脉冲熔融法测定金属及陶瓷中氧、氮含量的研究进展
Research Progress in Determination of Oxygen and Nitrogen in Metals and Ceramic Materials by Pulse Fusion Method
摘 要
脉冲熔融法已广泛用于金属及陶瓷中氧、氮含量的测定。然而，国内关于相关设备的研究报道较少，在实际分析中，主要依据条件试验确定最佳参数，依赖加标回收保证准确度，缺少必要的理论研究及辅助方法验证检测结果。国外相关研究比较深入，设备、理论研究以及辅助方法应用均不乏亮点。基于此，系统介绍了设备，特别是检测系统、气路系统的改进，石墨坩埚的应用进展及其差异对测定的影响，还介绍了国外在钢中超低氧、活化金属分析以及陶瓷中氧、氮分析等方面的研究工作，并与国内相关工作进行对比，指出可靠的比对试验可帮助发现传统方法中存在的问题，而理论研究可从根本上解释所观察的试验现象（引用文献78篇）。
金属
陶瓷
氧
氮
研究进展
pulse fusion method
metal
ceramic
oxygen
nitrogen
research progess
Abstract
Pulse fusion method had been widely used for determination of oxygen and nitrogen in metals and ceramics. However, few researches were reported on relevant equipments in China. In the actual analysis, the optimal parameters were mainly obtained according to the conditional tests, the accuracy was ensured relying on the standard addition recovery, and necessary theoretical researches and auxiliary methods for verifying the test results was lacking. The relevant researches abroad were relatively wealthy, and there were many highlights in the application of equipments, theoretical research and auxiliary methods. Based on those, equipment improvements, especially for detection system and pneumatic system, the application progress of graphite crucibles and effect of crucible difference on the determination were systematically introduced. The research work abroad on ultra-low oxygen in steel, activated metal analysis, and oxygen and nitrogen analysis in ceramic materials were also introduced, which were compared with the domestic related work. It was concluded that reliable comparison tests could help to find the problems existing in traditional methods, and theoretical research could fundamentally explain the observed testing phenomena (78 ref. cited).
中图分类号 O659.2 DOI 10.11973/lhjy-hx202202022
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收稿日期 2021/4/2
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备注张庸,工程师,研究方向为金属材料化学分析,694785642@qq.com
引用该论文: ZHANG Yong,LI Yao,YAO Jiaren,LI Renbo,LI Hui,ZHANG Zhongyuan. Research Progress in Determination of Oxygen and Nitrogen in Metals and Ceramic Materials by Pulse Fusion Method[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2022, 58(2): 238～248
张庸,李瑶,姚佳人,李任博,李辉,张重远. 脉冲熔融法测定金属及陶瓷中氧、氮含量的研究进展[J]. 理化检验－化学分册, 2022, 58(2): 238～248
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参考文献
【1】GORKUSHA D V, GRIGOROVICH K V, KARASEV A V, et al. Content modification of different types of nonmetallic inclusions during low-carbon if steel ladle treatment[J]. Izvestiya Ferrous Metallurgy, 2019,62(5):345-352.
【2】MASUMURA T, FUJINO K, TSUCHIYAMA T, et al. Effect of carbon and nitrogen on Md30 in metastable austenitic stainless steel[J]. Tetsu-to-Hagane, 2019,105(12):1163-1172.
【3】DUBOK V A, KORNILOVA V I, GARBUZ V V. Features of determination of the oxygen and nitrogen contents in aluminum nitride and oxide powders by the method of reduction extraction[J]. Soviet Powder Metallurgy and Metal Ceramics, 1990,29(3):206-209.
【4】CUSHMAN A S. The determination of oxygen in iron and steel[J]. Journal of Industrial & Engineering Chemistry, 1911,3(6):372-374.
【5】ODA N, KATAYAMA N, ENDO K. The tin-bath technique for the simultaneous determination of oxygen and hydrogen in tantalum[J]. Transactions of the Japan Institute of Metals, 1962,3(3):142-146.
