TiO2掺杂对CaO-Al2O3-SiO2系玻璃结构和性能的影响
Effect of TiO2 Doping on Structure and Properties ofCaO-Al2O3-SiO2 Series Glass
摘 要
采用传统熔体冷却法制备TiO2掺杂量（物质的量分数）为0~5.0%的CaO-Al2O3-SiO2（CAS）系玻璃，研究了TiO2掺杂量对该玻璃微观结构、热稳定性、弯曲强度的影响规律。结果表明：TiO2在CAS系玻璃网络中主要以[TiO5]单元的形式存在，随着TiO2掺杂量的增加，玻璃中的[TiO5]单元和Ti-O-Si键数量先增加后降低，玻璃网络中的桥氧数量先增多后减少，玻璃的光学带隙先增大后减小，且均在TiO2掺杂量为4.0%时达到最大值；随着TiO2掺杂量的增加，CAS系玻璃的热稳定性和弯曲强度均先提高后降低，当TiO2掺杂量为4%时综合性能最好，此时玻璃化转变温度、弯曲强度和光学带隙分别为798.24℃，95.58 MPa，3.75 eV。
TiO2
热稳定性
弯曲强度
CaO-Al2O3-SiO2 series glass
TiO2
thermal stability
bending strength
Abstract
CaO-Al2O3-SiO2 (CAS) series glass with TiO2 doping amount (mole fraction) of 0-5.0% was prepared by traditional melt cooling method, and the effect of TiO2 doping amount on the micro structure, thermal stability and bending strength of the glass was studied. The results show that TiO2 mainly existed in the form of[TiO5] unit in CAS series glass network. With increasing TiO2 doping amount, the number of[TiO5] unit and Ti-O-Si bond in the glass, the number of bridge oxygen in the glass network, and optical band gap of the glass all first increased and then decreased, and all reached the largest value when the TiO2 doping amount was 4.0%. With increasing TiO2 doping amount, the thermal stability and flexural strength of CAS series glass first increased and then decreased. When the doping amount of TiO2 was 4%, the comprehensive performance was the best, and the glass transition temperature, bending strength and optical band gap were 798.24℃, 95.58 MPa and 3.75 eV, respectively.
中图分类号 TQ171 DOI 10.11973/jxgccl202204005
所属栏目 试验研究
基金项目 浙江省基础公益研究计划项目（LGG19E020003）；国家国际科技合作专项项目（2013DFE63070）
收稿日期 2020/12/11
修改稿日期 2021/12/15
网络出版日期
作者单位点击查看
备注陈超(1993-),男,江西南昌人,硕士研究生
引用该论文: CHEN Chao,ZHU Qingong,WANG Huanping,XU Shiqing,CAO Yongsheng,PEI Weiwei. Effect of TiO2 Doping on Structure and Properties ofCaO-Al2O3-SiO2 Series Glass[J]. Materials for mechancial engineering, 2022, 46(4): 32～36
陈超,朱钦塨,王焕平,徐时清,曹永盛,裴魏魏. TiO2掺杂对CaO-Al2O3-SiO2系玻璃结构和性能的影响[J]. 机械工程材料, 2022, 46(4): 32～36
共有人对该论文发表了看法，其中：
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】叶时迁.高强度高模量玻璃的结构与性能研究[D].武汉:武汉理工大学, 2018. YE S Q.Study on structure and properties of high strength and high modulus glass[D].Wuhan:Wuhan University of Technology, 2018.
【2】DUAN R G, LIANG K M, GU S R.The effect of Ti4+ on the site of Al3+ in the structure of CaO-Al2O3-SiO2-TiO2 system glass[J].Materials Science and Engineering:A, 1998, 249(1/2):217-222.
【3】PAPAGEORGIOU D G, KINLOCH I A, YOUNG R J.Hybrid multifunctional graphene/glass-fibre polypropylene composites[J].Composites Science and Technology, 2016, 137:44-51.
【4】范栋浩, 莫利毫.新型悬浮式风力发电装置设计[J].节能, 2020, 39(7):39-40. FAN D H, MO L H.Design of new type suspended wind power generation device[J].Energy Conservation, 2020, 39(7):39-40.
【5】LAHUERTA F, NIJSSEN R P L, VAN DER MEER F P, et al.Thickness scaled compression tests in unidirectional glass fibre reinforced composites in static and fatigue loading[J].Composites Science and Technology, 2016, 123:115-124.
