扫一扫 加微信
首页 > 期刊论文 > 论文摘要
不同有机酸环境中相对湿度对铅腐蚀的影响
          
Influence of Relative Humidity on Different Organic Acid Vapour-Induced Atmospheric Corrosion of Lead

摘    要
模拟了不同湿度条件的无酸、甲酸、乙酸、新鲜樟木屑气氛环境,采用质量改变法、光泽度测量、SEM形貌观察、XRD和Raman光谱分析等技术,量化研究了不同酸环境中湿度对铅腐蚀的影响。研究表明:在各类环境中,铅的最初腐蚀产物主要是β-PbO,随后进一步生成致密度、晶型不同的腐蚀产物,腐蚀产物的致密性影响铅的持续腐蚀行为;有机酸会加速铅的腐蚀,且铅对环境中的乙酸更敏感,甲酸次之,樟木屑挥发有机物对铅的腐蚀有明显影响;基本上,环境中的湿度越高,腐蚀时间越长,铅的腐蚀速率越大;在新鲜樟木屑环境中,控制湿度能减缓铅器腐蚀。
标    签 铅器   铅质文物   铅腐蚀   有机酸   相对湿度   预防性保护   lead   lead cultural relic   lead corrosion   organic acid   relative humidity   preventive conservation  
 
Abstract
The atmosphere environment including acid-free, formic acid, acetic acid and fresh camphor sawdust with different humidity was simulated. The effects of humidity on lead corrosion in different environments were quantitatively studied by mass change method, gloss measurement, SEM morphology observation, XRD and Raman spectroscopy. The research showed that in various environments, the initial corrosion product of lead was mainly composed of β-PbO, and then further corrosion products with different densities and crystal forms were formed. The compactness of the corrosion products affected the continuous corrosion behavior of lead. Organic acids would accelerate the corrosion of lead, and lead was more sensitive to acetic acid in the environment, followed by formic acid, and the volatile organic compounds of camphor sawdust had a significant impact on the corrosion of lead. Basically, the higher the humidity in the environment and the longer the corrosion time, the greater the corrosion rate of lead. In the environment of fresh camphor sawdust, controlling humidity could slow down lead corrosion.

中图分类号 TG174   DOI 10.11973/fsyfh-202210003

 
  中国光学期刊网论文下载说明


所属栏目 试验研究

基金项目 中国国家博物馆馆级课题(GBKX2017Y10)

收稿日期 2022/4/3

修改稿日期

网络出版日期

作者单位点击查看


引用该论文: ZHAO Dandan,SHAN Ying,ZHANG Ran. Influence of Relative Humidity on Different Organic Acid Vapour-Induced Atmospheric Corrosion of Lead[J]. Corrosion & Protection, 2022, 43(10): 14


论文评价
共有人对该论文发表了看法,其中:
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
分享论文
分享到新浪微博 分享到腾讯微博 分享到人人网 分享到 Google Reader 分享到百度搜藏分享到Twitter

参考文献
【1】我国馆藏文物3018万件:50.66%存在腐蚀损害[J]. 收藏界, 2013(7):135-136.
 
【2】田景茹. 大气环境对博物馆内文物的影响[C]//决策论坛——如何制定科学决策学术研讨会.[出版地不详]:[出版者不详], 2015.
 
【3】李松瑞. 铅及铅合金[M]. 长沙:中南工业大学出版社, 1996:127.
 
【4】LEYGRAF C, ODNEVALL I, TIDBLAD J, et al. General characteristics of indoor environments[M]. Wiley:Hoboken, 2016:79-85.
 
【5】DEGRIGNY C. Use of artificial metal coupons to test new protection systems on cultural heritage objects:manufacturing and validation[J]. Corrosion Engineering, Science and Technology, 2010, 45(5):367-374.
 
【6】KWESTROO W, LANGEREIS C. Basic lead acetates[J]. Journal of Inorganic and Nuclear Chemistry, 1965, 27(12):2533-2536.
 
【7】RIMMER M, THICKETT D, WATKINSON D, et al. Guidelines for the storage and display of archaeological metalwork[M].[S.l.]:English Heritage, 2013:12.
 
【8】KOUR[AKČ]IL M, BOHÁC[AKČ]KOVÁ T, STRACHOTOV[AKČ] K C, et al. Lead corrosion and corrosivity classification in archives, museums, and churches[J]. Materials, 2022, 15(2):639.
 
【9】FITZHUGH E W, GETTENS R J. Calclacite and other efflorescent salts on objects stored in wooden museum cases[M]. Washington, DC:Science and Archaeology, 1971:20-40.
 
【10】TÉTREAULT J, SIROIS J, STAMATOPOULOU E, et al. Studies of lead corrosion in acetic acid environments[J]. Studies in Conservation, 1998, 43(1):17.
 
