海水痕量金属元素分析中前处理技术的研究进展
Research Progress of Pretreatment Technology for Analysis of Trace Metal Elements in Seawater
摘 要
痕量金属元素在海洋生态系统中发挥着不可或缺的作用，准确测定海洋中的痕量金属元素对海洋生态系统的结构和功能有重要意义。为降低海水基体效应，提高测定准确度，综述了海水痕量金属元素分析中的前处理技术，包括螯合-溶剂萃取法、共沉淀法、稀释-直接进样法、氩气在线稀释法和基于螯合树脂的固相萃取法，比较了各方法的优劣和适用性，并对该领域的发展趋势进行了展望（引用文献75篇）。
痕量金属元素
前处理
电感耦合等离子体质谱法
seawater
trace metal element
pretreatment
inductively coupled plasma mass spectrometry
Abstract
Trace metal elements are indispensable in marine ecosystem. Accurate determination of trace metal elements in seawater is of great significance to the structure and function of marine ecosystem. In order to reduce the matrix effect of seawater and improve the detemination accuracy, the pretreatment techniques for analysis of trace metal elements in seawater were reviewed, including chelation-solvent extraction, co-precipitation, dilution-direct injection, argon gas online dilution and solid phase extraction based on chelating resin. The advantages and disadvantages of these methods and their applicability were compared, and the development trend in this field was prospected (75 ref. cited).
中图分类号 O65 DOI 10.11973/lhjy-hx202210021
所属栏目 综述
基金项目 国家重大科学仪器设备开发专项（2017YFF0108203）
收稿日期 2021/6/22
修改稿日期
网络出版日期
作者单位点击查看
备注胡建坤,高级工程师,博士研究生,主要从事分析仪器研发、能源和环保研究,jiankun_hu@fpi-inc.com
引用该论文: HU Jiankun,HAN Shuanglai,LU Shuimiao,YOU Minghua,CAO Yanlong. Research Progress of Pretreatment Technology for Analysis of Trace Metal Elements in Seawater[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2022, 58(10): 1232～1240
胡建坤,韩双来,卢水淼,游明华,曹衍龙. 海水痕量金属元素分析中前处理技术的研究进展[J]. 理化检验－化学分册, 2022, 58(10): 1232～1240
共有人对该论文发表了看法，其中：
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】BRULAND K W, LOHAN M C. Controls of trace metals in seawater[M]//HOLLAND H D, TUREKIAN K K. Treatise on geochemistry. Amsterdam:Elsevier, 2003:23-47.
【2】郑辰禾.海水微型生物与颗粒物痕量元素组成动态变化及主控因素分析[D].厦门:厦门大学, 2017.
【3】MOREL F M M, PRICE N M. The biogeochemical cycles of trace metals in the oceans[J]. Science, 2003,300(5621):944-947.
【4】WATSON A J, BAKKER D C E, RIDGWELL A J, et al. Effect of iron supply on Southern Ocean CO2 uptake and implications for glacial atmospheric CO2[J]. Nature, 2000,407(6805):730-733.
【5】刘慧杰,刘文君,刘继平,等.南中国海表层海水重金属含量及其潜在生态风险分析[J].中国环境科学, 2017,37(10):3891-3898.
【6】SOHRIN Y, BRULAND K W. Global status of trace elements in the ocean[J]. TrAC Trends in Analytical Chemistry, 2011,30(8):1291-1307.
【7】荆淼,沈阳,沈金灿,等.应用带八级杆碰撞/反应池(ORS)的电感耦合等离子体质谱(ICP-MS)同时测定大洋海水中的痕量元素[J].环境化学, 2004,23(5):600-604.
【8】刘莹,翟世奎,张爱滨,等.ICP-MS测定海水中溶解态痕量重金属——直接稀释法[J].海洋学报(中文版), 2008,30(5):151-158.
【9】BRULAND K W, FRANKS R P, KNAUER G A, et al. Sampling and analytical methods for the determination of copper, cadmium, zinc, and nickel at the nanogram per liter level in sea water[J]. Analytica Chimica Acta, 1979,105:233-245.
【10】ZHANG J, XU H, REN J L. Fluorimetric determination of dissolved aluminium in natural waters after liquid-liquid extraction into n-hexanol[J]. Analytica Chimica Acta, 2000,405(1/2):31-42.
【11】刘伟,宋金明,袁华茂,等.Mg(OH)2共沉淀和直接稀释联用ICP-MS法准确测定海水中的多种常量-微量元素[J].分析测试学报, 2017,36(4):471-477.
