搜索热:失效分析 陶瓷
扫一扫 加微信
首页 > 期刊论文 > 论文摘要
固溶时效处理过程中Mg-Ce合金中稀土相的分布变化规律
          
Distribution Variation of Rare Earth Phase in Mg-Ce AlloyDuring Solution and Aging Treatment

摘    要
以纯镁和Mg-30Ce中间合金为原料铸造铈质量分数为1%的Mg-Ce合金,并进行420 ℃×8 h固溶和200 ℃×20 h时效处理,研究了不同状态时合金中稀土相分布的变化规律。结果表明:铸态、固溶态和时效态合金中的稀土相均为Mg12Ce;铸态合金中的稀土析出相分布不均匀,以晶界处析出为主,晶粒内析出为辅,且析出相尺寸、形貌差异较大;固溶处理后,稀土相大多溶解于镁基体,但晶界处和部分晶粒内仍有一定量残余;时效处理后稀土相在晶粒内重新均匀、弥散析出,晶界处析出量较少,与铸态合金相比,析出相尺寸更加细小、分布更加均匀。
标    签 铈元素   镁稀土合金   稀土相   固溶时效处理   Ce element   magnesium-rare earth alloy   rare earth phrase   solution and aging treatment  
 
Abstract
With pure magnesium and Mg-30Ce master alloy as raw materials, the Mg-Ce alloy with 1wt% Ce was prepared by casting, and treated by solution at 420 ℃ for 8 h and aging at 200 ℃ for 20 h. The change of rare earth phase distribution in the alloy in different states was studied. The results show that the rare earth phases of the as-cast, solution-treated and aging-treated alloy were all Mg12Ce. The distribution of rare earth precipitation phases in the as-cast alloy was uneven, which was dominated by boundary precipitation and supplemented by in-grain precipitation, and the size and morphology of the precipitation phase were quite different. After solution treatment, most of the precipitated rare earth phase was soluted in the magnesium matrix, but there were still a certain number of rare earth phases at grain boundaries and in part of grains. After the aging treatment, the rare earth phase uniformly dispersed in grains, and the amount of precipitation at grain boundaries was smaller. Compared with the as-cast sample, the precipitated phase after aging was smaller in size and distributed more uniformly.

中图分类号 TG456   DOI 10.11973/jxgccl202201009

 
  中国光学期刊网论文下载说明


所属栏目 试验研究

基金项目 江西省自然科学基金面上项目(20202BABA204009);江西省重点研发计划项目(20203BBG73070)

收稿日期 2020/12/25

修改稿日期 2021/12/8

网络出版日期

作者单位点击查看

备注陈燕飞(1990-),男,江西赣州人,工程师,硕士

引用该论文: CHEN Yanfei,HUANG Shaojun,WANG Yuxiang,ZHANG Jinxiang. Distribution Variation of Rare Earth Phase in Mg-Ce AlloyDuring Solution and Aging Treatment[J]. Materials for mechancial engineering, 2022, 46(1): 56~60
陈燕飞,黄绍军,王玉香,张金祥. 固溶时效处理过程中Mg-Ce合金中稀土相的分布变化规律[J]. 机械工程材料, 2022, 46(1): 56~60


论文评价
共有人对该论文发表了看法,其中:
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
分享论文
分享到新浪微博 分享到腾讯微博 分享到人人网 分享到 Google Reader 分享到百度搜藏分享到Twitter

参考文献
【1】丁文江,付彭怀,彭立明,等.先进镁合金材料及其在航空航天领域中的应用[J].航天器环境工程,2011,28(2):103-109. DING W J,FU P H,PENG L M,et al.Advanced magnesium alloys and their applications in aerospace[J].Spacecraft Environment Engineering,2011,28(2):103-109.
 
【2】张学东.全球化背景下中国稀土产品供给问题研究[D].北京:中央财经大学,2015. ZHANG X D.Research on Chinese rare earth products supply problem under the background of globalization[D].Beijing:Central University of Finance and Economics,2015.
 
【3】汤晗均.中国稀土产业经济研究现状与发展趋势分析[J].中国市场,2016(37):61-61. TANG H J.Analysis of economic research status and development trend of China's rare earth industry[J].China Market,2016(37):61-61.
 
【4】罗非.我国稀土供需预测研究[D].北京:中国地质大学(北京),2012. LUO F.Research on China's rare earth supply and demand forecasting[D].Beijing:China University of Geosciences,2012.
 
【5】廖新庚.江西稀土产业发展战略研究[D].南昌:南昌大学,2011. LIAO X G.Study on the development strategy of Jiangxi rare earth industry[D].Nanchang:Nanchang University,2011.
 
【6】刘红.新形势下江西稀土企业发展战略研究——以J公司为例[D].南昌:南昌大学,2012. LIU H.Study on Jiangxi rare earth enterprises development strategy based on the new situation-Take J company as an example[D].Nanchang:Nanchang University,2012.
 
【7】刘余九.中国稀土产业现状及发展的主要任务[J].中国稀土学报,2007,25(3):257-263. LIU Y J.Present state and main task of development of rare earth industry in China[J].Journal of the Chinese Rare Earth Society,2007,25(3):257-263.
 
【8】王佳男.中国稀土需求预测模型研究与应用[D].赣州:江西理工大学,2018. WANG J N.Demand forecasting model for rare earth of China and its applications[D].Ganzhou:Jiangxi University of Science and Technology,2018.
 
【9】曾小勤.稀土镁合金研究与应用进展[J].稀土信息,2016(2):26-29. ZENG X Q.Progress in research and application of rare earth magnesium alloys[J].Rare Earth Information,2016(2):26-29.
 
