/2/3):108-112.
【44】LIU Z Z, QI P P, WANG X Y, et al. Multi-pesticides residue analysis of grains using modified magnetic nanoparticle adsorbent for facile and efficient cleanup[J]. Food Chemistry, 2017, 230:423-431.
【45】LI N, CHEN J, SHI Y P. Magnetic polyethyleneimine functionalized reduced graphene oxide as a novel magnetic solid-phase extraction adsorbent for the determination of polar acidic herbicides in rice[J]. Analytica Chimica Acta, 2017, 949:23-34.
【46】MACIEL E V S, TOFFOLI A L, LANÇAS F M. Recent trends in sorption-based sample preparation and liquid chromatography techniques for food analysis[J]. Electrophoresis, 2018, 39(13):1582-1596.
【47】HOU X D, TANG S, WANG J. Recent advances and applications of graphene-based extraction materials in food safety[J]. TrAC Trends in Analytical Chemistry, 2019, 119:115603.
【48】MOHD N I, GOPAL K, RAOOV M, et al. Evaluation of a magnetic activated charcoal modified with non-ionic silicone surfactant as a new magnetic solid phase extraction sorbent with triazine herbicides as model compounds in selected milk and rice samples[J]. Talanta, 2019, 196:217-225.
【49】WULFF G, SARHAN A, ZABROCKI K. Enzyme-analogue built polymers and their use for the resolution of racemates[J]. Tetrahedron Letters, 1973, 14(44):4329-4332.
【50】刘亚强, 王大伟.分子印迹原理及其聚合物的合成[J]. 渭南师范学院学报, 2004, 19(2):30-32.
【51】HU Y L, PAN J L, ZHANG K G, et al. Novel applications of molecularly-imprinted polymers in sample preparation[J]. TrAC Trends in Analytical Chemistry, 2013, 43:37-52.
【52】SUEDEE R, SRICHANA T, SAELIM J, et al. Chiral determination of various adrenergic drugs by thin-layer chromatography using molecularly imprinted chiral stationary phases prepared with alpha-agonists[J]. The Analyst, 1999, 124(7):1003-1009.
【53】DOWLATSHAH S, SARAJI M. A silica-based three-dimensional molecularly imprinted coating for the selective solid-phase microextraction of difenoconazole from wheat and fruits samples[J]. Analytica Chimica Acta, 2020, 1098:37-46.
【54】HUANG X C, MA J K, FENG R X, et al. Simultaneous determination of five organophosphorus pesticide residues in different food samples by solid-phase microextraction fibers coupled with high-performance liquid chromatography[J]. Journal of the Science of Food and Agriculture, 2019, 99(15):6998-7007.
【55】WANG S S, SHE Y X, HONG S H, et al. Dual-template imprinted polymers for class-selective solid-phase extraction of seventeen triazine herbicides and metabolites in agro-products[J]. Journal of Hazardous Materials, 2019, 367:686-693.
【56】ⅡJIMA S. Helical microtubules of graphitic carbon[J]. Nature, 1991, 354(6348):56-58.
【57】PYRZYNSKA K. Carbon nanotubes as sorbents in the analysis of pesticides[J]. Chemosphere, 2011, 83(11):1407-1413.
【58】QIN Z C, JIANG Y X, PIAO H L, et al. MIL-101(Cr)/MWCNTs-functionalized melamine sponges for solid-phase extraction of triazines from corn samples, and their subsequent determination by HPLC-MS/MS[J]. Talanta, 2020, 211:120676.
【59】TIAN J Y, XU J Q, ZHU F, et al. Application of nanomaterials in sample preparation[J]. Journal of Chromatography A, 2013, 1300:2-16.
【60】FRESCO-CALA B, CÁRDENAS S, VALCÁRCEL M. Improved microextraction of selected triazines using polymer monoliths modified with carboxylated multi-walled carbon nanotubes[J]. Microchimica Acta, 2016, 183(1):465-474.
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