【12】ZENG C J, YAN Y Y, TANG J, et al. Speciation of Arsenic(Ⅲ) and Arsenic(V) based on Triton X-100 hollow fiber liquid phase microextraction coupled with flame atomic absorption spectrometry[J]. Spectroscopy Letters, 2017,50(4):220-226.
【13】ELÇI L, ŞAHIN U, ÖZTAŞ S. Determination of trace amounts of some metals in samples with high salt content by atomic absorption spectrometry after cobalt-diethyldithiocarbamate coprecipitation[J]. Talanta, 1997,44(6):1017-1023.
【14】LLAVER M, CORONADO E A, WUILLOUD R G. High performance preconcentration of inorganic Se species by dispersive micro-solid phase extraction with a nanosilica-ionic liquid hybrid material[J]. Spectrochimica Acta Part B:Atomic Spectroscopy, 2017,138:23-30.
【15】SUN R, MA G, DUAN X, et al. Determination of cadmium in seawater by chelate vapor generation atomic fluorescence spectrometry[J]. Spectrochimica Acta Part B:Atomic Spectroscopy, 2018,141:22-27.
【16】苏耀东,李静,黄燕,等.应用内标的APDC-Cu(Ⅱ)快速共沉淀分离富集和原子吸收光谱测定食盐中的铅[J].光谱学与光谱分析, 2006,26(3):564-566.
【17】陈瑛娜,王增焕,谷阳光,等.无载体离子有机共沉淀分离-石墨炉原子吸收光谱法测定海水中铜铅铬镍[J].分析试验室, 2018,37(10):1179-1182.
【18】苏耀东,黄燕,郝冰冰,等.吡咯烷二硫代氨基甲酸铵-Ni(Ⅱ)快速共沉淀分离富集和原子吸收光谱法测定痕量铜、铅和镉[J].分析科学学报, 2007,23(2):173-176.
【19】肖红玺,苏耀东,王玉科,等.共沉淀分离富集原子吸收光谱法测定氯化物中痕量镉[J].理化检验-化学分册, 2003,39(1):18-19.
【20】祝旭初,谷颖.共沉淀-微量进样火焰原子吸收光谱法测定海水中铁和锰[J].理化检验-化学分册, 2008,44(7):681-682.
【21】ARSLAN Z, OYMAK T, WHITE J. Triethylamine-assisted Mg(OH)2 coprecipitation/preconcentration for determination of trace metals and rare earth elements in seawater by inductively coupled plasma mass spectrometry (ICP-MS)[J]. Analytica Chimica Acta, 2018,1008:18-28.
【22】ARL B, CAN S Z, BAKLRDERE S. Traceable and accurate quantification of iron in seawater using isotope dilution calibration strategies by triple quadrupole ICP-MS/MS:Characterization measurements of iron in a candidate seawater CRM[J]. Talanta, 2020,209:120503.
【23】WU J F. Determination of picomolar iron in seawater by double Mg(OH)2 precipitation isotope dilution high-resolution ICPMS[J]. Marine Chemistry, 2007,103(3/4):370-381.
【24】WU J F, BOYLE E A. Determination of iron in seawater by high-resolution isotope dilution inductively coupled plasma mass spectrometry after Mg(OH)2 coprecipitation[J]. Analytica Chimica Acta, 1998,367(1/2/3):183-191.
【25】SAITO M A, SCHNEIDER D L. Examination of precipitation chemistry and improvements in precision using the Mg(OH)2 preconcentration inductively coupled plasma mass spectrometry (ICP-MS) method for high-throughput analysis of open-ocean Fe and Mn in seawater[J]. Analytica Chimica Acta, 2006,565(2):222-233.
【26】WU J F, BOYLE E A. Low blank preconcentration technique for the determination of lead, copper, and cadmium in small-volume seawater samples by isotope dilution ICPMS[J]. Analytical Chemistry, 1997,69(13):2464-2470.
【27】林杰,洪华生,庄峙厦.Co-APDC共沉淀预富集、石墨炉原子吸收分光光度法测定海水中铜、镍、镉[J].海洋环境科学, 1988,7(2):63-68.
【28】CUTTER G, ANDERSSON P, CODISPOTI L, et al. Sampling and sample-handling protocols for GEOTRACES cruises.[2021-06-20]. https://www.geotraces.org/methods-cookbook.
【29】DONG J, LI B W, BAO Q. In situ reactive zone with modified Mg(OH)2 for remediation of heavy metal polluted groundwater:Immobilization and interaction of Cr(Ⅲ), Pb(Ⅱ) and Cd(Ⅱ)[J]. Journal of Contaminant Hydrology, 2017,199:50-57.
