水体中氯酚类化合物测定方法的研究进展
Research Progress on Determination Methods of Chlorophenols in Water
摘 要
综述了近年来分光光度法、色谱法及质谱法、毛细管电泳法等主要分析方法检测水体中氯酚类化合物的进展，并对水体中氯酚类化合物的测定方法的发展趋势进行展望（引用文献50篇）。
测定方法
水体
研究进展
chlorophenol
determination method
water
research progress
Abstract
The progress on the determination of chlorophenols in water by spectrophotometry, chromatography, mass spectrometry and capillary electrophoresis in recent years was reviewed, and the determination methods of chlorophenols in water were prospected (50 ref. cited).
中图分类号 O65 DOI 10.11973/lhjy-hx202112017
所属栏目 综述
基金项目 江苏省卫生计生委科研课题（Y2018080）
收稿日期 2020/10/28
修改稿日期
网络出版日期
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备注付正伟,硕士研究生,研究方向为水环境中污染物的吸附行为
引用该论文: FU Zhengwei,HUO Zongli,YANG Hong. Research Progress on Determination Methods of Chlorophenols in Water[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2021, 57(12): 1142～1148
付正伟,霍宗利,杨红. 水体中氯酚类化合物测定方法的研究进展[J]. 理化检验－化学分册, 2021, 57(12): 1142～1148
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参考文献
【1】SINGH A K, CHANDRA R. Pollutants released from the pulp paper industry:Aquatic toxicity and their health hazards[J]. Aquatic Toxicology, 2019,211:202-216.
【2】MARTINEZ M, BAEZA J, FREER J, et al. Chlorophenol tolerant and degradative bacteria isolated from a river receiving pulp mill discharges[J]. Toxicological & Environmental Chemistry, 2000,77(3/4):159-170.
【3】黄轶昕.我国灭螺药物研究和现场应用[J].中国血吸虫病防治杂志, 2019,31(6):679-684.
【4】徐明.长江中下游湖泊中氯酚化合物的沉积记录和来源解析[D].合肥:合肥工业大学, 2018.
【5】毕薇薇,叶胜,于建全,等.长距离供水系统中消毒副产物分布特征及二次加氯的影响[J].环境科学, 2020,41(7):3297-3306.
【6】金梨娟.氯过氧化物酶催化形成天然卤代有机物的过程探究[D].杭州:浙江大学, 2018.
【7】GAO J J, LIU L H, LIU X R, et al. Levels and spatial distribution of chlorophenols-2,4-dichlorophenol, 2,4,6-trichlorophenol, and pentachlorophenol in surface water of China[J]. Chemosphere, 2008,71(6):1181-1187.
【8】甄一尘.新型管式磁膜光催化反应体系对氯酚废水的降解效果与机制研究[D].保定:河北大学, 2020.
【9】POLLACK A Z, MUMFORD S L, KRALL J R, et al. Urinary levels of environmental phenols and parabens and antioxidant enzyme activity in the blood of women[J]. Environmental Research, 2020,186:109507.
【10】黄晓敏.孕期五氯酚暴露在早期自发性流产发生中的作用及其机制研究[D].南京:南京医科大学, 2018.
【11】MA Y B, LIU C S, LAM P K S, et al. Modulation of steroidogenic gene expression and hormone synthesis in H295R cells exposed to PCP and TCP[J]. Toxicology, 2011,282(3):146-153.
【12】马幼骐.一种简易的分光光度法测定水中的五氯酚[J].广东卫生防疫资料, 1985,11(1):137-139.
【13】李永波,陈敏芳.分光光度法测定皮革手套中微量五氯酚[J].中国皮革, 1991,20(2):46-46.
【14】刘志明.4-氨基安替吡啉分光光度法测定饮用水中挥发酚的改进[J].中国卫生检验杂志, 2019,29(14):1683-1685.
【15】TABARAKI R, HEIDARIZADI E. Spectrophotometric determination of phenol and chlorophenols by salting out assisted liquid-liquid extraction combined with dispersive liquid-liquid microextraction[J]. Spectrochimica Acta Part A:Molecular and Biomolecular Spectroscopy, 2019,215:405-409.
【16】李晓霞.碳点分子印迹复合材料荧光传感器检测2,3,4,6-四氯酚的研究[D].天津:天津科技大学, 2018.
【17】陈艳芳,张锦宏.流动注射仪测定水中挥发酚的探讨[J].中国卫生检验杂志, 2019,29(5):539-541.