【6】PETERSON J I, MELNICK F A, STEERS J E. Evaluation of inert gas fusion method for rapid determination of oxygen in steel[J]. Analytical Chemistry, 1958,30(6):1086-1089.
【7】DENNIS L, MITCHELL J. Thermal evolution methods for carbon, sulfur, oxygen, nitrogen and hydrogen in iron and steel analysis. Encyclopedia of analytical chemistry:Applications, theory and instrumentation[M]. Hoboken:John Wiley & Sons, Ltd, 2006.
【8】DENNIS L, JOHN H. Simultaneous oxygen, nitrogen and hydrogen determination of metals[C]//2002年中国机械工程学会年会论文集.北京:[出版者不详], 2002:211-212.
【9】吴全兴.金属中气体分析的进展[J].稀有金属材料与工程, 1987,16(5):34-43.
【10】吴全兴.金属中气体分析评述[J].稀有金属材料与工程, 1992,21(1):14-19.
【11】叶信火.还原熔融法测定铜中氧的现状[J].分析试验室, 1992,11(5):58-61.
【12】王蓬,王海舟.金属中氢的分析技术进展[J].冶金分析, 2007,27(3):37-44.
【13】胡少成,沈学静,王蓬.固态金属及合金材料中氧、氮、氢联测技术进展[J].冶金分析, 2009,29(11):34-40.
【14】朱跃进.金属中气体分析现状与未来[J].冶金分析, 2014,34(3):19-23.
【15】刘攀,杜丽丽,聂富强,等.惰气熔融-红外吸收/热导法在无机固态材料气体分析中的应用[J].冶金分析, 2014,34(6):42-48.
【16】YASUHARA H, SHIMURA M, YOSHIOKA K. Influence of sample pretreatment methods on the determination of trace oxygen in iron and steel[J]. Physica Status Solidi (a), 1997,160(2):575-581.
【17】KRASOVSKII P V, GRUNER W, GRIGOROVITCH K V. Comparative study of oxide speciation in steel by inert gas fusion technique[J]. Steel Research International, 2006,77(1):64-72.
【18】KARASEV A V, GORKUSHA D, GRIGOROVICH K V, et al. Application of some modern analytical techniques for characterization of non-metallic inclusions in a Fe-10mass%Ni alloy deoxidized by Ti/Zr and Ti/Mg[J]. Metals, 2021,11(3):448-463.
【19】GRUNER W. Determination of oxygen in oxides by carrier gas hot extraction analysis with simultaneous CO<i>x detection[J]. Fresenius' Journal of Analytical Chemistry, 1999,365(7):597-603.
【20】GRUNER W, STOLLE S, BERGER L M, et al. A new experimental approach for accelerated investigations of carbothermal reactions[J]. International Journal of Refractory Metals and Hard Materials, 1999,17(1/3):227-234.
【21】BERGER L M, GRUNER W, LANGHOLF E, et al. On the mechanism of carbothermal reduction processes of TiO2 and ZrO2[J]. International Journal of Refractory Metals and Hard Materials, 1999,17(1/3):235-243.
【22】张庸,张琳,那铎,等.惰气熔融-程序升温法测定金属及粉末中氧、氮分量的研究进展[J].分析试验室, 2020,39(11):1357-1364.
【23】庄艾春, 肖红新, 张胜. 无机材料氧氮标准分析技术进展及现状[J]. 冶金分析, 2020,40(8):30-37.
【24】吴玲绮,唐舜民.用热抽提法测定铜中氧时有关抑制二氧化碳生成的研究[J].分析化学, 1989,17(9):851-853.
【25】COLOMBO A. The determination of oxygen in powdered tungsten carbide by reducing fusion:Suppression of primary carbon dioxide, selection of working conditions and adsorbed-moisture effects[J]. Talanta, 1980,27(11):881-885.