【6】王文, 滕元成, 吴浪, 等.ZnO掺杂对CaO-Al2O3-SiO2系玻璃的结构和化学稳定性的影响[J].玻璃, 2019, 46(12):1-9. WANG W, TENG Y C, WU L, et al.Effect of ZnO on structure and chemical stability of CaO-Al2O3-SiO2 glasses[J].Glass, 2019, 46(12):1-9.
【7】MARZOUK M A, ELBATAL H A, ABDEL GHANY A M, et al.Ultraviolet, visible, ESR, and infrared spectroscopic studies of CeO2-doped lithium phosphate glasses and effect of gamma irradiation[J].Journal of Molecular Structure, 2011, 997(1/2/3):94-102.
【8】RAO C S, RAVIKUMAR V, SRIKUMAR T, et al.The role of coordination and valance states of tungsten ions on some physical properties of Li2O-Al2O3-ZrO2-SiO2 glass system[J].Journal of Non-Crystalline Solids, 2011, 357(16/17):3094-3102.
【9】MARIYAPPAN M, ARUNKUMAR S, MARIMUTHU K.Effect of Bi2O3 on the structural and spectroscopic properties of Sm3+ ions doped sodiumfluoroborate glasses[J].Journal of Molecular Structure, 2016, 1105:214-224.
【10】KUNDU R S, DULT M, PUNIA R, et al.Titanium induced structural modifications in bismuth silicate glasses[J].Journal of Molecular Structure, 2014, 1063:77-82.
【11】SINGH L, THAKUR V, PUNIA R, et al.Structural and optical properties of barium titanate modified bismuth borate glasses[J].Solid State Sciences, 2014, 37:64-71.
【12】KUMAR M, UNIYAL A, CHAUHAN A P S, et al.Optical absorption and fluorescent behaviour of titanium ions in silicate glasses[J].Bulletin of Materials Science, 2003, 26(3):335-341.
【13】SCHABBACH L M, BONDIOLI F, FREDEL M C.Color prediction with simplified Kubelka-Munk model in glazes containing Fe2O3-ZrSiO4 coral pink pigments[J].Dyes and Pigments, 2013, 99(3):1029-1035.
【14】SHAKERI M S, REZVANI M.Optical band gap and spectroscopic study of lithium alumino silicate glass containing Y3+ ions[J].Spectrochimica Acta Part A:Molecular and Biomolecular Spectroscopy, 2011, 79(5):1920-1925.
【15】WANG Z L, CHENG L F.Effects of doping CeO2/TiO2 on structure and properties of silicate glass[J].Journal of Alloys and Compounds, 2014, 597:167-174.
【16】BROW R K, TALLANT D R, WARREN W L, et al.Spectroscopic studies of the structure of titanophosphate and calcium titanophosphate glasses[J].Physics and Chemistry of Glasses, 1997, 38(6):300-306.
【17】MCMILLAN P, PIRIOU B.Raman spectroscopy of calcium aluminate glasses and crystals[J].Journal of Non-Crystalline Solids, 1983, 55(2):221-242.
【18】MCMILLAN P.Structural studies of silicate glasses and melts-applications and limitations of Raman spectroscopy[J].American Mineralogist, 1984, 69(6):622-644.
【19】ZHANG X H, DU Z, WU H T, et al.Effect of TiO2 on structure and dielectric properties of RO-Al2O3-B2O3-SiO2(R=Ca, Mg) glasses[J].Surface Review and Letters, 2013, 20(3/4):1350030.
【20】BUNKER B C, ARNOLD G W, WILDER J A.Phosphate glass dissolution in aqueous solutions[J].Journal of Non-Crystalline Solids, 1984, 64(3):291-316.
【21】JHA P, SINGH K.Effect of MgO on bioactivity, hardness, structural and optical properties of SiO2-K2O-CaO-MgO glasses[J].Ceramics International, 2016, 42(1):436-444.
【22】MASSERA J, VASSALLO-BREILLOT M, TÖRNGREN B, et al.Effect of CeO2 doping on thermal, optical, structural and in vitro properties of a phosphate based bioactive glass[J].Journal of Non-Crystalline Solids, 2014, 402:28-35.
【2】DUAN R G, LIANG K M, GU S R.The effect of Ti4+ on the site of Al3+ in the structure of CaO-Al2O3-SiO2-TiO2 system glass[J].Materials Science and Engineering:A, 1998, 249(1/2):217-222.
【3】PAPAGEORGIOU D G, KINLOCH I A, YOUNG R J.Hybrid multifunctional graphene/glass-fibre polypropylene composites[J].Composites Science and Technology, 2016, 137:44-51.