【18】杨利娴.流动注射分析法测定挥发酚考核样探讨[J].广东化工, 2019,46(21):129-130.
【19】YUAN S F, LIU Z H, LIAN H X, et al. Simultaneous determination of eleven estrogenic and odorous chloro- and bromo-phenolic compounds in surface water through an automated online headspace SPME followed by on-fiber derivatization coupled with GC-MS[J]. Analytical Methods, 2017,9(33):4819-4827.
【20】谭晓燕,黎国兰,李松,等.水中痕量苯酚的微波萃取气相色谱分析[J].化学研究与应用, 2009,21(7):1067-1069.
【21】张鸣珊,李腾崖,曹小聪,等.液液萃取-气相色谱对水体中21种酚类化合物的测定[C]//《环境工程》2019年全国学术年会论文集.北京:[出版者不详], 2019:132-136.
【22】崔君,顾华,张强.改进的五氟苄基溴衍生化反应测定水中酚类化合物[J].分析试验室, 2021,40(1):54-58.
【23】TOBISZEWSKI M, ZABROCKA W, BYSTRZANOWSKA M. Diethyl carbonate as a green extraction solvent for chlorophenol determination with dispersive liquid-liquid microextraction[J]. Analytical Methods, 2019,11(6):844-850.
【24】JAIN A, SONI S, REDDY-NOONE K, et al. Combined headspace single-drop microextraction and solid-phase microextraction for the determination of phenols as their methyl ethers by gas chromatography-mass spectrometry[J]. Analytical Methods, 2017,9(46):6590-6598.
【25】HONG J J, HAO X T, LIU T T, et al. Rapid synergistic cloud point extraction (RS-CPE) with partial least squares (PLS) for the simultaneous determination of chlorophenols (CPs) in environmental water samples using a microplate assay (MPA)[J]. Analytical Letters, 2020,53(11):1719-1733.
【26】张权,殷忠.顶空固相微萃取-气相色谱法测定生活饮用水中的氯酚化合物[J].微量元素与健康研究, 2020,37(2):64-66.
【27】王孝生,卢嘉,孙军勇.硫酸二甲酯衍生化-顶空气相色谱法测定环境水样中3种氯酚[J].环境保护与循环经济, 2020,40(9):60-64.
【28】LIU B, HAO Y Q, WANG L X, et al. Ordered mesoporous carbon in solid-phase microextraction for analysis of volatile organic compounds in water samples[J]. Analytical Methods, 2019,11(29):3741-3749.
【29】MENG W K, LIU L, WANG X, et al. Polyphenylene core-conjugated microporous polymer coating for highly sensitive solid-phase microextraction of polar phenol compounds in water samples[J]. Analytica Chimica Acta, 2018,1015:27-34.
【30】ESRAFILI A, GHAMBARIAN M, TAJIK M, et al. Spin-column micro-solid phase extraction of chlorophenols using MFU-4l metal-organic framework[J]. Microchimica Acta, 2019,187(1):1-9.
【31】HASHEMI-MOGHADDAM H, HOSSENI M, MOHAMMADHOSSEINI M. Preparation of molecularly imprinted polymers on the surface of optical fiber for HS-solid-phase microextraction of phenol[J]. Separation Science and Technology, 2017,52(11):1826-1834.
【32】POKRYSHKIN S A, KOSYAKOV D S, KOZHEVNIKOV A Y, et al. Highly sensitive determination of chlorophenols in sea water by gas chromatography-tandem mass spectrometry[J]. Journal of Analytical Chemistry, 2018,73(10):991-998.
【33】LI L, HUANG L J, SUN S T, et al. An amino-functionalized ordered mesoporous polymer as a fiber coating for solid phase microextraction of phenols prior to GC-MS analysis[J]. Microchimica Acta, 2019,186(9):1-8.
【34】TAFAZOLI Z, AZAR P A, TEHRANI M S, et al. Facile preparation of multifunctional carbon nanotube/magnetite/polyaniline nanocomposite offering a strong option for efficient solid-phase microextraction coupled with GC-MS for the analysis of phenolic compounds[J]. Journal of Separation Science, 2018,41(13):2736-2742.
【35】欧天成,郭艳芬,陈少芳,等.高效液相色谱法同时测定水中挥发性酚(以苯酚计)、2,4,6-三氯酚、五氯酚[J].中国卫生工程学, 2018,17(1):55-57.