【26】GRUNER W, STOLLE S, WETZIG K. Formation of CO<i>x species during the carbothermal reduction of oxides of Zr, Si, Ti, Cr, W and Mo[J]. International Journal of Refractory Metals and Hard Materials, 2000,18(2/3):137-145.
【27】GUERRA C. Inert gas fusion analyzer:US6827903[P]. 2001-10-26[2021-03-18].
【28】KRASOVSKII P V. Determination of oxygen in oxides with high dissociation pressure by inert gas fusion method[J]. Inorganic Materials, 2014,50(15):1480-1486.
【29】UEMURA T, HIRANO A, UKON J. Combustion furnace system for analyzing elements in a sample:US6627155[P]. 1999-06-09[2021-03-18].
【30】胡少成,沈学静,王蓬,等.脉冲熔融-飞行时间质谱法同时测定钢铁中氧、氮和氢[J].冶金分析, 2011,31(7):26-30.
【31】韩维儒,周海收,陈然,等.脉冲熔融-飞行时间质谱法同时测定钨和钽中氧氮氢[J].冶金分析, 2014,34(5):20-24.
【32】但娟,陈小毅,刘林,等.脉冲熔融-飞行时间质谱法测定钒氮合金材料中氧氮氢[J].冶金分析, 2016,36(6):8-12.
【33】PACK B W, GUERRA C, WILLIS P M, et al. Analyzing system for high accuracy nitrogen determination:US6623699[P]. 2000-11-15[2021-03-18].
【34】REVESZ R N, SITEK G J. Electrically resistive crucible:US3636229[P]. 1970-10-26[2021-03-18].
【35】GEORGE J, SITEK C W. Crucible:US3899627[P]. 1974-06-28[2021-03-18].
【36】HAYASHI M. Crucible for an analyzer:US5452881[P]. 1993-11-05[2021-03-18].
【37】JOSHUA N, WETZEL G C. Crucible:US0337396[P]. 2013-06-18[2021-03-18].
【38】BREDEWEG R L. Crucible assembly:US4328386[P]. 1980-09-24[2021-03-18].
【39】TSUGE A, ACHIWA H, MORIKAWA H, et al. Determination of oxygen content in magnesium and its alloys by inert gas fusion-infrared absorptiometry[J]. Analytical Sciences, 2011,27(7):721-725.
【40】王学华,王蓬,吴振宁,等.不同类型石墨坩埚对钢中氮分析影响的探讨[J].冶金分析, 2012,32(4):33-35.
【41】张长均,王蓬,黄小峰,等.氧氮氢气体分析仪的石墨坩埚升温过程研究[J].冶金分析, 2010,30(11):71-73.
【42】谢君,朱瑛才,仉凤江,等.坩埚对高温合金中氧氮及氢分析结果的影响[J].冶金分析, 2018,38(10):7-15.
【43】COLOMBO A. Systematic errors in vacuum and inert gas fusion analysis for oxygen in metals[J]. Analytica Chimica Acta, 1976,81(2):397-402.
【44】GRUNER W,HAßLER J,BARTH P, et al. The precise determination of nitrogen in boron nitride[J]. Journal of the European Ceramic Society, 2009,29(10):2029-2035.
【45】刘英,臧慕文.金属材料分析原理与技术[M].北京:化学工业出版社, 2009.
【46】侯桂臣,张琳,李一懿,等."直投法"应用于金属粉末样品中氧氮氢分析[J].冶金分析, 2019,39(6):7-13.
【47】LÓPEZ G A, MITTEMEIJER E J.The solubility of C in solid Cu[J]. Scripta Materialia, 2004,51(1):1-5.
【48】谢孝昌,贺自强,耿小颖,等.试样表面粗糙度和表面清洗方式对M50NiL钢氧含量测定的影响[J].材料工程, 2011,39(7):61-65.
【49】TAKAHARI T, ABIKO K, OGAHARA I, et al. Determination of micro trace oxygen in high purity iron with the inert gas fusion method[J]. Tetsu-to-Hagane, 1992,78(5):774-781.
