超临界水氧化反应器的研究进展
Research Progress of Supercritical Water Oxidation Reactor
摘 要
利用超临界水氧化法处理难降解有机废弃物具有诸多优点,日益受到重视,但其核心装置反应器的制造成本较高,且在运行过程中易产生盐堵和腐蚀等问题,阻碍了其工业化进程。为满足高参量、大容量、长周期稳定运行的需要,对超临界水氧化反应器的研究与应用现状进行了详细的介绍,在此基础上对反应器的结构优化提出了建议和可能的解决方案,以期为超临界水氧化技术的工业应用提供指导。
有机废弃物
反应器
结构优化
supercritical water oxidation (SCWO)
organic waste material
reactor
structure optimization
Abstract
Treatment of refractory organic waste by supercritical water oxidation (SCWO) has many advantages and is gaining more and more attentions. However, the manufacturing cost of the core device reactor of SCWO is relatively high, and problems such as salt plugging and corrosion are easily generated during operation, which hinders its industrialization. In order to meet the needs of high-parameter, large-capacity and long-term stable operation, the research and application status of the SCWO reactor is introduced in detail. And on this basis, suggestions and possible solutions for the structure optimization of the reactor are proposed. All these were expected to provide guidance for the industrial application of SCWO technology.
中图分类号 X703 DOI 10.11973/fsyfh-202208014
所属栏目 专论
基金项目 江苏省环保科研项目(2012031)
收稿日期 2020/8/17
修改稿日期
网络出版日期
作者单位点击查看
引用该论文: ZHOU Hongyi,LIAO Chuanhua. Research Progress of Supercritical Water Oxidation Reactor[J]. Corrosion & Protection, 2022, 43(8): 70
共有人对该论文发表了看法，其中：
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】MODELL M. Treatment for oxidation of organic material in supercritical water:US 433819 . 1982-04-03.
【2】廖玮,廖传华,朱廷风,等. 超临界水氧化技术在环境治理中的应用 . 印染助剂,2019,36(8):6-10.
【3】AL-DURI B,ALSOQYANI F,KINGS I. Supercritical water oxidation for the destruction of hazardous waste:better than incineration . Philosophical Transactions. Series A,Mathematical,Physical,and Engineering Sciences,2015,373(2057):20150013.
【4】廖玮,朱廷风,廖传华,等. 超临界水氧化技术在能量转化中的应用 . 水处理技术,2019,45(3):14-17.
【5】廖传华,朱跃钊,李永生. 超临界水氧化反应器的研究进展 . 环境工程,2010,28(2):7-12,23.
【6】邢军,于驰,詹世平,等. 连续式超临界水氧化反应器处理对苯甲酸模拟废水 . 资源节约与环保,2013(12):75,82.
【7】MUEGGENBURG H H,ROUSAR D C,YOUNG M F. Supercritical water oxidation reactor with wall conduits for boundary flow control:US5387398 . 1995-02-07.
【8】BERMEJO M D,MARTÍN Á,QUEIROZ J P S,et al. Computational fluid dynamics simulation of a transpiring wall reactor for supercritical water oxidation . Chemical Engineering Journal,2010,158(3):431-440.
【9】ZHANG F M,YANG J,MA J N,et al. Optimization of structural parameters of an inner preheating transpiring-wall SCWO reactor . Chemical Engineering Research and Design,2019,141:372-387.
【10】AHLUWALIA K S. Internal platelet heat source and method of use in a supercritical water oxidation reactor:US 5571424 . 1996-11-05.
【11】HAROLDSEN B L,MILLS B E,ARIIZUMI D Y,et al. Transpiring wall supercritical water oxidation reactor salt deposition studies . :US department of Energy Office of Scientific and Technical Information,1996.
【12】LEE H C,IN J H,LEE S Y,et al. An anti-corrosive reactor for the decomposition of halogenated hydrocarbons with supercritical water oxidation . The Journal of Supercritical Fluids,2005,36(1):59-69.
【13】DIEUDÉ-FAUVEL E,HÉRITIER P,CHANET M,et al. Modelling the rheological properties of sludge during anaerobic digestion in a batch reactor by using electrical measurements . Water Research,2014,51:104-112.
【14】ABELN J,KLUTH M,PETRICH G,et al. Supercritical water oxidation (SCWO):a process for the treatment of industrial waste effluents . High Pressure Research,2001,20(1/2/3/4/5/6):537-547.
【15】ABELN J,KLUTH M,BÖTTCHER M,et al. Supercritical water oxidation (SCWO) using a transpiring wall reactor:CFD simulations and experimental results of ethanol oxidation . Environmental Engineering Science,2004,21(1):93-99.
【16】WELLIG B,LIEBALL K,VON ROHR P R. Operating characteristics of a transpiring-wall SCWO reactor with a hydrothermal flame as internal heat source . The Journal of Supercritical Fluids,2005,34(1):35-50.
【17】WELLIG B,LIEBALL K,VON ROHR P R,et al. Operating transpiring wall SCWO reactors:characteristics and quantitative aspects //Corrosion 2001,Houston,Texas:NACE International,2001.
【18】NARAYANAN C,FROUZAKIS C,BOULOUCHOS K,et al. Numerical modelling of a supercritical water oxidation reactor containing a hydrothermal flame . The Journal of Supercritical Fluids,2008,46(2):149-155.
【19】龚为进,李方,奚旦立. 超临界水氧化处理高浓度丙烯酸废水 . 化工环保,2007,27(5):413-416.
