Properties of Nano Graphite/Hydrogenated Nitrile Rubber Composite by Solution Blending Masterbatch Method
摘 要
采用溶液共混母胶法制备了纳米石墨/氢化丁腈橡胶(HNBR)复合材料,研究了其微观结构、硫化性能、力学性能、耐磨性能等,并将其与采用传统机械共混法制备得到的复合材料进行对比。结果表明:溶液共混母胶法可使纳米石墨更加均匀地分散在HNBR基体中;与传统机械共混法相比,用溶液共混母胶法制备的复合材料的硫化性能和力学性能更优,最大综合扭矩、弹性模量、交联程度、硫化速率分别提高了35%,44%,32%,46%,但该工艺对复合材料拉伸强度和耐磨性能的提高作用不明显。
Abstract
The nanographite composite/hydrogenated nitrile rubber (HNBR) was prepared by the solution blending masterbatch method, and the microstructure, vulcanization properties, mechanical properties, wear resistance were studied and compared with those of the composite prepared by the traditional mechanical blending method. The results show that the solution blending masterbatch method could make the nano graphite more uniformly disperse in the HNBR matrix. Compared with the composite by the traditional mechanical blending method, the composite prepared by the solution blending masterbatch method had better vulcanization and mechanical properties; the maximum comprehensive torque, elastic modulus, crosslinking degree, vulcanization speed increased by 35%, 44%, 32%, 46%, respectively, but the effect of the process on the improvement of tensile strength and wear resistance of the composites was not obvious.
中图分类号 TB332 DOI 10.11973/jxgccl202109012
所属栏目 材料性能及应用
基金项目 国家自然科学基金资助项目(51605316);四川省科技计划资助项目(2018GZ0523);中国博士后科学基金资助项目(2018T110971,2017M623027)
收稿日期 2020/8/24
修改稿日期 2021/7/21
网络出版日期
作者单位点击查看
备注吴克鹏(1994-),男,四川广元人,硕士研究生
引用该论文: WU Kepeng,WEN Bocheng,ZHOU Guangwu. Properties of Nano Graphite/Hydrogenated Nitrile Rubber Composite by Solution Blending Masterbatch Method[J]. Materials for mechancial engineering, 2021, 45(9): 62~66
吴克鹏,文薄程,周广武. 溶液共混母胶法制备纳米石墨/氢化丁腈橡胶复合材料的性能[J]. 机械工程材料, 2021, 45(9): 62~66
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参考文献
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【3】GU Z, ZHANG X, BAO C, et al.Simultaneous enhancement and percolation behaviors of damping and mechanical properties of ethylene-propylene-diene rubber by introducing phase-change organic acid[J].Journal of Non-Crystalline Solids, 2014, 388:17-22.
【4】张琦, 田明, 吴友平, 等.纳米氢氧化镁/橡胶复合材料的分散特性及分散机理[J].复合材料学报, 2003(4):88-95. ZHANG Q, TIAN M, WU Y P, et al. Dispersion structure and mechanism of the nano-magnesium hydroxide/rubber composites[J].Acta Materiae Compositae Sinica, 2003(4):88-95.
【5】周湘文, 王敬东, 朱跃峰, 等.添加碳纳米管丁苯粉末橡胶的制备[J].炭素技术, 2005(3):4-8. ZHOU X W, WANG J D, ZHU Y F, et al. The preparation of carbon nanotubes/powder styree-butadiene rubber composites[J].Carbon Techniques, 2005(3):4-8.
【6】贾承赟, 周新聪, 王超, 等.丁腈橡胶/碳纳米管复合轴承材料摩擦磨损性能研究[J].中国修船, 2019, 32(5):37-41. JIA C Y, ZHOU X C, WANG C, et al.Study on friction and wear properties of nitrile butadiene rabber/multi-walled carbon nanotube bearing materials[J].China Shiprepair, 2019, 32(5):37-41.
【7】陈永军, 邹华, 伍社毛, 等.丁腈橡胶复合材料的制备与性能[J].机械工程材料, 2017, 41(9):61-67. CHEN Y J, ZOU H, WU S M, et al.Preparation and properties of nitrile rubber composite[J].Materials for Mechanical Engineering, 2017, 41(9):61-67.
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【9】高利, 宋国君, 李培耀, 等. 有机蒙脱土对橡胶硫化特性的影响及其理论分析[J]. 石油化工, 2009(9):1004-1008. GAO L, SONG G J, LI P Y, et al. Effect of organomontmorillonite on curing characteristics of rubber[J].Petrochemical Technology, 2009(9):1004-1008.
【10】DAS A, COSTA F R, WAGENKNECHT U, et al.Nanocomposites based on chloroprene rubber:Effect of chemical nature and organic modification of nanoclay on the vulcanizate properties[J].European Polymer Journal, 2008, 44(11):3456-3465.
【11】吴祖旻, 盛晨兴, 郭智威, 等.船舶水润滑尾轴承当量半径等效计算及其摩擦学性能研究[J].摩擦学学报, 2017, 37(5):656-662. WU Z M, SHENG C X, GUO Z W, et al.Equivalent calculate of the equivalent radius and the tribological performance of the marine water-lubricated bearing[J].Tribology, 2017, 37(5):656-662.
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【15】KIM W, YU E, RYU G, et al.Silica dispersion and properties of silica filled ESBR/BR/NR ternary blend composites by applying wet masterbatch technology[J].Polymer Testing, 2020, 84:106350.
【16】杨凤艳, 王世杰, 吕晓仁, 等.不同工况下丁腈橡胶的摩擦磨损机理[J].沈阳工业大学学报, 2014, 36(3):291-296. YANG F Y, WANG S J, LV X R, et al.Friction and wear mechanism of NBR under different operating conditions[J].Journal of Shenyang University of Technology, 2014, 36(3):291-296.
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