【30】DAVIDSON A B, SEMENIUK D M, KOH J, et al. A Mg(OH)2 coprecipitation method for determining chromium speciation and isotopic composition in seawater[J]. Limnology and Oceanography:Methods, 2020,18(1):8-19.
【31】MA X L, DUAN M S, DUAN D M, et al.A study on comprehensive evaluation of multiple-depth sea water quality in the South China sea[J]. IOP Conference Series:Earth and Environmental Science, 2021,809(1):12013.
【32】王静,王鑫,耿哲,等.碰撞池-电感耦合等离子体质谱测定海水重金属[J].环境工程学报, 2016,10(4):2139-2143.
【33】钟跃汉,王利华,孙友宝,等.ICP-MS微量进样法直接测定海水中微量元素的含量[J].环境化学, 2018,37(10):2329-2331.
【34】LI S Z, GAO Y. Direct determination of trace lead in seawater by inductively coupled plasma mass spectrometry after photochemical vapor generation[J]. Atomic Spectroscopy, 2017,38(3):37-43.
【35】卢水淼,邱明,李剑,等.六极杆碰撞反应池-ICP-MS法测定海水中痕量金属元素[J].化学分析计量, 2016,25(6):13-16.
【36】RATHOD T D, TIWARI M, MAITY S, et al. Multi-element detection in sea water using preconcentration procedure and EDXRF technique[J]. Applied Radiation and Isotopes, 2018,135:57-60.
【37】杨红霞,曹为,荆淼,等.氩气稀释(AGD)-电感耦合等离子体质谱(ICP-MS)技术直接分析高盐样品中痕量元素[J].环境化学, 2014,33(11):2014-2016.
【38】李鹰,俞晓峰,李剑,等.氩气在线稀释-电感耦合等离子体质谱法直接测定饱和食盐水中总砷[J].理化检验-化学分册, 2018,54(9):1088-1091.
【39】郭雪松,商琳.氩气在线稀释/ICP-MS测定纺织品中可迁移金属元素[J].印染, 2019,45(4):48-51.
【40】SUZUKI Y. Flow analytical systems for the determination of components in seawater[J]. Bulletin of the Society of Sea Water Science, 2007,61:253-259.
【41】LIU K, GAO X L, LI L, et al. Determination of ultra-trace Pt, Pd and Rh in seawater using an off-line pre-concentration method and inductively coupled plasma mass spectrometry[J]. Chemosphere, 2018,212:429-437.
【42】XING G W, SARDAR M R, LIN B X, et al. Analysis of trace metals in water samples using NOBIAS chelate resins by HPLC and ICP-MS[J]. Talanta, 2019,204:50-56.
【43】FEI J J, ZHAO L Y, WU X H, et al. In-tube solid-phase microextraction with a hybrid monolithic column for the preconcentration of ultra-trace metals prior to simultaneous determination by ICP-MS[J]. Mikrochimica Acta, 2020,187(6):356-365.
【44】MASSADEH A M, EL-RJOOB A W O, GHARAIBEH S A. Analysis of selected heavy metals in tap water by inductively coupled plasma-optical emission spectrometry after pre-concentration using chelex-100 ion exchange resin[J]. Water, Air, & Soil Pollution, 2020,231(5):1-14.
【45】GE H Y, CHEN D, LI S, et al. Determination of Fe, Ti in seawater using a flow-injection pretreatment system with ICP-MS[J]. Journal of Coastal Research, 2019,93(S1):77-82.
【46】HUNG J J, YEH H Y, PENG S H, et al. Influence of submarine hydrothermalism on sulfur and metal accumulation in surface sediments in the Kueishantao venting field off northeastern Taiwan[J]. Marine Chemistry, 2018,198:88-96.
【47】HUNTSMAN-MAPILA P, SKEAFF J M, PAWLAK M, et al. Addressing aquatic hazard classification for metals,metal compounds and alloys in marine systems[J]. Marine Pollution Bulletin, 2016,109(1):550-557.
【48】BONIFORTI R, FERRAROLI R, FRIGIERI P, et al. Intercomparison of five methods for the determination of trace metals in sea water[J]. Analytica Chimica Acta, 1984,162:33-46.
【49】RILEY J P, TAYLOR D. Chelating resins for the concentration of trace elements from sea water and their analytical use in conjunction with atomic absorption spectrophotometry[J]. Analytica Chimica Acta, 1968,40:479-485.
【50】ZHOU C Y, VAN DE VELDE S, BAEYENS W, et al. Comparison of Chelex based resins in diffusive gradients in thin-film for high resolution assessment of metals[J]. Talanta, 2018,186:397-405.