【50】YASUHARA H, SHIMURA M, YOSHIOKA K. Influence of sample treatment methods on the determination of trace oxygen in iron and steel[J]. Tetsu-to-Hagane, 1999,85(2):138-142.
【51】YASUHARA H, SHIMURA M, YOSHIOKA K, et al. Determination of trace amount of gaseous elements in iron and steel[J]. Materials Transactions, JIM, 2000,41(1):71-74.
【52】YASUHARA H, SHIMURA M, YOSHIOKA K, et al. Development of a pre-treatment procedure for the determination of trace amount of bulk oxygen in iron and steel[J]. Physica Status Solidi (a), 2002,189(1):133-138.
【53】UCHIHARA H, BANDO A, YOSHIDA S, et al. Determination of trace oxygen in steel using tin after removing surface oxide by preheating[J]. Bunseki Kagaku, 2003,52(1):27-33.
【54】UCHIHARA H, BANDO A, IKEDA M, et al. Development of determination of trace oxygen in steel using molten tin after removing surface oxide under the closed system[J]. Tetsu-to-Hagane, 2003,89(9):988-993.
【55】ITO K,KOIKE M. Development of determination of trace oxygen in steel after removing surface oxide[J]. Tetsu-to-Hagane, 2001,87(12):756-761.
【56】YOSHIOKA T, OKOCHI H, HASEGAWA R. Determination of ultra low contents of oxygen in high purity iron[J]. Materials Transactions, JIM, 1993,34(6):504-510.
【57】SUZUKI Y, TOMIYAMA S, MURASE N. Investigation on the microanalysis of oxygen in steel[J]. Denki-Seiko[Electric Furnace Steel], 1987,58(3):190-196.
【58】GRIGOROVICH K V. Nonisothermal reduction of oxides in carbon-saturated melts[J]. Journal of Physics:Conference Series, 2008,98(3):1-4.
【59】刁伟涛.粉状铝中氧的测定[J].分析化学, 1985,13(10):728-732.
【60】朱跃进,李素娟,陈文绣.铝中氧的测定[J].冶金分析, 1995,15(5):1-1.
【61】朱跃进,李素娟.惰气熔融法测定镁中氧、氢、氮[J].冶金分析, 2011,31(12):58-61.
【62】钟华.惰气熔融-红外吸收/热导法同时测定钒铝中间合金中氧氮[J].冶金分析, 2014,34(12):7-12.
【63】王宽,杨军红,柴琴琴,等.惰气熔融-热导法测定铝钒合金中氮[J].冶金分析, 2020,40(5):79-82.
【64】刘攀,张欣耀,张毅.惰气熔融-红外吸收法测定铬铝、钼铝中间合金粉中氧[J].冶金分析, 2020,40(6):13-20.
【65】王学华,杨植岗,王蓬,等.惰气熔融-红外吸收法测定硅钙合金中氧[J].冶金分析, 2017,37(4):53-56.
【66】张琳,那铎,尹志华,等.脉冲熔融-红外吸收法测定镧铈合金中氧[J].冶金分析, 2020,40(6):8-12.
【67】INOUE R, SUITO H. Determination of oxygen in iron-aluminum alloy by inert gas fusion-infrared absorptiometry[J]. Materials Transactions, JIM, 1991,32(12):1164-1169.
【68】宋忠训.脉冲惰性气氛熔融法测定钼中微量氧所用浴料的探讨[J].分析试验室, 1989,8(5):30-32.
【69】TSUGE A, UWAMINO Y, ISHIZUKA T, et al. Determination of oxygen in oxide ceramics by inert gas fusion analysis[J]. Journal of the Ceramic Society of Japan, 1993,101(6):713-716.
【70】BECK H P, MVLLER H. Determination of the oxygen content of ceramic materials by carrier-gas-heat-extraction (CGHE)-feasibility and restrictions of the method[J]. Fresenius' Journal of Analytical Chemistry, 1997,357(6):652-655.
