环保型铝合金化学氧化工艺的研究进展
Research Progress of Chemical Oxidation Technology for Environment Friendly Aluminum Alloy
摘 要
铝合金化学氧化液中普遍采用六价铬酸盐。高污染且不易沉降的六价铬离子不仅给操作人员的健康造成危害,而且还严重污染环境,因此世界各国都在研发环保型铝合金化学氧化工艺。对国内外铝合金无六价铬化学氧化处理的研究现状进行了综述,分析了其发展前景。
化学氧化
无六价铬
环保工艺
aluminum alloy
chemical oxidation
hexavalent chromium free
environment friendly process
Abstract
Hexavalent chromate is commonly used in chemical oxidation solution of aluminum alloy. Hexavalent chromium ions with high pollution and not easy sedimentation not only cause harm to the health of operators, but also seriously pollute the environment. Therefore, countries all over the world are developing environmentally friendly aluminum alloy chemical oxidation process. The research status of hexavalent chromium free chemical oxidation treatment for aluminum alloys at home and abroad is reviewed, and its development prospects are analyzed.
中图分类号 TG172 DOI 10.11973/fsyfh-202208015
所属栏目 专论
基金项目
收稿日期 2020/9/6
修改稿日期
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引用该论文: HUANg,WANG Meifeng,LI Xiang,YE Xiufang,LENG Ying,WANG Xiayan. Research Progress of Chemical Oxidation Technology for Environment Friendly Aluminum Alloy[J]. Corrosion & Protection, 2022, 43(8): 75
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参考文献
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【3】王娇,郭瑞光.2024铝合金表面钒锆复合转化膜的制备及其性能 .材料保护,2014,47(3):1-4,68.
【4】SHIDA A,SUGIMURA H,FUTSUHARA M,et al.Zirconium-phosphate films self-assembled on aluminum substrate toward corrosion protection .Surface and Coatings Technology,2003,169/170:686-690.
【5】徐临超,陈贤杭,李勇.7075铝合金表面钼酸盐钝化工艺 .浙江工贸职业技术学院学报,2015,15(2):49-52.
【6】LIANG C S,LV Z F,ZHU Y L,et al.Protection of aluminium foil AA8021 by molybdate-based conversion coatings .Applied Surface Science,2014,288:497-502.
【7】XIA X F,GU Y Y,XU S A.Titanium conversion coatings on the aluminum foil AA 8021 used for lithium-ion battery package .Applied Surface Science,2017,419:447-453.
【8】LIU Q,CAO X M,DU A,et al.Investigation on adhesion strength and corrosion resistance of Ti-Zr aminotrimethylene phosphonic acid composite conversion coating on 7A52 aluminum alloy .Applied Surface Science,2018,458:350-359.
【9】ZUO X,LI W F,MU S L,et al.Investigation of composition and structure for a novel Ti-Zr chemical conversion coating on 6063 aluminum alloy .Progress in Organic Coatings,2015,87:61-68.
【10】郑辅养,丁洪波,温国谋.不同pH值下铝合金及其含锂转化层的抗蚀性能 .腐蚀与防护,2001,22(1):12-14.
【11】MARCOEN K,VISSER P,TRINDADE G F,et al.Compositional study of a corrosion protective layer formed by leachable lithium salts in a coating defect on AA2024-T3 aluminium alloys .Progress in Organic Coatings,2018,119:65-75.
【12】WANG D P,LI H S,LIU J,et al.Evaluation of AA5052 alloy anode in alkaline electrolyte with organic rare-earth complex additives for aluminium-air batteries .Journal of Power Sources,2015,293:484-491.
【13】VALDEZ B,KIYOTA S,STOYTCHEVA M,et al.Cerium-based conversion coatings to improve the corrosion resistance of aluminium alloy 6061-T6 .Corrosion Science,2014,87:141-149.
【14】YU X W,CAO C N,YAO Z M,et al.Study of double layer rare earth metal conversion coating on aluminum alloy LY12 .Corrosion Science,2001,43(7):1283-1294.
【15】KULINICH S A,AKHTAR A S,WONG P C,et al.Growth of permanganate conversion coating on 2024-Al alloy .Thin Solid Films,2007,515(23):8386-8392.
【16】YOGANANDAN G,BALARAJU J N,WILLIAM GRIPS V K.The surface and electrochemical analysis of permanganate based conversion coating on alclad and unclad 2024 alloy .Applied Surface Science,2012,258(22):8880-8888.
【17】GUO Y,FRANKEL G S.Characterization of trivalent chromium process coating on AA2024-T3 .Surface and Coatings Technology,2012,206(19/20):3895-3902.
【18】VIROULAUD R,ŚWIATOWSKA J,SEYEUX A,et al.Influence of surface pretreatments on the quality of trivalent chromium process coatings on aluminum alloy .Applied Surface Science,2017,423:927-938.
【19】CHEN W K,BAI C Y,LIU C M,et al.The effect of chromic sulfate concentration and immersion time on the structures and anticorrosive performance of the Cr(III) conversion coatings on aluminum alloys .Applied Surface Science,2010,256(16):4924-4929.
【20】CHEN W K,LEE J L,BAI C Y,et al.Growth and characteristics of Cr(III)-based conversion coating on aluminum alloy .Journal of the Taiwan Institute of Chemical Engineers,2012,43(6):989-995.
【21】YU H C,HUANG X Y,LEI F H,et al.Preparation and electrochemical properties of Cr(III)-Ti-based coatings on 6063 Al alloy .Surface and Coatings Technology,2013,218:137-141.
【22】STOICA A I,ŚWIATOWSKA J,ROMAINE A,et al.Influence of post-treatment time of trivalent chromium protection coating on aluminium alloy 2024-T3 on improved corrosion resistance .Surface and Coatings Technology,2019,369:186-197.
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