【51】AMARA-REKKAB A, DIDI M. Selective liquid-solid extraction of Cr(Ⅲ) from Cr(Ⅲ) and Fe(Ⅲ) mixture by Chelex 100 resin[J]. Scientific Study and Research:Chemistry and Chemical Engineering, 2019,20(1):63-74.
【52】PAI S C, FANG T H, CHEN C T A, et al. A low contamination Chelex-100 technique for shipboard pre-concentration of heavy metals in seawater[J]. Marine Chemistry, 1990,29:295-306.
【53】GROTTI M, ABELMOSCHI M L, SOGGIA F, et al. Determination of ultratrace elements in natural waters by solid-phase extraction and atomic spectrometry methods[J]. Analytical and Bioanalytical Chemistry, 2003,375(2):242-247.
【54】HO T Y, CHIEN C T, WANG B N, et al. Determination of trace metals in seawater by an automated flow injection ion chromatograph pretreatment system with ICP-MS[J]. Talanta, 2010,82(4):1478-1484.
【55】ZHU Z H, ZHENG A R. Fast determination of yttrium and rare earth elements in seawater by inductively coupled plasma-mass spectrometry after online flow injection pretreatment[J]. Molecules, 2018,23(2):489-501.
【56】WARNKEN K W, TANG D G, GILL G A, et al. Performance optimization of a commercially available iminodiacetate resin for the determination of Mn, Ni, Cu, Cd and Pb by on-line preconcentration inductively coupled plasma-mass spectrometry[J]. Analytica Chimica Acta, 2000,423(2):265-276.
【57】OLIVEIRA E P, YANG L, STURGEON R E, et al. Determination of trace metals in high-salinity petroleum produced formation water by inductively coupled plasma mass spectrometry following on-line analyte separation/preconcentration[J]. Journal of Analytical Atomic Spectrometry, 2011,26(3):578-585.
【58】LONG S E, MARTIN T D. Determination of trace elements in marine waters by on-line chelation preconcentration and inductively coupled plasma-mass spectrometry[M]//Environmental Monitoring Systems Laboratory. Methods for the determination of metals in environmental samples. Amsterdam:Elsevier, 1996:187-209.
【59】LEE J M, BOYLE E A, ECHEGOYEN-SANZ Y, et al. Analysis of trace metals (Cu, Cd, Pb, and Fe) in seawater using single batch nitrilotriacetate resin extraction and isotope dilution inductively coupled plasma mass spectrometry[J]. Analytica Chimica Acta, 2011,686(1/2):93-101.
【60】HUANG Y M, XU J, CHEN L D, et al. Flow injection analysis method with on-line resin separation for determining trace Fe(Ⅱ) and Fe(Ⅱ+Ⅲ) using catalytic spectrophotometry[J]. Microchemical Journal, 2021,162:105840.
【61】LOHAN M C, AGUILAR-ISLAS A M, FRANKS R P, et al. Determination of iron and copper in seawater at pH 1.7 with a new commercially available chelating resin, NTA Superflow[J]. Analytica Chimica Acta, 2005,530(1):121-129.
【62】EVANS L K, NISHIOKA J. Quantitative analysis of Fe, Mn and Cd from sea ice and seawater in the Chukchi Sea, Arctic Ocean[J]. Polar Science, 2018,17:50-58.
【63】WANG B S, LEE C P, HO T Y. Trace metal determination in natural waters by automated solid phase extraction system and ICP-MS:The influence of low level Mg and Ca[J]. Talanta, 2014,128:337-344.
【64】WUTTIG K, TOWNSEND A T, VAN DER MERWE P, et al. Critical evaluation of a seaFAST system for the analysis of trace metals in marine samples[J]. Talanta, 2019,197:653-668.
【65】谭赛章,张昊飞,吴康康,等.自动化树脂分离富集装置与ICP-MS联用在海水痕量金属元素分析中的应用[J].上海海洋大学学报, 2019,28(5):662-670.
【66】RAPP I, SCHLOSSER C, RUSIECKA D, et al. Automated preconcentration of Fe, Zn, Cu, Ni, Cd, Pb, Co, and Mn in seawater with analysis using high-resolution sector field inductively-coupled plasma mass spectrometry[J]. Analytica Chimica Acta, 2017,976:1-13.
【67】FISCHER L, HANN S, WORSFOLD P J, et al. On-line sample treatment coupled with atomic spectrometric detection for the determination of trace elements in natural waters[J]. Journal of Analytical Atomic Spectrometry, 2020,35(4):643-670.
【68】黄志勇,陈发荣,庄峙厦,等.微柱流动注射同位素稀释电感耦合等离子体质谱法测定海水中的痕量铅[J].分析科学学报, 2003,19(4):301-304.