【4】范栋浩, 莫利毫.新型悬浮式风力发电装置设计[J].节能, 2020, 39(7):39-40. FAN D H, MO L H.Design of new type suspended wind power generation device[J].Energy Conservation, 2020, 39(7):39-40.
【5】LAHUERTA F, NIJSSEN R P L, VAN DER MEER F P, et al.Thickness scaled compression tests in unidirectional glass fibre reinforced composites in static and fatigue loading[J].Composites Science and Technology, 2016, 123:115-124.
【6】王文, 滕元成, 吴浪, 等.ZnO掺杂对CaO-Al2O3-SiO2系玻璃的结构和化学稳定性的影响[J].玻璃, 2019, 46(12):1-9. WANG W, TENG Y C, WU L, et al.Effect of ZnO on structure and chemical stability of CaO-Al2O3-SiO2 glasses[J].Glass, 2019, 46(12):1-9.
【7】MARZOUK M A, ELBATAL H A, ABDEL GHANY A M, et al.Ultraviolet, visible, ESR, and infrared spectroscopic studies of CeO2-doped lithium phosphate glasses and effect of gamma irradiation[J].Journal of Molecular Structure, 2011, 997(1/2/3):94-102.
【8】RAO C S, RAVIKUMAR V, SRIKUMAR T, et al.The role of coordination and valance states of tungsten ions on some physical properties of Li2O-Al2O3-ZrO2-SiO2 glass system[J].Journal of Non-Crystalline Solids, 2011, 357(16/17):3094-3102.
【9】MARIYAPPAN M, ARUNKUMAR S, MARIMUTHU K.Effect of Bi2O3 on the structural and spectroscopic properties of Sm3+ ions doped sodiumfluoroborate glasses[J].Journal of Molecular Structure, 2016, 1105:214-224.
【10】KUNDU R S, DULT M, PUNIA R, et al.Titanium induced structural modifications in bismuth silicate glasses[J].Journal of Molecular Structure, 2014, 1063:77-82.
【11】SINGH L, THAKUR V, PUNIA R, et al.Structural and optical properties of barium titanate modified bismuth borate glasses[J].Solid State Sciences, 2014, 37:64-71.
【12】KUMAR M, UNIYAL A, CHAUHAN A P S, et al.Optical absorption and fluorescent behaviour of titanium ions in silicate glasses[J].Bulletin of Materials Science, 2003, 26(3):335-341.
【13】SCHABBACH L M, BONDIOLI F, FREDEL M C.Color prediction with simplified Kubelka-Munk model in glazes containing Fe2O3-ZrSiO4 coral pink pigments[J].Dyes and Pigments, 2013, 99(3):1029-1035.
【14】SHAKERI M S, REZVANI M.Optical band gap and spectroscopic study of lithium alumino silicate glass containing Y3+ ions[J].Spectrochimica Acta Part A:Molecular and Biomolecular Spectroscopy, 2011, 79(5):1920-1925.
【15】WANG Z L, CHENG L F.Effects of doping CeO2/TiO2 on structure and properties of silicate glass[J].Journal of Alloys and Compounds, 2014, 597:167-174.
【16】BROW R K, TALLANT D R, WARREN W L, et al.Spectroscopic studies of the structure of titanophosphate and calcium titanophosphate glasses[J].Physics and Chemistry of Glasses, 1997, 38(6):300-306.
【17】MCMILLAN P, PIRIOU B.Raman spectroscopy of calcium aluminate glasses and crystals[J].Journal of Non-Crystalline Solids, 1983, 55(2):221-242.
【18】MCMILLAN P.Structural studies of silicate glasses and melts-applications and limitations of Raman spectroscopy[J].American Mineralogist, 1984, 69(6):622-644.
【19】ZHANG X H, DU Z, WU H T, et al.Effect of TiO2 on structure and dielectric properties of RO-Al2O3-B2O3-SiO2(R=Ca, Mg) glasses[J].Surface Review and Letters, 2013, 20(3/4):1350030.
【20】BUNKER B C, ARNOLD G W, WILDER J A.Phosphate glass dissolution in aqueous solutions[J].Journal of Non-Crystalline Solids, 1984, 64(3):291-316.
【21】JHA P, SINGH K.Effect of MgO on bioactivity, hardness, structural and optical properties of SiO2-K2O-CaO-MgO glasses[J].Ceramics International, 2016, 42(1):436-444.
【22】MASSERA J, VASSALLO-BREILLOT M, TÖRNGREN B, et al.Effect of CeO2 doping on thermal, optical, structural and in vitro properties of a phosphate based bioactive glass[J].Journal of Non-Crystalline Solids, 2014, 402:28-35.
相关信息
