无机纳米粒子改性石墨烯基复合涂层的研究现状
Research Status of Inorganic Nano-Particle Modified Graphene Based Composite Coatings
摘 要
基于不同无机纳米粒子改性石墨烯的改性方法，综述了无机纳米粒子改性石墨烯基复合涂层的研究进展，探讨了无机纳米粒子改性石墨烯的机理，论述了改性复合涂层的合成方法。最后对无机纳米粒子改性石墨烯基复合防腐蚀涂层的发展前景进行了展望。
纳米粒子
复合涂层
防腐蚀
graphene
nano-particle
composite coating
corrosion protection
Abstract
The research progress of inorganic nano-particle modified graphene based composite coatings is reviewed based on modification methods of graphene modified by different inorganic nano-particles. The mechanisms of graphene modified by inorganic nano-particles are discussed, and the synthesis methods of modified composite coating are introduced. Finally, the development prospects of inorganic nano-particle modified graphene composite anticorrosion coating is proposed.
中图分类号 TG174 DOI 10.11973/fsyfh-202211016
所属栏目 专论
基金项目 国家自然科学基金（51176015）；江苏省重点实验室开放基金（312035）；常州市科技计划（CE20160069）；常州市应用基础研究（CJ20200085）
收稿日期 2020/11/5
修改稿日期
网络出版日期
作者单位点击查看
联系人作者王树立(wsl@cczu.edu.cn)
引用该论文: ZHAO Shuhua,DUAN Yunfei,CUI Jiawei,WANG Shuli,RAO Yongchao,LI Jiabo,LU Xiaodie. Research Status of Inorganic Nano-Particle Modified Graphene Based Composite Coatings[J]. Corrosion & Protection, 2022, 43(11): 88
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参考文献
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【33】IZADI M, SHAHRABI T, RAMEZANZADEH B. Active corrosion protection performance of an epoxy coating applied on the mild steel modified with an eco-friendly sol-gel film impregnated with green corrosion inhibitor loaded nanocontainers[J]. Applied Surface Science, 2018, 440:491-505.
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【35】RAMEZANZADEH B, BAHLAKEH G, RAMEZANZADEH M. Polyaniline-cerium oxide (PAni-CeO2) coated graphene oxide for enhancement of epoxy coating corrosion protection performance on mild steel[J]. Corrosion Science, 2018, 137:111-126.
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【37】SHEN L, LI Y, ZHAO W J, et al. Corrosion protection of graphene-modified zinc-rich epoxy coatings in dilute NaCl solution[J]. ACS Applied Nano Materials, 2019, 2(1):180-190.
【38】WU H S, ZHANG L Y, ZHANG Y C, et al. Corrosion behavior of Mg-Al LDH film in situ assembled with graphene on Mg alloy pre-sprayed Al layer[J]. Journal of Alloys and Compounds, 2020, 834:155107.
【2】CHAUHAN D S, QURAISHI M A, ANSARI K R, et al. Graphene and graphene oxide as new class of materials for corrosion control and protection:present status and future scenario[J]. Progress in Organic Coatings, 2020, 147:105741.
【3】赵书华, 黄从明, 王树立, 等. 氧化石墨烯/环氧复合涂层研究进展[J]. 腐蚀科学与防护技术, 2018, 30(5):552-556.
【4】RAMASAMY M S, MAHAPATRA S S, CHO J W. Functionalization of graphene with self-doped conducting polypyrrole by click coupling[J]. Journal of Colloid and Interface Science, 2015, 455:63-70.
【5】吕生华, 雷颖, 刘雷鹏, 等. 通过点击化学对氧化石墨烯进行改性的研究进展[J]. 陕西科技大学学报, 2020, 38(2):147-159, 171.
【6】CHANG K C, JI W F, LAI M C, et al. Correction:Synergistic effects of hydrophobicity and gas barrier properties on the anticorrosion property of PMMA nanocomposite coatings embedded with graphene nanosheets[J]. Polym Chem, 2014, 5(23):6865.
【7】CHANG C H, HUANG T C, PENG C W, et al. Novel anticorrosion coatings prepared from polyaniline/graphene composites[J]. Carbon, 2012, 50(14):5044-5051.
【8】KUILLA T, BHADRA S, YAO D H, et al. Recent advances in graphene based polymer composites[J]. Progress in Polymer Science, 2010, 35(11):1350-1375.
【9】SUN W, WANG L D, WU T T, et al. Synthesis oflow-electrical-conductivitygraphene/pernigranilinecom-posites and their application in corrosion protection[J]. Carbon, 2014, 79:605-614.
【10】SUN W, WANG L D, WU T T, et al. Inhibiting the corrosion-promotion activity of graphene[J]. Chemistry of Materials, 2015, 27(7):2367-2373.
【11】HUANG Y C, LO T Y, CHAO C G, et al. Anti-corrosion characteristics of polyimide/h-boron nitride composite films with different polymer configurations[J]. Surface and Coatings Technology, 2014, 260:113-117.
【12】李子帙. 偶联剂与无机纳米粒子之间的相互作用[J]. 哈尔滨理工大学学报, 2007, 12(5):61-63.
