Effect of Polyacrylic Acid on Flow Accelerated Corrosion Behavior of Pipe Materials in Secondary Circuit of Nuclear Power Plant
摘 要
采用核电厂二回路材料评估试验平台模拟核电厂二回路环境,在高纯度聚丙烯酸(PAA)分散剂条件下研究了不同Cr含量的管道材料的流动加速腐蚀(FAC)速率,并采用扫描电镜观察FAC后管材表面氧化层形貌。结果表明:在150℃、pH (25℃)为9.2,流速为5 m/s,溶解氧含量低于10 μg/L的条件下,连续循环200 h,添加1 mg/L PAA没有加快Cr含量低的WB36 CN1、A106B合金钢的FAC速率,但使Cr含量较高的A335 P22合金钢的FAC速率从0.005 1 mm/a加快至0.007 8 mm/a;PAA通过促进疏松微小氧化物颗粒的分散,减缓颗粒沉积,使A335 P22合金钢表面氧化膜变得疏松多孔;给水中PAA加量不超过5 μg/L时,PAA长期在线应用对二回路管道使用寿命降低的风险较低。
Abstract
Using nuclear power plant secondary circuit material evaluation test platform to simulate the environment of secondary circuit in power plant, the flow accelerated corrosion (FAC) rates of pipe materials with different Cr content were studied under high-purity polyacrylic acid (PAA) dispersant condition. And the morphology of oxide films on surfaces of pipe materials after FAC was observed by scanning electron microscopy (SEM). The results showed that under the conditions of 150℃, pH (25℃) 9.2, flow rate of 5 m/s, and dissolved oxygen content less than 10 μg/L, continuous circulation for 200 h, adding 1 mg/L PAA did not accelerate the FAC rates of alloy steels WB36 CN1, A106B with low Cr content, but accelerated the FAC rate of alloy steel A335 P22 with high Cr content from 0.005 1 mm/a to 0.007 8 mm/a. PAA made the oxide film on the surface of alloy steel A335 P22 loose and porous by promoting the dispersion of small loose oxide particles and slowing down the deposition of particles. If the dosage of PAA in feed water is no more than 5 μg/L, the risk of service life reduction of the secondary circuit pipe caused by long-term online PAA application should be low.
中图分类号 TG174 DOI 10.11973/fsyfh-202211009
所属栏目 试验研究
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收稿日期 2021/12/24
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引用该论文: QIAO Hang,WANG Li,LIN Genxian,LI Fuhai,LIU Canshuai. Effect of Polyacrylic Acid on Flow Accelerated Corrosion Behavior of Pipe Materials in Secondary Circuit of Nuclear Power Plant[J]. Corrosion & Protection, 2022, 43(11): 49
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参考文献
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【2】TREVIN S. Flow accelerated corrosion (FAC) in nuclear power plant components[M]//Nuclear Corrosion Science and Engineerin.[S.l.]:Woodhead Publishing Limited, 2012.
【3】王亮亮, 饶德林, 匡波, 等. A335P11钢在流动加速腐蚀条件下的管壁减薄行为[J]. 腐蚀与防护, 2018, 39(7):511-514, 520.
【4】钟志民, 郑会, 李杰. 核电厂二回路汽水管道局部减薄管理的挑战和应对[J]. 腐蚀与防护, 2020, 41(9):39-44.
【5】丁训慎. 核电站蒸汽发生器中的泥渣与污垢及其清洗[J]. 清洗世界, 2006, 22(5):27-32.
【6】YANG G Z, POINTEAU V, TEVISSEN E, et al. A review on clogging of recirculating steam generators in pressurized-water reactors[J]. Progress in Nuclear Energy, 2017, 97:182-196.
【7】林根仙, 薛飞, 鲁俊东, 等. 减少核电站蒸汽发生器淤泥沉积的方法[J]. 热力发电, 2011, 40(11):68-70.
【8】JOSHI A C, RUFUS A L, VELMURUGAN S. Poly(acrylic acid-co-maleic acid), a polymer dispersant for the control of oxide deposition over nuclear steam generator surfaces[J]. Journal of Nuclear Materials, 2018, 498:421-429.
【9】SONG G D, KIM M H, MAENG W Y. Optimization of polymeric dispersant concentration for the dispersion-stability of magnetite nanoparticles in water solution[J]. Journal of Nanoscience and Nanotechnology, 2014, 14(12):9525-9533.
【10】Dispersants for pressurized water reactor secondary side fouling control:2014 field evaluations[R]. Palo Alto:EPRI, 2015.
【11】Effect of polymer dispersant on flow-accelerated corrosion of steam generator materials[R]. Palo Alto:EPRI, 2005.
【12】Effect of polyacrylic acid injection on flow accelerated corrosion[R]. Paris:MAI, 2016.
【13】王力, 罗坤杰, 方可伟, 等. 在不同碱化剂溶液中TU48C钢的均匀腐蚀及流动加速腐蚀速率[J]. 机械工程材料, 2017, 41(8):80-83.
【14】曹林园, 王辉, 杨明馨, 等. 压水堆二回路工况下碱化剂对结构材料腐蚀的影响[J]. 原子能科学技术, 2020, 54(5):842-849.
【15】LÉPINE L, GILBERT R. Thermal degradation of polyacrylic acid in dilute aqueous solution[J]. Polymer Degradation and Stability, 2002, 75(2):337-345.
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