【36】郑晓峰,李鹏鹏,张晓霞,等.液液萃取-液相色谱法测定饮用水中的2,4,6-三氯酚和五氯酚[J].城镇供水, 2019(2):27-29.
【37】韩宝武,李敏,蔡依莎.高效液相色谱法测定3种氯酚类化合物[J].绿色科技, 2016(16):119-121.
【38】王珂,蔡海芸.固相萃取高效液相色谱法测定水中三种氯酚物质[J].净水技术, 2016,35(增刊1):104-105.
【39】陈建华,彭刚华,乔支卫,等.固相萃取-超高效液相色谱法检测地表水中7种氯酚类化合物[J].中国环境监测, 2015,31(3):144-149.
【40】黄喜寿,叶凡,唐丽,等.高效液相色谱法检测废水中酚类化合物研究[J].环境科学与管理, 2018,43(11):98-101.
【41】冷俊,夏青,汤洁.固相萃取-高效液相色谱法测定水中氯酚类化合物[J].环境监控与预警, 2016,8(2):20-22.
【42】CHONG Y T, MOHD A M, MOHD T N, et al. A green solvent holder in electro-mediated microextraction for the extraction of phenols in water[J]. Talanta, 2018,176:558-564.
【43】SEEBUNRUENG K, DEJCHAIWATANA C, SANTALADCHAIYAKIT Y, et al. Development of supramolecular solvent based microextraction prior to high performance liquid chromatography for simultaneous determination of phenols in environmental water[J]. RSC Adv, 2017,7(79):50143-50149.
【44】陈晓红,闵剑青,王倩,等.两亲性聚离子液体膜微萃取-液相色谱-串联质谱法测定水中5种氯酚[J].理化检验-化学分册, 2017,53(11):1276-1280.
【45】CAI M Q, SU J, HU J Q, et al. Planar graphene oxide-based magnetic ionic liquid nanomaterial for extraction of chlorophenols from environmental water samples coupled with liquid chromatography-tandem mass spectrometry[J]. Journal of Chromatography A, 2016,1459:38-46.
【46】庄立,闵剑青,陈晓红,等.超声辅助固相微萃取-超快速液相色谱串联质谱法测定尿液中五氯酚[J].中国卫生检验杂志, 2017,27(22):3209-3211.
【47】WU D B, XIONG Y H, HE M H, et al. Determination of phenol degradation in chloride ion rich water by ferrate using a chromatographic method in combination with on-line mass spectrometry analysis[J]. Analytical Methods, 2019,11(36):4651-4658.
【48】MA S Y, GAO F F, LU W H, et al. Dispersive liquid-liquid microextraction coupled with pressure-assisted electrokinetic injection for simultaneous enrichment of seven phenolic compounds in water samples followed by determination using capillary electrophoresis[J]. Journal of Separation Science, 2019,42(13):2263-2271.
【49】GAO F F, CHEN X X, LI X B, et al. Field-amplified sample injection combined with capillary electrophoresis for the simultaneous determination of five chlorophenols in water samples[J]. Electrophoresis, 2019,40(14):1771-1778.
【2】MARTINEZ M, BAEZA J, FREER J, et al. Chlorophenol tolerant and degradative bacteria isolated from a river receiving pulp mill discharges[J]. Toxicological & Environmental Chemistry, 2000,77(3/4):159-170.
【3】黄轶昕.我国灭螺药物研究和现场应用[J].中国血吸虫病防治杂志, 2019,31(6):679-684.
【4】徐明.长江中下游湖泊中氯酚化合物的沉积记录和来源解析[D].合肥:合肥工业大学, 2018.
【5】毕薇薇,叶胜,于建全,等.长距离供水系统中消毒副产物分布特征及二次加氯的影响[J].环境科学, 2020,41(7):3297-3306.
【6】金梨娟.氯过氧化物酶催化形成天然卤代有机物的过程探究[D].杭州:浙江大学, 2018.
【7】GAO J J, LIU L H, LIU X R, et al. Levels and spatial distribution of chlorophenols-2,4-dichlorophenol, 2,4,6-trichlorophenol, and pentachlorophenol in surface water of China[J]. Chemosphere, 2008,71(6):1181-1187.
【8】甄一尘.新型管式磁膜光催化反应体系对氯酚废水的降解效果与机制研究[D].保定:河北大学, 2020.
【9】POLLACK A Z, MUMFORD S L, KRALL J R, et al. Urinary levels of environmental phenols and parabens and antioxidant enzyme activity in the blood of women[J]. Environmental Research, 2020,186:109507.
