Corrosion Behavior of Ni, Cr-Containing Corrosion Resistant Steel in High Temperature and High Cl- Environment
摘 要
冶炼了含Ni和Ni-Cr复合钢,采用室外暴晒试验结合锈层成分分析,腐蚀速率计算等研究了其在热带海洋大气环境中的腐蚀行为。结果表明:普碳钢、含Ni钢、和含Ni-Cr复合钢在试验环境中的腐蚀速率分别为66.84,41.54,38.29 μm/a。合金元素Ni、Cr明显提高钢的耐蚀性。试样表面锈层主要由γ-FeOOH、α-FeOOH组成,还包含较小的Fe3O4颗粒和FeO片层。普通碳钢的锈层比另外两种试样厚,锈层中α-FeOOH含量更高、更稳定,而加Ni、Ni-Cr的试样经过半年试验后,表面未生成稳定锈层。经过半年室外暴晒试验,Ni元素在锈层中含量较少,但是在锈层下钢材内有富集现象。点蚀坑中存在Cr、Cu元素富集。
Abstract
Steels containing Ni and Ni-Cr were smelted, and the corrosion behavior of these steels in tropical marine atmosphere was studied by outdoor exposure test combined with rust layer composition analysis and corrosion rate calculation. The results showed that the corrosion rates of plain carbon steel, Ni-containing steel, and Ni-Cr-containing steel in the experimental environment were 66.84, 41.54, and 38.29 μm/a, respectively. Alloying elements Ni and Cr significantly improved the corrosion resistance of steel. The rust layer on the surface of samples was mainly composed of γ-FeOOH and α-FeOOH, and also contained relatively small Fe3O4 particles and FeO lamellae. The rust layer of ordinary carbon steel was thicker than that of the other two steels, and the content of α-FeOOH in the rust layer of carbon steel was higher and more stable, while the samples with Ni and Ni-Cr had no stable rust layer formed on the surface after half a year of testing. After half a year of outdoor exposure test, the content of Ni element in the rust layer was small, but there was an enrichment phenomenon in the steel under the rust layer. Cr and Cu were enriched in pitting pits.
中图分类号 TJ07 TG174 DOI 10.11973/fsyfh-202204003
所属栏目 试验研究
基金项目 国家重点研发计划(2016YFC0401205)
收稿日期 2020/7/25
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引用该论文: YANG Jianwei,CAI Ning,JIANG Shan,HOU Qiang,CAO Jianping,XU Feifan,LIU Liwei. Corrosion Behavior of Ni, Cr-Containing Corrosion Resistant Steel in High Temperature and High Cl- Environment[J]. Corrosion & Protection, 2022, 43(4): 13
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【5】MA Y T,LI Y,WANG F H. Weatherability of 09CuPCrNi steel in a tropical marine environment[J]. Corrosion Science,2009,51(8):1725-1732.
【6】MORCILLO M,CHICO B,DÍAZ I,et al. Atmospheric corrosion data of weathering steels. A review[J]. Corrosion Science,2013,77:6-24.
【7】王力,董超芳,张达威,等. 合金元素对铝合金在泰国曼谷地区初期腐蚀行为的影响[J]. 金属学报,2020,56(1):119-128.
【8】KAMIMURA T,KASHIMA K,SUGAE K,et al. The role of chloride ion on the atmospheric corrosion of steel and corrosion resistance of Sn-bearing steel[J]. Corrosion Science,2012,62:34-41.
【9】程多云,赵晋斌,刘波,等. 高镍钢和传统耐候钢在马尔代夫严酷海洋大气环境中的腐蚀行为研究[J]. 中国腐蚀与防护学报,2019,39(1):29-35.
【10】赵柏杰,赵俊杰,范益,等. 含Mo低合金钢在模拟酸性海洋大气环境中的腐蚀规律研究[J]. 材料开发与应用,2019,34(6):86-95.
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【12】WU W,CHENG X Q,HOU H X,et al. Insight into the product film formed on Ni-advanced weathering steel in a tropical marine atmosphere[J]. Applied Surface Science,2018,436:80-89.
【13】郝献超,肖葵,张汉青,等. 模拟海洋大气环境下Cu和Cr对耐候钢耐腐蚀性能的影响[J]. 材料保护,2009,42(1):21-23,43,90.
【14】CANO H,NEFF D,MORCILLO M,et al. Characterization of corrosion products formed on Ni2.4 wt%-Cu 0.5 wt%-Cr 0.5 wt% weathering steel exposed in marine atmospheres[J]. Corrosion Science,2014,87:438-451.
【15】DÍAZ I,CANO H,LOPESINO P,et al. Five-year atmospheric corrosion of Cu,Cr and Ni weathering steels in a wide range of environments[J]. Corrosion Science,2018,141:146-157.
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