【71】ADELHELM C, HIRSCHFELD D. Inter-laboratory comparison of the chemical analysis of silicon nitride[J]. Fresenius' Journal of Analytical Chemistry, 1992,342(1/2):125-127.
【72】WÖRNER W, KAISER G, SCHUBERT H. Analytical scheme for tracing sources of contamination during processing of Si3N4 in clean rooms[J]. Microchimica Acta, 1993,110(4/6):173-186.
【73】KITAYAMA M, HIRAO K, TSUGE A, et al. Oxygen content in β-Si3N4 crystal lattice[J]. Journal of the American Ceramic Society, 2004,82(11):3263-3265.
【74】WATANABE M, NARUKAWA A. Determination of the surface oxygen contents of silicon nitride powder using an acid dissolution/inert-gas fusion method[J]. Bunseki Kagaku, 2001,50(1):57-60.
【75】TANAKA S, OKAYAMA J, UCHIHARA H, et al. Improvement of precisionin oxygen and nitrogen analysis of raw ceramic powders[J]. Journal of the Ceramic Society of Japan, 1998.106(10):1031-1033.
【76】WATANABE M, NARUKAWA A. Automatic sample molding for measurements of oxygen and nitrogen in silicon nitrides with an inert-gas fusion technique[J]. Bunseki Kagaku, 2000,49(10):771-774.
【77】GRUNER W, WOLLEIN B, LENGAUER W. ε-TaN as a reference material for the determination of high nitrogen contents[J]. Microchimica Acta, 2004,146(1):1-6.
【2】MASUMURA T, FUJINO K, TSUCHIYAMA T, et al. Effect of carbon and nitrogen on Md30 in metastable austenitic stainless steel[J]. Tetsu-to-Hagane, 2019,105(12):1163-1172.
【3】DUBOK V A, KORNILOVA V I, GARBUZ V V. Features of determination of the oxygen and nitrogen contents in aluminum nitride and oxide powders by the method of reduction extraction[J]. Soviet Powder Metallurgy and Metal Ceramics, 1990,29(3):206-209.
【4】CUSHMAN A S. The determination of oxygen in iron and steel[J]. Journal of Industrial & Engineering Chemistry, 1911,3(6):372-374.
【5】ODA N, KATAYAMA N, ENDO K. The tin-bath technique for the simultaneous determination of oxygen and hydrogen in tantalum[J]. Transactions of the Japan Institute of Metals, 1962,3(3):142-146.
【6】PETERSON J I, MELNICK F A, STEERS J E. Evaluation of inert gas fusion method for rapid determination of oxygen in steel[J]. Analytical Chemistry, 1958,30(6):1086-1089.
【7】DENNIS L, MITCHELL J. Thermal evolution methods for carbon, sulfur, oxygen, nitrogen and hydrogen in iron and steel analysis. Encyclopedia of analytical chemistry:Applications, theory and instrumentation[M]. Hoboken:John Wiley & Sons, Ltd, 2006.
【8】DENNIS L, JOHN H. Simultaneous oxygen, nitrogen and hydrogen determination of metals[C]//2002年中国机械工程学会年会论文集.北京:[出版者不详], 2002:211-212.
【9】吴全兴.金属中气体分析的进展[J].稀有金属材料与工程, 1987,16(5):34-43.
【10】吴全兴.金属中气体分析评述[J].稀有金属材料与工程, 1992,21(1):14-19.
【11】叶信火.还原熔融法测定铜中氧的现状[J].分析试验室, 1992,11(5):58-61.
【12】王蓬,王海舟.金属中氢的分析技术进展[J].冶金分析, 2007,27(3):37-44.
【13】胡少成,沈学静,王蓬.固态金属及合金材料中氧、氮、氢联测技术进展[J].冶金分析, 2009,29(11):34-40.
【14】朱跃进.金属中气体分析现状与未来[J].冶金分析, 2014,34(3):19-23.