【69】李发明.在线富集-流动注射测定溶解态铝的方法及其在中国陆架边缘海中的应用[D].青岛:中国海洋大学, 2015.
【70】吴冬梅,胡城翠.新型螯合树脂在线预富集测定海水中痕量Cd[J].分析试验室, 2008,27(9):18-21.
【71】PAN F, ZHU R L, HAN H T, et al. Flow-injection analysis (FIA) electrochemical speciation of copper in coastal waters by anodic stripping voltammetry (ASV)[J]. Analytical Letters, 2021,54(11):1858-1870.
【72】FENG S C, YUAN D X, HUANG Y M, et al. A catalytic spectrophotometric method for determination of nanomolar manganese in seawater using reverse flow injection analysis and a long path length liquid waveguide capillary cell[J]. Talanta, 2018,178:577-582.
【73】马莉.在线浓缩-流动注射分光光度法测定海水中痕量Cd(Ⅱ)和Cu(Ⅱ)的方法研究[D].成都:四川大学, 2006.
【74】母清林,方杰,佘运勇,等.在线稀释/预浓缩-电感耦合等离子体质谱法分析海水中11种痕量元素[J].分析化学, 2015,43(9):1360-1365.
【2】郑辰禾.海水微型生物与颗粒物痕量元素组成动态变化及主控因素分析[D].厦门:厦门大学, 2017.
【3】MOREL F M M, PRICE N M. The biogeochemical cycles of trace metals in the oceans[J]. Science, 2003,300(5621):944-947.
【4】WATSON A J, BAKKER D C E, RIDGWELL A J, et al. Effect of iron supply on Southern Ocean CO2 uptake and implications for glacial atmospheric CO2[J]. Nature, 2000,407(6805):730-733.
【5】刘慧杰,刘文君,刘继平,等.南中国海表层海水重金属含量及其潜在生态风险分析[J].中国环境科学, 2017,37(10):3891-3898.
【6】SOHRIN Y, BRULAND K W. Global status of trace elements in the ocean[J]. TrAC Trends in Analytical Chemistry, 2011,30(8):1291-1307.
【7】荆淼,沈阳,沈金灿,等.应用带八级杆碰撞/反应池(ORS)的电感耦合等离子体质谱(ICP-MS)同时测定大洋海水中的痕量元素[J].环境化学, 2004,23(5):600-604.
【8】刘莹,翟世奎,张爱滨,等.ICP-MS测定海水中溶解态痕量重金属——直接稀释法[J].海洋学报(中文版), 2008,30(5):151-158.
【9】BRULAND K W, FRANKS R P, KNAUER G A, et al. Sampling and analytical methods for the determination of copper, cadmium, zinc, and nickel at the nanogram per liter level in sea water[J]. Analytica Chimica Acta, 1979,105:233-245.
【10】ZHANG J, XU H, REN J L. Fluorimetric determination of dissolved aluminium in natural waters after liquid-liquid extraction into n-hexanol[J]. Analytica Chimica Acta, 2000,405(1/2):31-42.
【11】刘伟,宋金明,袁华茂,等.Mg(OH)2共沉淀和直接稀释联用ICP-MS法准确测定海水中的多种常量-微量元素[J].分析测试学报, 2017,36(4):471-477.
【12】ZENG C J, YAN Y Y, TANG J, et al. Speciation of Arsenic(Ⅲ) and Arsenic(V) based on Triton X-100 hollow fiber liquid phase microextraction coupled with flame atomic absorption spectrometry[J]. Spectroscopy Letters, 2017,50(4):220-226.
【13】ELÇI L, ŞAHIN U, ÖZTAŞ S. Determination of trace amounts of some metals in samples with high salt content by atomic absorption spectrometry after cobalt-diethyldithiocarbamate coprecipitation[J]. Talanta, 1997,44(6):1017-1023.
【14】LLAVER M, CORONADO E A, WUILLOUD R G. High performance preconcentration of inorganic Se species by dispersive micro-solid phase extraction with a nanosilica-ionic liquid hybrid material[J]. Spectrochimica Acta Part B:Atomic Spectroscopy, 2017,138:23-30.
【15】SUN R, MA G, DUAN X, et al. Determination of cadmium in seawater by chelate vapor generation atomic fluorescence spectrometry[J]. Spectrochimica Acta Part B:Atomic Spectroscopy, 2018,141:22-27.
【16】苏耀东,李静,黄燕,等.应用内标的APDC-Cu(Ⅱ)快速共沉淀分离富集和原子吸收光谱测定食盐中的铅[J].光谱学与光谱分析, 2006,26(3):564-566.