【13】SHAO L, QUAN S, LIU Y, et al. A novel "gel-Sol" strategy to synthesize TiO2 nanorod combining reduced graphene oxide composites[J]. Materials Letters, 2013, 107:307-310.
【14】王英楠. 改性纳米填料/双酚A型环氧树脂涂层的制备及防腐蚀性能研究[D]. 长春:吉林大学, 2018.
【15】POURHASHEM S, VAEZI M R, RASHIDI A. Investigating the effect of SiO2-graphene oxide hybrid as inorganic nanofiller on corrosion protection properties of epoxy coatings[J]. Surface and Coatings Technology, 2017, 311:282-294.
【16】吕鑫, 王维, 房冉冉, 等. 改性氧化石墨烯复合涂料的制备及其性能分析[J]. 山东化工, 2020, 49(4):63-64.
【17】RAMEZANZADEH B, NIROUMANDRAD S, AHMADI A, et al. Enhancement of barrier and corrosion protection performance of an epoxy coating through wet transfer of amino functionalized graphene oxide[J]. Corrosion Science, 2016, 103:283-304.
【18】巴淼, 张占平, 齐育红. 有机硅防污涂料的研究进展[J]. 表面技术, 2017, 46(10):1-8.
【19】KNOPP D, TANG D P, NIESSNER R. Review:Bioanalytical applications of biomolecule-functionalized nanometer-sized doped silica particles[J]. Analytica Chimica Acta, 2009, 647(1):14-30.
【20】SIENGCHIN S. Impact, thermal and mechanical properties of high density polyethylene/flax/SiO2 composites:effect of flax reinforcing structures[J]. Journal of Reinforced Plastics and Composites, 2012, 31(14):959-966.
【21】SUN W, WANG L D, WU T T, et al. Inhibited corrosion-promotion activity of graphene encapsulated in nanosized silicon oxide[J]. Journal of Materials Chemistry A, 2015, 3(32):16843-16848.
【22】MA Y, DI H H, YU Z X, et al. Fabrication of silica-decorated graphene oxide nanohybrids and the properties of composite epoxy coatings research[J]. Applied Surface Science, 2016, 360:936-945.
【23】杨凝. 石墨烯基层状纳米材料改性水性涂层的制备及防腐蚀性能研究[D]. 青岛:中国科学院大学(中国科学院海洋研究所), 2019.
【24】张美玲. 二氧化硅包覆氧化石墨烯/环氧复合涂层防腐性能的研究[D]. 西安:西北大学, 2018.
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【27】LIU S L, ZHU Y S, ZHENG X P, et al. Graphene oxide modified by zirconium dioxide to enhance the corrosion resistance of zinc/aluminum coatings[J]. Diamond and Related Materials, 2020, 108:107868.
【28】赵书华, 陈宏, 王树立, 等. 石墨烯对硅酸盐富锌防腐蚀涂层性能的影响[J]. 腐蚀与防护, 2018, 39(12):930-935, 940.
【29】PUNITH KUMAR M K, RAY S, SRIVASTAVA C. Effect of graphene addition on composition, morphology and corrosion behavior of ZnNiFe-graphene composite coatings[J]. Diamond and Related Materials, 2020, 107:107904.
【30】丁明洁, 肖雅丽. 纳米四氧化三铁及其复合材料的性能研究进展[J]. 广东化工, 2017, 44(16):129-131.
【31】张慧勇. Fe3O4/SiO2核壳结构复合纳米粒子的制备研究[J]. 广州化工, 2016, 44(7):52-54.
【32】ZHAN Y Q, ZHANG J M, WAN X Y, et al. Epoxy composites coating with Fe3O4 decorated graphene oxide:modified bio-inspired surface chemistry, synergistic effect and improved anti-corrosion performance[J]. Applied Surface Science, 2018, 436:756-767.
【33】IZADI M, SHAHRABI T, RAMEZANZADEH B. Active corrosion protection performance of an epoxy coating applied on the mild steel modified with an eco-friendly sol-gel film impregnated with green corrosion inhibitor loaded nanocontainers[J]. Applied Surface Science, 2018, 440:491-505.
【34】杜鹏. 二维材料/自修复有机涂层的制备及其防腐性能研究[D]. 济南:山东大学, 2019.
【35】RAMEZANZADEH B, BAHLAKEH G, RAMEZANZADEH M. Polyaniline-cerium oxide (PAni-CeO2) coated graphene oxide for enhancement of epoxy coating corrosion protection performance on mild steel[J]. Corrosion Science, 2018, 137:111-126.
【36】左银泽, 陈亮, 朱斌, 等. 纳米氧化锌负载氧化石墨烯/环氧树脂复合材料性能研究[J]. 材料工程, 2018, 46(5):22-28.
【37】SHEN L, LI Y, ZHAO W J, et al. Corrosion protection of graphene-modified zinc-rich epoxy coatings in dilute NaCl solution[J]. ACS Applied Nano Materials, 2019, 2(1):180-190.
【38】WU H S, ZHANG L Y, ZHANG Y C, et al. Corrosion behavior of Mg-Al LDH film in situ assembled with graphene on Mg alloy pre-sprayed Al layer[J]. Journal of Alloys and Compounds, 2020, 834:155107.
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