【15】刘攀,杜丽丽,聂富强,等.惰气熔融-红外吸收/热导法在无机固态材料气体分析中的应用[J].冶金分析, 2014,34(6):42-48.
【16】YASUHARA H, SHIMURA M, YOSHIOKA K. Influence of sample pretreatment methods on the determination of trace oxygen in iron and steel[J]. Physica Status Solidi (a), 1997,160(2):575-581.
【17】KRASOVSKII P V, GRUNER W, GRIGOROVITCH K V. Comparative study of oxide speciation in steel by inert gas fusion technique[J]. Steel Research International, 2006,77(1):64-72.
【18】KARASEV A V, GORKUSHA D, GRIGOROVICH K V, et al. Application of some modern analytical techniques for characterization of non-metallic inclusions in a Fe-10mass%Ni alloy deoxidized by Ti/Zr and Ti/Mg[J]. Metals, 2021,11(3):448-463.
【19】GRUNER W. Determination of oxygen in oxides by carrier gas hot extraction analysis with simultaneous CO<i>x detection[J]. Fresenius' Journal of Analytical Chemistry, 1999,365(7):597-603.
【20】GRUNER W, STOLLE S, BERGER L M, et al. A new experimental approach for accelerated investigations of carbothermal reactions[J]. International Journal of Refractory Metals and Hard Materials, 1999,17(1/3):227-234.
【21】BERGER L M, GRUNER W, LANGHOLF E, et al. On the mechanism of carbothermal reduction processes of TiO2 and ZrO2[J]. International Journal of Refractory Metals and Hard Materials, 1999,17(1/3):235-243.
【22】张庸,张琳,那铎,等.惰气熔融-程序升温法测定金属及粉末中氧、氮分量的研究进展[J].分析试验室, 2020,39(11):1357-1364.
【23】庄艾春, 肖红新, 张胜. 无机材料氧氮标准分析技术进展及现状[J]. 冶金分析, 2020,40(8):30-37.
【24】吴玲绮,唐舜民.用热抽提法测定铜中氧时有关抑制二氧化碳生成的研究[J].分析化学, 1989,17(9):851-853.
【25】COLOMBO A. The determination of oxygen in powdered tungsten carbide by reducing fusion:Suppression of primary carbon dioxide, selection of working conditions and adsorbed-moisture effects[J]. Talanta, 1980,27(11):881-885.
【26】GRUNER W, STOLLE S, WETZIG K. Formation of CO<i>x species during the carbothermal reduction of oxides of Zr, Si, Ti, Cr, W and Mo[J]. International Journal of Refractory Metals and Hard Materials, 2000,18(2/3):137-145.
【27】GUERRA C. Inert gas fusion analyzer:US6827903[P]. 2001-10-26[2021-03-18].
【28】KRASOVSKII P V. Determination of oxygen in oxides with high dissociation pressure by inert gas fusion method[J]. Inorganic Materials, 2014,50(15):1480-1486.
【29】UEMURA T, HIRANO A, UKON J. Combustion furnace system for analyzing elements in a sample:US6627155[P]. 1999-06-09[2021-03-18].
【30】胡少成,沈学静,王蓬,等.脉冲熔融-飞行时间质谱法同时测定钢铁中氧、氮和氢[J].冶金分析, 2011,31(7):26-30.
【31】韩维儒,周海收,陈然,等.脉冲熔融-飞行时间质谱法同时测定钨和钽中氧氮氢[J].冶金分析, 2014,34(5):20-24.
【32】但娟,陈小毅,刘林,等.脉冲熔融-飞行时间质谱法测定钒氮合金材料中氧氮氢[J].冶金分析, 2016,36(6):8-12.
【33】PACK B W, GUERRA C, WILLIS P M, et al. Analyzing system for high accuracy nitrogen determination:US6623699[P]. 2000-11-15[2021-03-18].
【34】REVESZ R N, SITEK G J. Electrically resistive crucible:US3636229[P]. 1970-10-26[2021-03-18].