【17】陈瑛娜,王增焕,谷阳光,等.无载体离子有机共沉淀分离-石墨炉原子吸收光谱法测定海水中铜铅铬镍[J].分析试验室, 2018,37(10):1179-1182.
【18】苏耀东,黄燕,郝冰冰,等.吡咯烷二硫代氨基甲酸铵-Ni(Ⅱ)快速共沉淀分离富集和原子吸收光谱法测定痕量铜、铅和镉[J].分析科学学报, 2007,23(2):173-176.
【19】肖红玺,苏耀东,王玉科,等.共沉淀分离富集原子吸收光谱法测定氯化物中痕量镉[J].理化检验-化学分册, 2003,39(1):18-19.
【20】祝旭初,谷颖.共沉淀-微量进样火焰原子吸收光谱法测定海水中铁和锰[J].理化检验-化学分册, 2008,44(7):681-682.
【21】ARSLAN Z, OYMAK T, WHITE J. Triethylamine-assisted Mg(OH)2 coprecipitation/preconcentration for determination of trace metals and rare earth elements in seawater by inductively coupled plasma mass spectrometry (ICP-MS)[J]. Analytica Chimica Acta, 2018,1008:18-28.
【22】ARL B, CAN S Z, BAKLRDERE S. Traceable and accurate quantification of iron in seawater using isotope dilution calibration strategies by triple quadrupole ICP-MS/MS:Characterization measurements of iron in a candidate seawater CRM[J]. Talanta, 2020,209:120503.
【23】WU J F. Determination of picomolar iron in seawater by double Mg(OH)2 precipitation isotope dilution high-resolution ICPMS[J]. Marine Chemistry, 2007,103(3/4):370-381.
【24】WU J F, BOYLE E A. Determination of iron in seawater by high-resolution isotope dilution inductively coupled plasma mass spectrometry after Mg(OH)2 coprecipitation[J]. Analytica Chimica Acta, 1998,367(1/2/3):183-191.
【25】SAITO M A, SCHNEIDER D L. Examination of precipitation chemistry and improvements in precision using the Mg(OH)2 preconcentration inductively coupled plasma mass spectrometry (ICP-MS) method for high-throughput analysis of open-ocean Fe and Mn in seawater[J]. Analytica Chimica Acta, 2006,565(2):222-233.
【26】WU J F, BOYLE E A. Low blank preconcentration technique for the determination of lead, copper, and cadmium in small-volume seawater samples by isotope dilution ICPMS[J]. Analytical Chemistry, 1997,69(13):2464-2470.
【27】林杰,洪华生,庄峙厦.Co-APDC共沉淀预富集、石墨炉原子吸收分光光度法测定海水中铜、镍、镉[J].海洋环境科学, 1988,7(2):63-68.
【28】CUTTER G, ANDERSSON P, CODISPOTI L, et al. Sampling and sample-handling protocols for GEOTRACES cruises.[2021-06-20]. https://www.geotraces.org/methods-cookbook.
【29】DONG J, LI B W, BAO Q. In situ reactive zone with modified Mg(OH)2 for remediation of heavy metal polluted groundwater:Immobilization and interaction of Cr(Ⅲ), Pb(Ⅱ) and Cd(Ⅱ)[J]. Journal of Contaminant Hydrology, 2017,199:50-57.
【30】DAVIDSON A B, SEMENIUK D M, KOH J, et al. A Mg(OH)2 coprecipitation method for determining chromium speciation and isotopic composition in seawater[J]. Limnology and Oceanography:Methods, 2020,18(1):8-19.
【31】MA X L, DUAN M S, DUAN D M, et al.A study on comprehensive evaluation of multiple-depth sea water quality in the South China sea[J]. IOP Conference Series:Earth and Environmental Science, 2021,809(1):12013.
【32】王静,王鑫,耿哲,等.碰撞池-电感耦合等离子体质谱测定海水重金属[J].环境工程学报, 2016,10(4):2139-2143.
【33】钟跃汉,王利华,孙友宝,等.ICP-MS微量进样法直接测定海水中微量元素的含量[J].环境化学, 2018,37(10):2329-2331.
【34】LI S Z, GAO Y. Direct determination of trace lead in seawater by inductively coupled plasma mass spectrometry after photochemical vapor generation[J]. Atomic Spectroscopy, 2017,38(3):37-43.
【35】卢水淼,邱明,李剑,等.六极杆碰撞反应池-ICP-MS法测定海水中痕量金属元素[J].化学分析计量, 2016,25(6):13-16.