【10】黄晓敏.孕期五氯酚暴露在早期自发性流产发生中的作用及其机制研究[D].南京:南京医科大学, 2018.
【11】MA Y B, LIU C S, LAM P K S, et al. Modulation of steroidogenic gene expression and hormone synthesis in H295R cells exposed to PCP and TCP[J]. Toxicology, 2011,282(3):146-153.
【12】马幼骐.一种简易的分光光度法测定水中的五氯酚[J].广东卫生防疫资料, 1985,11(1):137-139.
【13】李永波,陈敏芳.分光光度法测定皮革手套中微量五氯酚[J].中国皮革, 1991,20(2):46-46.
【14】刘志明.4-氨基安替吡啉分光光度法测定饮用水中挥发酚的改进[J].中国卫生检验杂志, 2019,29(14):1683-1685.
【15】TABARAKI R, HEIDARIZADI E. Spectrophotometric determination of phenol and chlorophenols by salting out assisted liquid-liquid extraction combined with dispersive liquid-liquid microextraction[J]. Spectrochimica Acta Part A:Molecular and Biomolecular Spectroscopy, 2019,215:405-409.
【16】李晓霞.碳点分子印迹复合材料荧光传感器检测2,3,4,6-四氯酚的研究[D].天津:天津科技大学, 2018.
【17】陈艳芳,张锦宏.流动注射仪测定水中挥发酚的探讨[J].中国卫生检验杂志, 2019,29(5):539-541.
【18】杨利娴.流动注射分析法测定挥发酚考核样探讨[J].广东化工, 2019,46(21):129-130.
【19】YUAN S F, LIU Z H, LIAN H X, et al. Simultaneous determination of eleven estrogenic and odorous chloro- and bromo-phenolic compounds in surface water through an automated online headspace SPME followed by on-fiber derivatization coupled with GC-MS[J]. Analytical Methods, 2017,9(33):4819-4827.
【20】谭晓燕,黎国兰,李松,等.水中痕量苯酚的微波萃取气相色谱分析[J].化学研究与应用, 2009,21(7):1067-1069.
【21】张鸣珊,李腾崖,曹小聪,等.液液萃取-气相色谱对水体中21种酚类化合物的测定[C]//《环境工程》2019年全国学术年会论文集.北京:[出版者不详], 2019:132-136.
【22】崔君,顾华,张强.改进的五氟苄基溴衍生化反应测定水中酚类化合物[J].分析试验室, 2021,40(1):54-58.
【23】TOBISZEWSKI M, ZABROCKA W, BYSTRZANOWSKA M. Diethyl carbonate as a green extraction solvent for chlorophenol determination with dispersive liquid-liquid microextraction[J]. Analytical Methods, 2019,11(6):844-850.
【24】JAIN A, SONI S, REDDY-NOONE K, et al. Combined headspace single-drop microextraction and solid-phase microextraction for the determination of phenols as their methyl ethers by gas chromatography-mass spectrometry[J]. Analytical Methods, 2017,9(46):6590-6598.
【25】HONG J J, HAO X T, LIU T T, et al. Rapid synergistic cloud point extraction (RS-CPE) with partial least squares (PLS) for the simultaneous determination of chlorophenols (CPs) in environmental water samples using a microplate assay (MPA)[J]. Analytical Letters, 2020,53(11):1719-1733.
【26】张权,殷忠.顶空固相微萃取-气相色谱法测定生活饮用水中的氯酚化合物[J].微量元素与健康研究, 2020,37(2):64-66.
【27】王孝生,卢嘉,孙军勇.硫酸二甲酯衍生化-顶空气相色谱法测定环境水样中3种氯酚[J].环境保护与循环经济, 2020,40(9):60-64.
【28】LIU B, HAO Y Q, WANG L X, et al. Ordered mesoporous carbon in solid-phase microextraction for analysis of volatile organic compounds in water samples[J]. Analytical Methods, 2019,11(29):3741-3749.
【29】MENG W K, LIU L, WANG X, et al. Polyphenylene core-conjugated microporous polymer coating for highly sensitive solid-phase microextraction of polar phenol compounds in water samples[J]. Analytica Chimica Acta, 2018,1015:27-34.
【30】ESRAFILI A, GHAMBARIAN M, TAJIK M, et al. Spin-column micro-solid phase extraction of chlorophenols using MFU-4l metal-organic framework[J]. Microchimica Acta, 2019,187(1):1-9.