【11】TÉTREAULT J, CANO E, VAN BOMMEL M, et al. Corrosion of copper and lead by formaldehyde, formic and acetic acid vapours[J]. Studies in Conservation, 2003, 48(4):237-250.
 
【12】RAYCHAUDHURI M R, BRIMBLECOMBE P. Formaldehyde oxidation and lead corrosion[J]. Studies in Conservation, 2000, 45(4):226-232.
 
【13】RYHL-SVENDSEN M. Corrosivity measurements of indoor museum environments using lead coupons as dosimeters[J]. Journal of Cultural Heritage, 2008, 9(3):285-293.
 
【14】NIKLASSON A, JOHANSSON L G, SVENSSON J E. The influence of relative humidity and temperature on the acetic acid vapour-induced atmospheric corrosion of lead[J]. Corrosion Science, 2008, 50(11):3031-3037.
 
【15】王永红, 文杰, 鹿中晖. 土壤中阴离子对铅、铝腐蚀的加速试验研究[J]. 现代有线传输, 2000(2):28-30.
 
【16】鹿中晖, 王永红, 文杰. 铅在酸性土壤中的腐蚀行为研究[J]. 现代有线传输, 2001(2):14-17.
 
【17】姚维义, 唐谟堂, 彭可, 等. 铸造铅腐蚀机理的研究[J]. 腐蚀科学与防护技术, 2004, 16(4):203-206.
 
【18】THICKETT D. Relative effects of formaldehyde, formic and acetic acids on lead, copper and silver[M].[S.l.]:[s.n.], 1997.
 
【19】易洪, 李占元, 任长青. 饱和盐溶液标准相对湿度表(国际建议)介绍[C]//气湿敏学术交流会.[出版地不详]:[出版者不详], 1998.
 
【20】GREENSPAN L. Humidity fixed points of binary saturated aqueous solutions[J]. Journal of Research of the National Bureau of Standards Section A:Physics and Chemistry, 1977, 81A(1):89.
 
【21】中国文化遗产研究院. 中国文物保护与修复技术[M]. 北京:文物出版社, 2010:389.
 
相关信息
   标题 相关频次
 馆藏脆弱铁质文物展柜相对湿度被动控制的定量研究
 4
 AgO/PS微胶囊改性环氧基涂层对被微生物污染航油的抗菌性
 2
 非饱和混凝土中氯离子的毛细吸附
 2
 高聚物型色谱柱在高效液相色谱法分离测定有机酸中的应用
 2
 高湿热海洋大气环境下温度和湿度对Q345钢耐蚀性能的影响
 2
 光学传感器辅助氧气消耗法评估灰口铁的腐蚀状态
 2
 含SO2大气中湿度对低碳钢腐蚀行为的影响
 2
 离子色谱法同时测定不同时段酸雨中17种离子
 2
 离子色谱法同时测定洁厕剂中10种有机酸和无机酸
 2
 埋地钢质管道外防腐蚀层补口工艺评定的发展和应用
 2
 气相色谱法测定食品中12种有机酸
 2
 青岛室内大气环境中铁质试样的腐蚀劣化的行为
 2
 铁质文物腐蚀产物β-FeOOH的产生及危害
 2
 铁质文物腐蚀产物β-FeOOH中Cl的脱出和物相转化
 2
 有机酸二次掺杂超疏水聚苯胺的制备及其耐蚀性
 2
 有机酸性污染物对铜质材料的腐蚀影响
 2
 在线固相萃取-液相色谱-串联质谱法测定动物源食品中阿维菌素和伊维菌素的残留量
 2
 5,10,15-三苯基-20-吡啶基卟啉荧光猝灭法测定痕量铅
 1
 Chelex-100树脂对铅、镉、钠的吸附性能及其应用于原子吸收光谱法测定高盐食品中铅、镉含量
 1
 GF-AAS法和HG-AFS法测定土壤中铅的分析方法比较
 1
 ICP-AES法同时测定搪瓷餐具中铅镉锑镍的溶出量
 1
 X射线荧光光谱法测定聚合物材料中铅和镉
 1
 X射线荧光光谱法测定液体化妆品中铅、砷和浴盐中氯的含量
 1
 超声提取-石墨炉原子吸收光谱法测定高纯石墨中铅的含量
 1
 持久性化学改进剂铱用于石墨炉原子吸收光谱法测定粮食中痕量铅
 1
 单扫描示波极谱法测定中草药中铅和镉
 1
 电感耦合等离子体原子发射光谱法测定动物源抗癌中药中痕量铅
 1
 电感耦合等离子体原子发射光谱法测定工业废水中铅、镉、铬和砷
 1
 电感耦合等离子体原子发射光谱法测定面粉中铅和镉
 1
 电感耦合等离子体原子发射光谱法测定汽油中的铁、锰、铅
 1