【36】RATHOD T D, TIWARI M, MAITY S, et al. Multi-element detection in sea water using preconcentration procedure and EDXRF technique[J]. Applied Radiation and Isotopes, 2018,135:57-60.
【37】杨红霞,曹为,荆淼,等.氩气稀释(AGD)-电感耦合等离子体质谱(ICP-MS)技术直接分析高盐样品中痕量元素[J].环境化学, 2014,33(11):2014-2016.
【38】李鹰,俞晓峰,李剑,等.氩气在线稀释-电感耦合等离子体质谱法直接测定饱和食盐水中总砷[J].理化检验-化学分册, 2018,54(9):1088-1091.
【39】郭雪松,商琳.氩气在线稀释/ICP-MS测定纺织品中可迁移金属元素[J].印染, 2019,45(4):48-51.
【40】SUZUKI Y. Flow analytical systems for the determination of components in seawater[J]. Bulletin of the Society of Sea Water Science, 2007,61:253-259.
【41】LIU K, GAO X L, LI L, et al. Determination of ultra-trace Pt, Pd and Rh in seawater using an off-line pre-concentration method and inductively coupled plasma mass spectrometry[J]. Chemosphere, 2018,212:429-437.
【42】XING G W, SARDAR M R, LIN B X, et al. Analysis of trace metals in water samples using NOBIAS chelate resins by HPLC and ICP-MS[J]. Talanta, 2019,204:50-56.
【43】FEI J J, ZHAO L Y, WU X H, et al. In-tube solid-phase microextraction with a hybrid monolithic column for the preconcentration of ultra-trace metals prior to simultaneous determination by ICP-MS[J]. Mikrochimica Acta, 2020,187(6):356-365.
【44】MASSADEH A M, EL-RJOOB A W O, GHARAIBEH S A. Analysis of selected heavy metals in tap water by inductively coupled plasma-optical emission spectrometry after pre-concentration using chelex-100 ion exchange resin[J]. Water, Air, & Soil Pollution, 2020,231(5):1-14.
【45】GE H Y, CHEN D, LI S, et al. Determination of Fe, Ti in seawater using a flow-injection pretreatment system with ICP-MS[J]. Journal of Coastal Research, 2019,93(S1):77-82.
【46】HUNG J J, YEH H Y, PENG S H, et al. Influence of submarine hydrothermalism on sulfur and metal accumulation in surface sediments in the Kueishantao venting field off northeastern Taiwan[J]. Marine Chemistry, 2018,198:88-96.
【47】HUNTSMAN-MAPILA P, SKEAFF J M, PAWLAK M, et al. Addressing aquatic hazard classification for metals,metal compounds and alloys in marine systems[J]. Marine Pollution Bulletin, 2016,109(1):550-557.
【48】BONIFORTI R, FERRAROLI R, FRIGIERI P, et al. Intercomparison of five methods for the determination of trace metals in sea water[J]. Analytica Chimica Acta, 1984,162:33-46.
【49】RILEY J P, TAYLOR D. Chelating resins for the concentration of trace elements from sea water and their analytical use in conjunction with atomic absorption spectrophotometry[J]. Analytica Chimica Acta, 1968,40:479-485.
【50】ZHOU C Y, VAN DE VELDE S, BAEYENS W, et al. Comparison of Chelex based resins in diffusive gradients in thin-film for high resolution assessment of metals[J]. Talanta, 2018,186:397-405.
【51】AMARA-REKKAB A, DIDI M. Selective liquid-solid extraction of Cr(Ⅲ) from Cr(Ⅲ) and Fe(Ⅲ) mixture by Chelex 100 resin[J]. Scientific Study and Research:Chemistry and Chemical Engineering, 2019,20(1):63-74.
【52】PAI S C, FANG T H, CHEN C T A, et al. A low contamination Chelex-100 technique for shipboard pre-concentration of heavy metals in seawater[J]. Marine Chemistry, 1990,29:295-306.
【53】GROTTI M, ABELMOSCHI M L, SOGGIA F, et al. Determination of ultratrace elements in natural waters by solid-phase extraction and atomic spectrometry methods[J]. Analytical and Bioanalytical Chemistry, 2003,375(2):242-247.
【54】HO T Y, CHIEN C T, WANG B N, et al. Determination of trace metals in seawater by an automated flow injection ion chromatograph pretreatment system with ICP-MS[J]. Talanta, 2010,82(4):1478-1484.
【55】ZHU Z H, ZHENG A R. Fast determination of yttrium and rare earth elements in seawater by inductively coupled plasma-mass spectrometry after online flow injection pretreatment[J]. Molecules, 2018,23(2):489-501.
