Effect of Material Property on Bidirectional Electro-migration Rehabilitation with Hexane Diamine Inhibitor
摘 要
海洋环境中混凝土结构易受氯盐侵蚀发生钢筋锈蚀,引发海工构件耐久性问题。双向电渗修复技术在去除混凝土中氯离子的同时可在钢筋表面形成阻锈剂钝化膜,是一种良好的结构延寿技术。采用1,6-己二胺为阻锈剂,在通电电流3 A/m2,通电时间9 d条件下,对氯盐侵蚀钢筋混凝土构件进行修复,研究了混凝土强度及保护层厚度对双向电渗修复效果的影响规律。结果表明:双向电渗有效提升了混凝土中钢筋的耐久性;混凝土中氯离子去除率、阻锈剂迁移量及钢筋耐蚀性随混凝土强度增加而降低。
Abstract
Concrete structures in marine environment were susceptible to corrosion by chloride salts, causing corrosion of steel bars, and causing durability problems for offshore structures. The two-way electroosmosis repair technology could form a rust inhibitor passive film on the surface of steel bar while removing the chloride ions in the concrete, which was a good structure life extension technology. Using 1,6-hexamethylene diamine as rust inhibitor, under the condition of energizing current of 3 A/m2 and energizing time of 9 d, the chloride salt corroded reinforced concrete members were repaired. The influence of concrete strength and protective layer thickness on the effect of the two-way electroosmosis repair was studied. The results showed that the two-way electroosmosis effectively improved the durability of the steel bars in the concrete; the chloride ion removal rate, the migration amount of rust inhibitors and the corrosion resistance of the steel bars in the concrete decreased with the increase of the concrete strength.
中图分类号 TU375 DOI 10.11973/fsyfh-202110009
所属栏目 试验研究
基金项目 国家自然科学基金(21576300);中国交通建设集团科技研发项目(2017-ZJKJ-PTJS04)
收稿日期 2020/3/19
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引用该论文: ZHANG Dongfang,FANG Xiang,FAN Zhihong,XIONG Jianbo,WANG Shengnian,WANG Yi. Effect of Material Property on Bidirectional Electro-migration Rehabilitation with Hexane Diamine Inhibitor[J]. Corrosion & Protection, 2021, 42(10): 43
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参考文献
【1】VASHI R T, KADIYA H K. Corrosion study of metals in marine environment[J]. E-Journal of Chemistry, 2009, 6(4):1240-1246.
【2】孙红尧, 傅宇方, 陆采荣, 等. 处于盐渍土和盐湖环境下建筑物的腐蚀与防护现状[J]. 腐蚀与防护, 2012, 33(8):652-656, 663.
【3】KUBO J, TANAKA Y, PAGE C L, et al. Application of electrochemical organic corrosion inhibitor injection to a carbonated reinforced concrete railway viaduct[J]. Construction and Building Materials, 2013, 39:2-8.
【4】金伟良, 黄楠, 许晨, 等. 双向电渗对钢筋混凝土修复效果的试验研究——保护层阻锈剂、氯离子和总碱度的变化规律[J]. 浙江大学学报(工学版), 2014, 48(9):1586-1594, 1609.
【5】XU C, JIN W L, WANG H L, et al. Organic corrosion inhibitor of triethylenetetramine into chloride contamination concrete by eletro-injection method[J]. Construction and Building Materials, 2016, 115:602-617.
【6】毛江鸿, 金伟良, 李志远, 等. 氯盐侵蚀钢筋混凝土桥梁耐久性提升及寿命预测[J]. 中国公路学报, 2016, 29(1):61-66.
【7】KARTHICK S P, MADHAVAMAYANDI A, MURALIDHARAN S, et al. Electrochemical process to improve the durability of concrete structures[J]. Journal of Building Engineering, 2016, 7:273-280.
【8】张东方, 方翔, 李佳蒙, 等. 双向电渗对钢筋混凝土耐久性提升效果研究[C]//第五届海洋材料与腐蚀防护大会暨海洋新材料及防护新技术展览会论文集.[出版地不详]:[出版者不详], 2018.
【9】郭柱, 金骏, 朱育军, 等. 材料特性对三乙烯四胺双向电渗技术短期效果试验研究[J]. 混凝土, 2017(1):71-75.
【10】章思颖. 应用于双向电渗技术的电迁移型阻锈剂的筛选[D]. 杭州:浙江大学, 2012.
【2】孙红尧, 傅宇方, 陆采荣, 等. 处于盐渍土和盐湖环境下建筑物的腐蚀与防护现状[J]. 腐蚀与防护, 2012, 33(8):652-656, 663.
【3】KUBO J, TANAKA Y, PAGE C L, et al. Application of electrochemical organic corrosion inhibitor injection to a carbonated reinforced concrete railway viaduct[J]. Construction and Building Materials, 2013, 39:2-8.
【4】金伟良, 黄楠, 许晨, 等. 双向电渗对钢筋混凝土修复效果的试验研究——保护层阻锈剂、氯离子和总碱度的变化规律[J]. 浙江大学学报(工学版), 2014, 48(9):1586-1594, 1609.
【5】XU C, JIN W L, WANG H L, et al. Organic corrosion inhibitor of triethylenetetramine into chloride contamination concrete by eletro-injection method[J]. Construction and Building Materials, 2016, 115:602-617.
【6】毛江鸿, 金伟良, 李志远, 等. 氯盐侵蚀钢筋混凝土桥梁耐久性提升及寿命预测[J]. 中国公路学报, 2016, 29(1):61-66.
【7】KARTHICK S P, MADHAVAMAYANDI A, MURALIDHARAN S, et al. Electrochemical process to improve the durability of concrete structures[J]. Journal of Building Engineering, 2016, 7:273-280.
【8】张东方, 方翔, 李佳蒙, 等. 双向电渗对钢筋混凝土耐久性提升效果研究[C]//第五届海洋材料与腐蚀防护大会暨海洋新材料及防护新技术展览会论文集.[出版地不详]:[出版者不详], 2018.
【9】郭柱, 金骏, 朱育军, 等. 材料特性对三乙烯四胺双向电渗技术短期效果试验研究[J]. 混凝土, 2017(1):71-75.
【10】章思颖. 应用于双向电渗技术的电迁移型阻锈剂的筛选[D]. 杭州:浙江大学, 2012.
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