【35】GEORGE J, SITEK C W. Crucible:US3899627[P]. 1974-06-28[2021-03-18].
【36】HAYASHI M. Crucible for an analyzer:US5452881[P]. 1993-11-05[2021-03-18].
【37】JOSHUA N, WETZEL G C. Crucible:US0337396[P]. 2013-06-18[2021-03-18].
【38】BREDEWEG R L. Crucible assembly:US4328386[P]. 1980-09-24[2021-03-18].
【39】TSUGE A, ACHIWA H, MORIKAWA H, et al. Determination of oxygen content in magnesium and its alloys by inert gas fusion-infrared absorptiometry[J]. Analytical Sciences, 2011,27(7):721-725.
【40】王学华,王蓬,吴振宁,等.不同类型石墨坩埚对钢中氮分析影响的探讨[J].冶金分析, 2012,32(4):33-35.
【41】张长均,王蓬,黄小峰,等.氧氮氢气体分析仪的石墨坩埚升温过程研究[J].冶金分析, 2010,30(11):71-73.
【42】谢君,朱瑛才,仉凤江,等.坩埚对高温合金中氧氮及氢分析结果的影响[J].冶金分析, 2018,38(10):7-15.
【43】COLOMBO A. Systematic errors in vacuum and inert gas fusion analysis for oxygen in metals[J]. Analytica Chimica Acta, 1976,81(2):397-402.
【44】GRUNER W,HAßLER J,BARTH P, et al. The precise determination of nitrogen in boron nitride[J]. Journal of the European Ceramic Society, 2009,29(10):2029-2035.
【45】刘英,臧慕文.金属材料分析原理与技术[M].北京:化学工业出版社, 2009.
【46】侯桂臣,张琳,李一懿,等."直投法"应用于金属粉末样品中氧氮氢分析[J].冶金分析, 2019,39(6):7-13.
【47】LÓPEZ G A, MITTEMEIJER E J.The solubility of C in solid Cu[J]. Scripta Materialia, 2004,51(1):1-5.
【48】谢孝昌,贺自强,耿小颖,等.试样表面粗糙度和表面清洗方式对M50NiL钢氧含量测定的影响[J].材料工程, 2011,39(7):61-65.
【49】TAKAHARI T, ABIKO K, OGAHARA I, et al. Determination of micro trace oxygen in high purity iron with the inert gas fusion method[J]. Tetsu-to-Hagane, 1992,78(5):774-781.
【50】YASUHARA H, SHIMURA M, YOSHIOKA K. Influence of sample treatment methods on the determination of trace oxygen in iron and steel[J]. Tetsu-to-Hagane, 1999,85(2):138-142.
【51】YASUHARA H, SHIMURA M, YOSHIOKA K, et al. Determination of trace amount of gaseous elements in iron and steel[J]. Materials Transactions, JIM, 2000,41(1):71-74.
【52】YASUHARA H, SHIMURA M, YOSHIOKA K, et al. Development of a pre-treatment procedure for the determination of trace amount of bulk oxygen in iron and steel[J]. Physica Status Solidi (a), 2002,189(1):133-138.
【53】UCHIHARA H, BANDO A, YOSHIDA S, et al. Determination of trace oxygen in steel using tin after removing surface oxide by preheating[J]. Bunseki Kagaku, 2003,52(1):27-33.
【54】UCHIHARA H, BANDO A, IKEDA M, et al. Development of determination of trace oxygen in steel using molten tin after removing surface oxide under the closed system[J]. Tetsu-to-Hagane, 2003,89(9):988-993.
【55】ITO K,KOIKE M. Development of determination of trace oxygen in steel after removing surface oxide[J]. Tetsu-to-Hagane, 2001,87(12):756-761.
【56】YOSHIOKA T, OKOCHI H, HASEGAWA R. Determination of ultra low contents of oxygen in high purity iron[J]. Materials Transactions, JIM, 1993,34(6):504-510.