【56】WARNKEN K W, TANG D G, GILL G A, et al. Performance optimization of a commercially available iminodiacetate resin for the determination of Mn, Ni, Cu, Cd and Pb by on-line preconcentration inductively coupled plasma-mass spectrometry[J]. Analytica Chimica Acta, 2000,423(2):265-276.
【57】OLIVEIRA E P, YANG L, STURGEON R E, et al. Determination of trace metals in high-salinity petroleum produced formation water by inductively coupled plasma mass spectrometry following on-line analyte separation/preconcentration[J]. Journal of Analytical Atomic Spectrometry, 2011,26(3):578-585.
【58】LONG S E, MARTIN T D. Determination of trace elements in marine waters by on-line chelation preconcentration and inductively coupled plasma-mass spectrometry[M]//Environmental Monitoring Systems Laboratory. Methods for the determination of metals in environmental samples. Amsterdam:Elsevier, 1996:187-209.
【59】LEE J M, BOYLE E A, ECHEGOYEN-SANZ Y, et al. Analysis of trace metals (Cu, Cd, Pb, and Fe) in seawater using single batch nitrilotriacetate resin extraction and isotope dilution inductively coupled plasma mass spectrometry[J]. Analytica Chimica Acta, 2011,686(1/2):93-101.
【60】HUANG Y M, XU J, CHEN L D, et al. Flow injection analysis method with on-line resin separation for determining trace Fe(Ⅱ) and Fe(Ⅱ+Ⅲ) using catalytic spectrophotometry[J]. Microchemical Journal, 2021,162:105840.
【61】LOHAN M C, AGUILAR-ISLAS A M, FRANKS R P, et al. Determination of iron and copper in seawater at pH 1.7 with a new commercially available chelating resin, NTA Superflow[J]. Analytica Chimica Acta, 2005,530(1):121-129.
【62】EVANS L K, NISHIOKA J. Quantitative analysis of Fe, Mn and Cd from sea ice and seawater in the Chukchi Sea, Arctic Ocean[J]. Polar Science, 2018,17:50-58.
【63】WANG B S, LEE C P, HO T Y. Trace metal determination in natural waters by automated solid phase extraction system and ICP-MS:The influence of low level Mg and Ca[J]. Talanta, 2014,128:337-344.
【64】WUTTIG K, TOWNSEND A T, VAN DER MERWE P, et al. Critical evaluation of a seaFAST system for the analysis of trace metals in marine samples[J]. Talanta, 2019,197:653-668.
【65】谭赛章,张昊飞,吴康康,等.自动化树脂分离富集装置与ICP-MS联用在海水痕量金属元素分析中的应用[J].上海海洋大学学报, 2019,28(5):662-670.
【66】RAPP I, SCHLOSSER C, RUSIECKA D, et al. Automated preconcentration of Fe, Zn, Cu, Ni, Cd, Pb, Co, and Mn in seawater with analysis using high-resolution sector field inductively-coupled plasma mass spectrometry[J]. Analytica Chimica Acta, 2017,976:1-13.
【67】FISCHER L, HANN S, WORSFOLD P J, et al. On-line sample treatment coupled with atomic spectrometric detection for the determination of trace elements in natural waters[J]. Journal of Analytical Atomic Spectrometry, 2020,35(4):643-670.
【68】黄志勇,陈发荣,庄峙厦,等.微柱流动注射同位素稀释电感耦合等离子体质谱法测定海水中的痕量铅[J].分析科学学报, 2003,19(4):301-304.
【69】李发明.在线富集-流动注射测定溶解态铝的方法及其在中国陆架边缘海中的应用[D].青岛:中国海洋大学, 2015.
【70】吴冬梅,胡城翠.新型螯合树脂在线预富集测定海水中痕量Cd[J].分析试验室, 2008,27(9):18-21.
【71】PAN F, ZHU R L, HAN H T, et al. Flow-injection analysis (FIA) electrochemical speciation of copper in coastal waters by anodic stripping voltammetry (ASV)[J]. Analytical Letters, 2021,54(11):1858-1870.
【72】FENG S C, YUAN D X, HUANG Y M, et al. A catalytic spectrophotometric method for determination of nanomolar manganese in seawater using reverse flow injection analysis and a long path length liquid waveguide capillary cell[J]. Talanta, 2018,178:577-582.
【73】马莉.在线浓缩-流动注射分光光度法测定海水中痕量Cd(Ⅱ)和Cu(Ⅱ)的方法研究[D].成都:四川大学, 2006.
【74】母清林,方杰,佘运勇,等.在线稀释/预浓缩-电感耦合等离子体质谱法分析海水中11种痕量元素[J].分析化学, 2015,43(9):1360-1365.
相关信息