【31】HASHEMI-MOGHADDAM H, HOSSENI M, MOHAMMADHOSSEINI M. Preparation of molecularly imprinted polymers on the surface of optical fiber for HS-solid-phase microextraction of phenol[J]. Separation Science and Technology, 2017,52(11):1826-1834.
【32】POKRYSHKIN S A, KOSYAKOV D S, KOZHEVNIKOV A Y, et al. Highly sensitive determination of chlorophenols in sea water by gas chromatography-tandem mass spectrometry[J]. Journal of Analytical Chemistry, 2018,73(10):991-998.
【33】LI L, HUANG L J, SUN S T, et al. An amino-functionalized ordered mesoporous polymer as a fiber coating for solid phase microextraction of phenols prior to GC-MS analysis[J]. Microchimica Acta, 2019,186(9):1-8.
【34】TAFAZOLI Z, AZAR P A, TEHRANI M S, et al. Facile preparation of multifunctional carbon nanotube/magnetite/polyaniline nanocomposite offering a strong option for efficient solid-phase microextraction coupled with GC-MS for the analysis of phenolic compounds[J]. Journal of Separation Science, 2018,41(13):2736-2742.
【35】欧天成,郭艳芬,陈少芳,等.高效液相色谱法同时测定水中挥发性酚(以苯酚计)、2,4,6-三氯酚、五氯酚[J].中国卫生工程学, 2018,17(1):55-57.
【36】郑晓峰,李鹏鹏,张晓霞,等.液液萃取-液相色谱法测定饮用水中的2,4,6-三氯酚和五氯酚[J].城镇供水, 2019(2):27-29.
【37】韩宝武,李敏,蔡依莎.高效液相色谱法测定3种氯酚类化合物[J].绿色科技, 2016(16):119-121.
【38】王珂,蔡海芸.固相萃取高效液相色谱法测定水中三种氯酚物质[J].净水技术, 2016,35(增刊1):104-105.
【39】陈建华,彭刚华,乔支卫,等.固相萃取-超高效液相色谱法检测地表水中7种氯酚类化合物[J].中国环境监测, 2015,31(3):144-149.
【40】黄喜寿,叶凡,唐丽,等.高效液相色谱法检测废水中酚类化合物研究[J].环境科学与管理, 2018,43(11):98-101.
【41】冷俊,夏青,汤洁.固相萃取-高效液相色谱法测定水中氯酚类化合物[J].环境监控与预警, 2016,8(2):20-22.
【42】CHONG Y T, MOHD A M, MOHD T N, et al. A green solvent holder in electro-mediated microextraction for the extraction of phenols in water[J]. Talanta, 2018,176:558-564.
【43】SEEBUNRUENG K, DEJCHAIWATANA C, SANTALADCHAIYAKIT Y, et al. Development of supramolecular solvent based microextraction prior to high performance liquid chromatography for simultaneous determination of phenols in environmental water[J]. RSC Adv, 2017,7(79):50143-50149.
【44】陈晓红,闵剑青,王倩,等.两亲性聚离子液体膜微萃取-液相色谱-串联质谱法测定水中5种氯酚[J].理化检验-化学分册, 2017,53(11):1276-1280.
【45】CAI M Q, SU J, HU J Q, et al. Planar graphene oxide-based magnetic ionic liquid nanomaterial for extraction of chlorophenols from environmental water samples coupled with liquid chromatography-tandem mass spectrometry[J]. Journal of Chromatography A, 2016,1459:38-46.
【46】庄立,闵剑青,陈晓红,等.超声辅助固相微萃取-超快速液相色谱串联质谱法测定尿液中五氯酚[J].中国卫生检验杂志, 2017,27(22):3209-3211.
【47】WU D B, XIONG Y H, HE M H, et al. Determination of phenol degradation in chloride ion rich water by ferrate using a chromatographic method in combination with on-line mass spectrometry analysis[J]. Analytical Methods, 2019,11(36):4651-4658.
【48】MA S Y, GAO F F, LU W H, et al. Dispersive liquid-liquid microextraction coupled with pressure-assisted electrokinetic injection for simultaneous enrichment of seven phenolic compounds in water samples followed by determination using capillary electrophoresis[J]. Journal of Separation Science, 2019,42(13):2263-2271.
【49】GAO F F, CHEN X X, LI X B, et al. Field-amplified sample injection combined with capillary electrophoresis for the simultaneous determination of five chlorophenols in water samples[J]. Electrophoresis, 2019,40(14):1771-1778.
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