【57】SUZUKI Y, TOMIYAMA S, MURASE N. Investigation on the microanalysis of oxygen in steel[J]. Denki-Seiko[Electric Furnace Steel], 1987,58(3):190-196.
【58】GRIGOROVICH K V. Nonisothermal reduction of oxides in carbon-saturated melts[J]. Journal of Physics:Conference Series, 2008,98(3):1-4.
【59】刁伟涛.粉状铝中氧的测定[J].分析化学, 1985,13(10):728-732.
【60】朱跃进,李素娟,陈文绣.铝中氧的测定[J].冶金分析, 1995,15(5):1-1.
【61】朱跃进,李素娟.惰气熔融法测定镁中氧、氢、氮[J].冶金分析, 2011,31(12):58-61.
【62】钟华.惰气熔融-红外吸收/热导法同时测定钒铝中间合金中氧氮[J].冶金分析, 2014,34(12):7-12.
【63】王宽,杨军红,柴琴琴,等.惰气熔融-热导法测定铝钒合金中氮[J].冶金分析, 2020,40(5):79-82.
【64】刘攀,张欣耀,张毅.惰气熔融-红外吸收法测定铬铝、钼铝中间合金粉中氧[J].冶金分析, 2020,40(6):13-20.
【65】王学华,杨植岗,王蓬,等.惰气熔融-红外吸收法测定硅钙合金中氧[J].冶金分析, 2017,37(4):53-56.
【66】张琳,那铎,尹志华,等.脉冲熔融-红外吸收法测定镧铈合金中氧[J].冶金分析, 2020,40(6):8-12.
【67】INOUE R, SUITO H. Determination of oxygen in iron-aluminum alloy by inert gas fusion-infrared absorptiometry[J]. Materials Transactions, JIM, 1991,32(12):1164-1169.
【68】宋忠训.脉冲惰性气氛熔融法测定钼中微量氧所用浴料的探讨[J].分析试验室, 1989,8(5):30-32.
【69】TSUGE A, UWAMINO Y, ISHIZUKA T, et al. Determination of oxygen in oxide ceramics by inert gas fusion analysis[J]. Journal of the Ceramic Society of Japan, 1993,101(6):713-716.
【70】BECK H P, MVLLER H. Determination of the oxygen content of ceramic materials by carrier-gas-heat-extraction (CGHE)-feasibility and restrictions of the method[J]. Fresenius' Journal of Analytical Chemistry, 1997,357(6):652-655.
【71】ADELHELM C, HIRSCHFELD D. Inter-laboratory comparison of the chemical analysis of silicon nitride[J]. Fresenius' Journal of Analytical Chemistry, 1992,342(1/2):125-127.
【72】WÖRNER W, KAISER G, SCHUBERT H. Analytical scheme for tracing sources of contamination during processing of Si3N4 in clean rooms[J]. Microchimica Acta, 1993,110(4/6):173-186.
【73】KITAYAMA M, HIRAO K, TSUGE A, et al. Oxygen content in β-Si3N4 crystal lattice[J]. Journal of the American Ceramic Society, 2004,82(11):3263-3265.
【74】WATANABE M, NARUKAWA A. Determination of the surface oxygen contents of silicon nitride powder using an acid dissolution/inert-gas fusion method[J]. Bunseki Kagaku, 2001,50(1):57-60.
【75】TANAKA S, OKAYAMA J, UCHIHARA H, et al. Improvement of precisionin oxygen and nitrogen analysis of raw ceramic powders[J]. Journal of the Ceramic Society of Japan, 1998.106(10):1031-1033.
【76】WATANABE M, NARUKAWA A. Automatic sample molding for measurements of oxygen and nitrogen in silicon nitrides with an inert-gas fusion technique[J]. Bunseki Kagaku, 2000,49(10):771-774.
【77】GRUNER W, WOLLEIN B, LENGAUER W. ε-TaN as a reference material for the determination of high nitrogen contents[J]. Microchimica Acta, 2004,146(1):1-6.
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