【10】AZZEDDINE H,HANNA A,DAKHOUCHE A,et al.Impact of rare-earth elements on the corrosion performance of binary magnesium alloys[J].Journal of Alloys and Compounds,2020,829:154569.
 
【11】LIU L Z,CHEN X H,PAN F S,et al.A new high-strength Mg-Zn-Ce-Y-Zr magnesium alloy[J].Journal of Alloys and Compounds,2016,688:537-541.
 
【12】LUO Q,GUO Y L,LIU B,et al.Thermodynamics and kinetics of phase transformation in rare earth-magnesium alloys:A critical review[J].Journal of Materials Science & Technology,2020,44:171-190.
 
【13】ANG H Q.Modelling of the strain hardening behaviour of Die-cast magnesium-aluminium-rare earth alloy[J].Advanced Engineering Forum,2020,35:1-8.
 
【14】刘伟.Mg-Gd-Y-Zn系合金时效析出行为的研究[D].北京:北京有色金属研究总院,2019. LIU W.Study on the precipitation behavior of Mg-Gd-Y-Zn alloy during aging treatment[D].Beijing:Beijing General Research Institute for Nonferrous Metals,2019.
 
【15】樊昀,周玲烨,陈彬,等.热处理对超细晶稀土镁合金组织和性能的影响[J].上海航天,2019,36(2):66-73. FAN Y,ZHOU L Y,CHEN B,et al.Effect of heat treatments on microstructures and properties of ultra-fine grain rare earth-magnesium alloy[J].Aerospace Shanghai,2019,36(2):66-73.
 
【16】朱文杰,李德江,曾小勤,等.Ce对铸造Mg-5Al-2Si合金中Mg2Si相改性及力学性能的影响[J].铸造,2019,68(7):679-683. ZHU W J,LI D J,ZENG X Q,et al.Effects of Ce on Mg2Si phase modification and mechanical properties of Mg-5Al-2Si alloy[J].Foundry,2019,68(7):679-683.
 
【17】董天顺,王拓,郑晓东,等.细晶Mg-Ce中间合金的制备及其对AZ91D组织和性能的影响[J].材料导报,2017,31(12):73-78. DONG T S,WANG T,ZHENG X D,et al.Preparation of fine-grained Mg-Ce master alloy and its effect on microstructure and properties of AZ91D[J].Materials Review,2017,31(12):73-78.
 
【18】杜金星,华建社,赵旭,等.热处理对Mg-Y-Zn-Ag稀土镁合金长周期组织结构的影响[J].金属热处理,2018,43(11):173-177. DU J X,HUA J S,ZHAO X,et al.Effect of heat treatment on long-period microstructure of Mg-Y-Zn-Ag rare earth magnesium alloy[J].Heat Treatment of Metals,2018,43(11):173-177.
 
【19】强晟.简述镁合金常见强化机理及应用[J].中国科技信息,2020(24):50-51. QIANG S.Common strengthening mechanism and application of magnesium alloys[J].China Science and Technology Information,2020(24):50-51.
 
【20】BOUREZG Y I,AZZEDDINE H,BAUDIN T,et al.Texture and microhardness of Mg-Rare Earth (Nd and Ce) alloys processed by high-pressure torsion[J].Materials Science and Engineering:A,2018,724:477-485.
 
【21】ZHU S M,EASTON M A,ABBOTT T B,et al.The influence of individual rare earth elements (La,Ce,or Nd) on creep resistance of die-cast magnesium alloy AE44[J].Advanced Engineering Materials,2016,18(6):932-937.
 
【22】CHEN Y F,ZHU Z Q,ZHOU J X,et al.Study on the strengthening mechanism of rare earth Ce in magnesium alloys,based on first-principle calculations and electronegativity theory[J].Materials,2021,14(21):6681.
 
【23】WANG G G,HUANG G S,CHEN X,et al.Effects of Zn addition on the mechanical properties and texture of extruded Mg-Zn-Ca-Ce magnesium alloy sheets[J].Materials Science and Engineering:A,2017,705:46-54.
 
【24】包明明,杨素媛,何杨宇.四种状态下Mg-10Gd合金微观组织及力学性能研究[J].稀土,2021,42(2):8-15. BAO M M,YANG S Y,HE Y Y.Microstructure and mechanical properties of Mg-10Gd alloy under four treatment states[J].Chinese Rare Earths,2021,42(2):8-15.
 
【25】HAN B J,GU D D,HE Q,et al.Fabrication of a novel Mg-RE (Nd,Ce) intermetallic compound coating by molten salt diffusion and its effect on corrosion resistance of magnesium alloys[J].Journal of Rare Earths,2016,34(7):731-735.
 
相关信息
   标题 相关频次
 固溶处理对Mg-Ce合金耐腐蚀性能的影响
 6
 钨极氩弧搭接焊钽片接头的显微组织
 4
 12Cr9NiAlMo模具钢的选区激光熔化成形工艺优化及热处理后的组织和性能
 2
 6061-7075异种铝合金搅拌摩擦焊接件表面整体陶瓷防护膜的制备
 2
 AZ31B镁合金/6061铝合金异质金属连接件整体微弧氧化膜的制备及其结构
 2
 扭转变形与退火处理对再生铜杆显微组织和性能的影响
 2
 微量锆元素对激光选区熔化成形AlSi10Mg合金组织及性能的影响
 2
 一种AZ80铸造镁合金用高效微弧氧化工艺
 2
 固溶和时效对0Cr21Ni6Mn9N含氮奥氏体不锈钢组织的影响
 1
 固相微萃取-气相色谱-质谱法测定地表水中10种痕量苯系物
 1
 热处理工艺对新型节镍奥氏体无磁钢组织和性能的影响
 1