【20】XU D H,WANG S Z,GONG Y M,et al. A novel concept reactor design for preventing salt deposition in supercritical water . Chemical Engineering Research and Design,2010,88(11):1515-1522.
【21】CALZAVARA Y,JOUSSOT-DUBIEN C,TURC H A,et al. A new reactor concept for hydrothermal oxidation . The Journal of Supercritical Fluids,2004,31(2):195-206.
【22】CHEN Z,CHEN H Z,LIU X L,et al. An inclined plug-flow reactor design for supercritical water oxidation . Chemical Engineering Journal,2018,343:351-361.
【23】BAUR S,SCHMIDT H,KRÁMER A,et al. The destruction of industrial aqueous waste containing biocides in supercritical water-development of the SUWOX process for the technical application . The Journal of Supercritical Fluids,2005,33(2):149-157.
【24】HALFF A H,REID A F. Method for separation and removal of impurities from liquids:US 5372725 . 1994-12-13.
【2】廖玮,廖传华,朱廷风,等. 超临界水氧化技术在环境治理中的应用 . 印染助剂,2019,36(8):6-10.
【3】AL-DURI B,ALSOQYANI F,KINGS I. Supercritical water oxidation for the destruction of hazardous waste:better than incineration . Philosophical Transactions. Series A,Mathematical,Physical,and Engineering Sciences,2015,373(2057):20150013.
【4】廖玮,朱廷风,廖传华,等. 超临界水氧化技术在能量转化中的应用 . 水处理技术,2019,45(3):14-17.
【5】廖传华,朱跃钊,李永生. 超临界水氧化反应器的研究进展 . 环境工程,2010,28(2):7-12,23.
【6】邢军,于驰,詹世平,等. 连续式超临界水氧化反应器处理对苯甲酸模拟废水 . 资源节约与环保,2013(12):75,82.
【7】MUEGGENBURG H H,ROUSAR D C,YOUNG M F. Supercritical water oxidation reactor with wall conduits for boundary flow control:US5387398 . 1995-02-07.
【8】BERMEJO M D,MARTÍN Á,QUEIROZ J P S,et al. Computational fluid dynamics simulation of a transpiring wall reactor for supercritical water oxidation . Chemical Engineering Journal,2010,158(3):431-440.
【9】ZHANG F M,YANG J,MA J N,et al. Optimization of structural parameters of an inner preheating transpiring-wall SCWO reactor . Chemical Engineering Research and Design,2019,141:372-387.
【10】AHLUWALIA K S. Internal platelet heat source and method of use in a supercritical water oxidation reactor:US 5571424 . 1996-11-05.
【11】HAROLDSEN B L,MILLS B E,ARIIZUMI D Y,et al. Transpiring wall supercritical water oxidation reactor salt deposition studies . :US department of Energy Office of Scientific and Technical Information,1996.
【12】LEE H C,IN J H,LEE S Y,et al. An anti-corrosive reactor for the decomposition of halogenated hydrocarbons with supercritical water oxidation . The Journal of Supercritical Fluids,2005,36(1):59-69.
【13】DIEUDÉ-FAUVEL E,HÉRITIER P,CHANET M,et al. Modelling the rheological properties of sludge during anaerobic digestion in a batch reactor by using electrical measurements . Water Research,2014,51:104-112.
【14】ABELN J,KLUTH M,PETRICH G,et al. Supercritical water oxidation (SCWO):a process for the treatment of industrial waste effluents . High Pressure Research,2001,20(1/2/3/4/5/6):537-547.
【15】ABELN J,KLUTH M,BÖTTCHER M,et al. Supercritical water oxidation (SCWO) using a transpiring wall reactor:CFD simulations and experimental results of ethanol oxidation . Environmental Engineering Science,2004,21(1):93-99.
【16】WELLIG B,LIEBALL K,VON ROHR P R. Operating characteristics of a transpiring-wall SCWO reactor with a hydrothermal flame as internal heat source . The Journal of Supercritical Fluids,2005,34(1):35-50.
【17】WELLIG B,LIEBALL K,VON ROHR P R,et al. Operating transpiring wall SCWO reactors:characteristics and quantitative aspects //Corrosion 2001,Houston,Texas:NACE International,2001.
【18】NARAYANAN C,FROUZAKIS C,BOULOUCHOS K,et al. Numerical modelling of a supercritical water oxidation reactor containing a hydrothermal flame . The Journal of Supercritical Fluids,2008,46(2):149-155.
【19】龚为进,李方,奚旦立. 超临界水氧化处理高浓度丙烯酸废水 . 化工环保,2007,27(5):413-416.
【20】XU D H,WANG S Z,GONG Y M,et al. A novel concept reactor design for preventing salt deposition in supercritical water . Chemical Engineering Research and Design,2010,88(11):1515-1522.
【21】CALZAVARA Y,JOUSSOT-DUBIEN C,TURC H A,et al. A new reactor concept for hydrothermal oxidation . The Journal of Supercritical Fluids,2004,31(2):195-206.
【22】CHEN Z,CHEN H Z,LIU X L,et al. An inclined plug-flow reactor design for supercritical water oxidation . Chemical Engineering Journal,2018,343:351-361.
【23】BAUR S,SCHMIDT H,KRÁMER A,et al. The destruction of industrial aqueous waste containing biocides in supercritical water-development of the SUWOX process for the technical application . The Journal of Supercritical Fluids,2005,33(2):149-157.
【24】HALFF A H,REID A F. Method for separation and removal of impurities from liquids:US 5372725 . 1994-12-13.
相关信息
